Texture and anisotropy analysis of Qusaiba shales

Scanning and transmission electron microscopy, synchrotron X‐ray diffraction, microtomography and ultrasonic velocity measurements were used to characterize microstructures and anisotropy of three deeply buried Qusaiba shales from the Rub’al‐Khali basin, Saudi Arabia. Kaolinite, illite‐smectite, illite‐mica and chlorite show strong preferred orientation with (001) pole figure maxima perpendicular to the bedding plane ranging from 2.4–6.8 multiples of a random distribution (m.r.d.). Quartz, feldspars and pyrite crystals have a random orientation distribution. Elastic properties of the polyphase aggregate are calculated by averaging the single crystal elastic properties over the orientation distribution, assuming a nonporous material. The average calculated bulk P‐wave velocities are 6.2 km/s (maximum) and 5.5 km/s (minimum), resulting in a P‐wave anisotropy of 12%. The calculated velocities are compared with those determined from ultrasonic velocity measurements on a similar sample. In the ultrasonic experiment, which measures the effects of the shale matrix as well as the effects of porosity, velocities are smaller (P‐wave maximum 5.3 km/s and minimum 4.1 km/s). The difference between calculated and measured velocities is attributed to the effects of anisotropic pore structure and to microfractures present in the sample, which have not been taken into account in the matrix averaging.     

Impact of recent climatic change on growth of low elevation eastern Mediterranean forest trees

Evidence is presented of how Pinus halepensis Miller from dry habitats at <300 m elevation of four Greek island regions have responded to climatic conditions of the last two centuries. We compared historical periods of low growth due to low precipitation with the recent period of significant precipitation decline. In all cases trees?? growth patterns across the twentieth century were consistent with trends in annual (rather than seasonal) precipitation, with lowest values in both precipitation and radial growth during the last two decades of the twentieth century, the worst conditions for tree growth in more than 200 years. The data are compared with trends across different vegetation belts of the northern Mediterranean basin. Drought related tree mortality in Greece in 2000 and 2007 coincided with the most severe fire outbreaks on record. IPCC WG I (2007) climate scenarios for the Mediterranean suggest a further decline in precipitation, particularly in the eastern regions. Should this occur, growth reduction in trees, tree mortality and damage from forest fires are likely to become more severe.     

Raman study of apatite amorphised with swift heavy ions under various irradiation conditions

Crystallographically oriented Durango fluorapatites were exposed to swift heavy ions (Xe, Ta, Au, U) at different irradiation conditions. Beam-induced sample modifications were investigated with respect to the effect of fluence (10⁹–10¹³ ions/cm²), electronic energy loss (18–27 keV/nm), and pressure (3.6–11.5 GPa) applied during irradiation. In situ high-pressure irradiation was performed in diamond anvil cells. Confocal Raman spectroscopy was used to trace the occurring changes in the crystal lattice. Fragmentation of the crystal specimen depends on the orientation and sample thickness and was found to scale with energy loss and fluence. The radiation damage for irradiation along the c-axis was found to be larger than for the 〈hk0〉 direction, independent of the confining pressure. Observations on samples irradiated at high pressures indicate a stabilising effect, leading to reduced amorphisation in comparison to the samples irradiated without pressure.     

Line-broadening effects in the powder infrared spectrum of apatite

The crystallinity of natural and synthetic apatite samples is often determined from the broadening of ν ₄ PO₄ infrared absorption bands. However, various physical mechanisms contribute to the observed linewidth. In the present study, the factors determining the linewidth in the powder spectrum of synthetic fluorapatite and hydroxyapatite samples are investigated. The temperature dependence of the infrared spectrum (10–270 K) is used to assess the respective contributions of homogeneous broadening, related to the decay of phonons through anharmonic coupling, and heterogeneous broadening related to elastic strain and macroscopic electrostatic effects. This latter contribution is dominant in the investigated samples and depends on the shape of powder particles. It is discussed under the light of the theoretical modeling of the low-frequency dielectric properties of apatite based on first-principles density functional theory calculations. The linewidth of the weak ν ₁ PO₄ absorption band provides a reliable information on microscopic sources of broadening, i.e., apatite crystallinity. In comparison, the other more intense PO₄ bands are more sensitive to long-range electrostatic effects.     

Lithospheric tectonic structures developed under high-grade metamorphism in the Southern part of Madagascar

Abstract

This paper describes the tectono-metamorphic evolution of a segment of the Precambrian deep crust, in the southern Madagascar island. This crust corresponds to an Archaean basement reworked by a widespread, late panAfrican event (550–580 Ma) during the formation of the Mozambican belt. The finite geometry and associated metamorphism are depicted by satellite imaging, field mapping and P-T estimations using both conventional thermobarometric methods and TWEEQ software program with internally consistent thermodynamic data and uniform set of solution models. The structural pattern developed during high-grade metamorphism shows the juxtaposition of domains with complex fold geometries separated by a 15 km wide ductile shear zone. Within the folded domains, kilometre scale interference patterns associated with strongly dipping metamorphic stretching lineations can be described as superposed folding (F1 and F2 folds). The tight and upright F2 folds result from East-West horizontal shortening. The shear zone is defined by homogeneous orientations of steep foliations, sub-horizontal stretching lineations, and kilometre scale strain gradient. Within the shear zone, we observe dominant non-coaxial criteria at various scales that are consistent with a sinistral strike-slip system during D2 deformation stage. Nevertheless, we have also found in the shear zone, geometries typical of a horizontal shortening. Such a strain pattern is characteristic of transpression tectonics.

The synkinematic metamorphic conditions are estimated on mafic garnetiferous metabasites. Results show that regional transpression tectonics has developed under very high and constant thermal regime (about 800°C). A pressure gap, of about 3 kbar between the domains separated by the shear zone is identified. This implies tectonic coupling of two different structural levels during tranpressive tectonic.     

Rock magnetic study of basic intrusions and massive sulphides in the Hercynian central Jebilets Massif (Occidental-Meseta), Morocco

This paper describes a multidisciplinary study approach (petrography and rock magnetism) conducted on samples collected from the study area to characterise the magnetic mineralogy and to determine if the magnetisation of both lithologies were induced or retain a remnant component. Petrophysical, mineralogical and geochemical analyses confirm bimodal aspects, particularly in basic rocks; the two magnetic modes depend essentially on the mineralogical and geochemical characteristics of the samples. The ultramafic rocks comprise a highly altered primary mineralogy with chromite and magnetite as magnetic phases. The second type is of mafic composition with a less altered primary mineralogy and essentially magnetite and/or (hemo-ilmenite) as a carrier of magnetic mineralisation. Sulphides are characterised by high concentrations of Cu, Zn and Pb. The mineralogy is composed mainly of pyrrhotite (85% to 90%), sphalerite, galena, chalcopyrite, arsenopyrite and, occasionally, stannite. Monocline pyrrhotite seems to be the magnetic carrier of magnetisation in both Draa Sfar and Koudiat Aïcha. However, we suspect a different amount of hexagonal pyrrhotite as the cause of different magnetic behaviour. Paleomagnetic and thermomagnetic analyses reveal different. The calculated characteristic direction of natural remnant magnetisation for sulphides was used to model the magnetic anomaly of Draa Sfar. The proposed model match the geological features concluded from geological mapping and boreholes. Results from this work can be very useful for any modelling processes of magnetic anomalies suspected due to a sulphide mineralisation in an area with poor outcrops and no presence of boreholes information or of any geological or geochemical data.     

Global height system unification with GOCE: a simulation study on the indirect bias term in the GBVP approach

One of the main objectives of ESA’s Gravity Field and Steady-State Ocean Circulation mission GOCE (Gravity field and steady-state ocean circulation mission, 1999) is to allow global unification of height systems by directly providing potential differences between benchmarks in different height datum zones. In other words, GOCE provides a globally consistent and unbiased geoid. If this information is combined with ellipsoidal (derived from geodetic space techniques) and physical heights (derived from leveling/gravimetry) at the same benchmarks, datum offsets between the datum zones can be determined and all zones unified. The expected accuracy of GOCE is around 2–3 cm up to spherical harmonic degree n _max ≈ 200. The omission error above this degree amounts to about 30 cm which cannot be neglected. Therefore, terrestrial residual gravity anomalies are necessary to evaluate the medium and short wavelengths of the geoid, i.e. one has to solve the Geodetic Boundary Value Problem (GBVP). The theory of height unification by the GBVP approach is well developed, see e.g. Colombo (A World Vertical Network. Report 296, Department of Geodetic Science and Surveying, 1980) or Rummel and Teunissen (Bull Geod 62:477–498, 1988). Thereby, it must be considered that terrestrial gravity anomalies referring to different datum zones are biased due to the respective datum offsets. Consequently, the height reference surface of a specific datum zone deviates from the unbiased geoid not only due to its own datum offset (direct bias term) but is also indirectly affected by the integration of biased gravity anomalies. The latter effect is called the indirect bias term and it considerably complicates the adjustment model for global height unification. If no satellite based gravity model is employed, this error amounts to about the same size as the datum offsets, i.e. 1–2 m globally. We show that this value decreases if a satellite-only gravity model is used. Specifically for GOCE with n _max ≈ 200, the error can be expected not to exceed the level of 1 cm, allowing the effect to be neglected in practical height unification. The results are supported by recent findings by Gatti et al. (J Geod, 2012).     

Positional accuracy of the Google Earth terrain model derived from stratigraphic unconformities in the Big Bend region,Texas, USA

The Google Earth terrain model could prove beneficial for extraction of positional data in the future. At present, only an aging independent benchmark study (Potere, D., 2008. Horizontal position accuracy of Google Earth's high-resolution imagery archive. Sensors, 8, 7973–7981) provides constraints on positional accuracy for Google Earth imagery. In this investigation, we compared virtually traced positions against high-precision (<1 m) field measurements along three stratigraphic unconformity sub-sections in the Big Bend region to determine current positional accuracy for the Google Earth terrain model. A horizontal position accuracy of 2.64 m RMSE_r was determined for the Google Earth terrain model with mean offset distance being 6.95 m. A vertical position accuracy of 1.63 m RMSE_z with mean offset distance of 2.66 m was also calculated for the terrain model. Results suggest data extracted from the Google Earth terrain model could plausibly be used in future studies. However, we urge caution in using Google Earth data due to limited information disclosures by developers.