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991.
Clément Fontana Christian Grenz Christel Pinazo Patrick Marsaleix Frédéric Diaz 《Continental Shelf Research》2009,29(11-12):1397-1409
In order to predict eutrophication events in coastal areas we tested an assimilation scheme based on sequential data assimilation of SeaWiFS chlorophyll data into a coupled 3D physical–biogeochemical model. The area investigated is a semi-enclosed estuarine system (Gulf of Fos–North-western Mediterranean Sea) closely linked to the Rhone River delta. This system is subjected to episodic eutrophication caused by certain hydrodynamic conditions and intermittent nutrient inputs. The 3D hydrodynamic model Symphonie was coupled to the biogeochemical modelling platform Eco3M. Surface chlorophyll concentrations were derived from SeaWiFS data using the OC5 algorithm and were sequentially assimilated using a singular evolutive extended Kalman filter. Assimilation efficiency was evaluated through an independent in situ data set collected during a field survey that took place in May 2001 (ModelFos cruise). An original approach was used in constructing the state vector and the observation vector. By assimilating pseudo-salinity extracted from the model biogeochemical dynamics in both open sea and plume region were respected. We proved that substantial improvements were made in short-term forecasts by integrating such satellite-estimated chlorophyll maps. We showed that missing freshwater inputs could be corrected to a certain extent by the assimilation process. Simulated concentrations of surface chlorophyll and other basic components of the pelagic ecosystem such as nitrates were improved by assimilating surface chlorophyll maps. Finally we showed the coherent spatial behaviour of the filter over the whole modelled domain. 相似文献
992.
W. I. Clarkson B. Enoch C. A. Haswell A. J. Norton D. J. Christian A. Collier Cameron S. R. Kane K. D. Horne T. A. Lister R. A. Street R. G. West D. M. Wilson N. Evans A. Fitzsimmons C. Hellier S. T. Hodgkin J. Irwin F. P. Keenan J. P. Osborne N. R. Parley D. L. Pollacco R. Ryans I. Skillen P. J. Wheatley 《Monthly notices of the Royal Astronomical Society》2007,381(2):851-864
993.
994.
Patricia Fernndez-Calvo Christian Nke Luis A. Rivas Miriam García-Villadangos Javier Gmez-Elvira Víctor Parro 《Planetary and Space Science》2006,54(15):1612-1621
We have developed antibodies and a multi-array competitive immunoassay (MACIA) for the detection of a wide range of molecular size compounds, from single aromatic ring derivatives or polycyclic aromatic hydrocarbons (PAHs), through small peptides, proteins or whole cells (spores). Multiple microarrays containing target molecules are used simultaneously to run several competitive immunoassays. The sensitivity of the MACIA for small organic compounds like naphthalene, 4-phenilphenol or 4-tertbutilphenol is in the range of 100–500 ppb (ng ml−1), for others like the insecticide terbutryn it is at the ppt (ng l−1) level, while for small peptides, as well as for more complex molecules like the protein thioredoxin, the sensitivity is approximately 1–2 ppb, or 104–105 spores of Bacillus subtilis per milliliter. For organic compounds, a water–methanol solution was used in order to achieve a better dissolution of the organics without compromising the antibody–antigen interaction. The above-mentioned compounds were detected by MACIA in water–(10%) methanol extracts from spiked pyrite and hematite-containing rock powder samples, as well as from a spiked-sand sample subjected to organic extraction with dichloromethane–methanol (1/1). 相似文献
995.
Jun-ichi Matsuda Kayo Matsubara Christian Koeberl 《Meteoritics & planetary science》1993,28(4):586-589
Abstract— Heavy noble gas concentrations in tektites (splash-form type) are considerably lower than those in impact glasses. This can not be explained only by high formation temperatures for tektites, as might be expected from low concentrations of water and most volatile elements in tektites, and indicates that tektites solidified in an atmosphere with an ambient pressure of much less than 1 atm. The heavy noble gas concentrations may be an indicator of the height to which tektites were carried by the impact before they solidified. 相似文献
996.
Abstract— The 1.07 Ma well‐preserved Bosumtwi impact structure in Ghana (10.5 km in diameter) formed in 2 Ga‐old metamorphosed and crystalline rocks of the Birimian system. The interior of the structure is largely filled by the 8 km diameter Lake Bosumtwi, and the crater rim and region in the environs of the crater is covered by tropical rainforest, making geological studies rather difficult and restricted to road cuts and streams. In early 1999, we undertook a shallow drilling program to the north of the crater rim to determine the extent of the ejecta blanket around the crater and to obtain subsurface core samples for mineralogical, petrological, and geochemical studies of ejecta of the Bosumtwi impact structure. A variety of impactite lithologies are present, consisting of impact glassrich suevite and several types of breccia: lithic breccia of single rock type, often grading into unbrecciated rock, with the rocks being shattered more or less in situ without much relative displacement (autochthonous?), and lithic polymict breccia that apparently do not contain any glassy material (allochtonous?). The suevite cores show that melt inclusions are present throughout the whole length of the cores in the form of vesicular glasses with no significant change of abundance with depth. Twenty samples from the 7 drill cores and 4 samples from recent road cuts in the structure were studied for their geochemical characteristics to accumulate a database for impact lithologies and their erosion products present at the Bosumtwi crater. Major and trace element analyses yielded compositions similar to those of the target rocks in the area (graywacke‐phyllite, shale, and granite). Graywacke‐phyllite and granite dikes seem to be important contributors to the compositions of the suevite and the road cut samples (fragmentary matrix), with a minor contribution of Pepiakese granite. The results also provide information about the thickness of the fallout suevite in the northern part of the Bosumtwi structure, which was determined to be ≤15 m and to occupy an area of ?1.5 km2. Present suevite distribution is likely to be caused by differential erosion and does not reflect the initial areal extent of the continuous Bosumtwi ejecta deposits. Our studies allow a comparison with the extent of the suevite at the Ries, another well‐preserved impact structure. 相似文献
997.
Internal parts of the Alps have undergone widespread extensional deformation in the course of their Neogene exhumation history. Palaeostress inversion methods are used to map the prevailing stress fields and their evolution through time. Here we present new data from 100 sites with a total of about 2000 faults/striae couples, covering a large portion of the inner north‐western Alps. Palaeostress tensors are mostly extensional, although one‐third of them are transcurrent. The dominant direction of minimum horizontal stress axes (σ3) is in an orogen‐parallel (N30° to N70°) orientation around the bend of the north‐west alpine arc. A comparison between this older (Neogene, post‐metamorphic) stress field with the current stress and strain field determined from seismotectonics and geodesy indicates a change in deformation mode from early orogen‐parallel extrusion to a late and ongoing orogen‐perpendicular spreading. 相似文献
998.
999.
Jamie Lee Stevenson Christian Birkel Aaron J. Neill Doerthe Tetzlaff Chris Soulsby 《水文研究》2021,35(6):e14223
Isotopes are increasingly used in rainfall-runoff models to constrain conceptualisations of internal catchment functioning and reduce model uncertainty. However, there is little guidance on how much tracer data is required to adequately do this, and different studies use data from different sampling strategies. Here, we used a 7-year time series of daily stable water isotope samples of precipitation and streamflow to derive a range of typical stream sampling regimes and investigate how this impacts calibration of a semi-distributed tracer-aided model in terms of flow, deuterium and flux age simulations. Over the 7 years weekly sampling facilitated an almost identical model performance as daily, and there were only slight deteriorations in performance for fortnightly sampling. Monthly sampling resulted in poorer deuterium simulations and greater uncertainty in the derived parameter sets ability to accurately represent catchment functioning, evidenced by unrealistic reductions in the volumes of water available for mixing in the saturation area causing simulated water age decreases. Reducing sampling effort and restricting data collection to 3 years caused reductions in the accuracy of deuterium simulation, though the deterioration did not occur if sampling continued for 5 years. Analysis was also undertaken to consider the effects of reduced sampling effort over the driest and wettest hydrological years to evaluate effects of more extreme conditions. This showed that the model was particularly sensitive to changes in sampling during dry conditions, when the catchment hydrological response is most non-linear. Across all dataset durations, sampling in relation to flow conditions, rather than time, revealed that samples collected at flows >Q50 could provide calibration results comparable to daily sampling. Targeting only extreme high flows resulted in poor deuterium and low flow simulations. This study suggests sufficient characterization of catchment functioning can be obtained through reduced sampling effort over longer timescales and the targeting of flows >Q50. 相似文献
1000.
Using lumped conceptual rainfall-runoff models to simulate daily isotope variability with fractionation in a nested mesoscale catchment 总被引:1,自引:0,他引:1
Christian Birkel Doerthe Tetzlaff Sarah M. Dunn Chris Soulsby 《Advances in water resources》2011,34(3):383-394
This paper presents 19 months of stable isotope (δ2H and δ18O) data to enhance understanding of water and solute transport at two spatial scales (2.3 km2 and 122 km2) in the agricultural Lunan catchment, Scotland. Daily precipitation and stream isotope data, weekly lake and spring isotope data and monthly groundwater isotope data revealed important insights into flow pathways and mixing of water at both scales. In particular, a deeper groundwater flow path significantly contributes to total streamflow (25-50%). Upstream lake isotope dynamics, susceptible to evaporative fractionation, also appeared to have an important influence on the downstream isotope composition. This unique tracer data set facilitated the conceptualization of a lumped catchment-scale flow-tracer model. The incorporation of hydrological, mixing and fractionation processes based on these data improved simulations of the stream δ2H isotope response at the catchment outlet from 0.37 to 0.56 for the Nash-Sutcliffe statistic. The stable isotope data successfully aided model conceptualization and calibration in the quest for a simple water and solute transport model with improved representation of process dynamics. 相似文献