Turbulent dispersion in the ocean

The mathematical framework for turbulent transport in the ocean is reasonably well established. It may be applied to large-scale fields of scalars in the ocean and to the instantaneous or continuous discharge from a point. The theory and its physical basis can also provide an interpretation of passive scalar spectra. Spatial variations in the rate of turbulent transfer can be related to the movement of the center of mass of a scalar and to a formulation in terms of entrainment. The relative dispersion of a scalar with respect to its center of mass and the streakiness of the concentration field within the relative dispersion domain need to be considered. In many of these problems it is valuable to think in terms of simple models for individual streaks, as well as overall statistical properties.     

Development of ST:REAM: a reach‐based stream power balance approach for predicting alluvial river channel adjustment

River channel sediment dynamics are important in integrated catchment management because changes in channel morphology resulting from sediment transfer have important implications for many river functions. However, application of existing approaches that account for catchment‐scale sediment dynamics has been limited, largely due to the difficulty in obtaining data necessary to support them. It is within this context that this study develops a new, reach‐based, stream power balance approach for predicting river channel adjustment. The new approach, named ST:REAM (sediment transport: reach equilibrium assessment method), is based upon calculations of unit bed area stream power (ω) derived from remotely sensed slope, width and discharge datasets. ST:REAM applies a zonation algorithm to values of ω that are spaced every 50 m along the catchment network in order to divide the branches of the network up into relatively homogenous reaches. ST:REAM then compares each reach's ω value with the ω of its upstream neighbour in order to predict whether or not the reach is likely to be either erosion dominated or deposition dominated. The paper describes the application of ST:REAM to the River Taff in South Wales, UK. This test study demonstrated that ST:REAM can be rapidly applied using remotely sensed data that are available across many river catchments and that ST:REAM correctly predicted the status of 87.5% of sites within the Taff catchment that field observations had defined as being either erosion or deposition dominated. However, there are currently a number of factors that limit the usefulness of ST:REAM, including inconsistent performance and the need for additional, resource intensive, data to be collected to both calibrate the model and aid interpretation of its results. Copyright © 2014 John Wiley & Sons, Ltd.     

Efstadalsvatn – a multi-proxy study of a Holocene lacustrine sequence from NW Iceland

Multi-proxy data, both lithostratigraphic and biostratigraphic, are presented from Efstadalsvatn, a lake in NW Iceland. The sequence covers the period 10,000 to 3500 ¹⁴C yr B.P. The biostratgraphic data include the first Icelandic chironomid-based reconstruction of Holocene mean July air temperatures, using a Norwegian training set in the absence of modern Icelandic data. The results show that deglaciation and ecosystem development probably began before 10,000 ¹⁴C yr B.P. and that July temperatures were around 4°C at ca. 9500 ¹⁴C yr B.P. Temperatures then rose to ca. 8°C at the time of the deposition of the Saksunarvatn tephra (9100 ¹⁴C yr B.P.), reaching ca. 10°C by 8500 ¹⁴C yr B.P., high enough for the growth of tree birch, although successful birch colonisation did not take place until 6750 ¹⁴C yr B.P. There is some evidence for cooling immediately preceding 9100 ¹⁴C yr B.P. There is little firm biostratigraphic evidence for the 8200 cal. B.P. event, although this may be due to a relatively low resolution pollen sampling interval, but there are changes at this time in the total carbon (TC) and mass susceptibility (MS) data. Optimal temperatures and relative vegetation stability may have occurred between 8000–6100 ¹⁴C yr B.P. but the chironomid assemblages indicate higher temperatures after 5000 ¹⁴C yr B.P. This latter interpretation may, however, reflect delayed colonisation of thermophilous taxa and requires further investigation. There is evidence in the lithostratigraphy for greater local terrestrial instability after 6100 ¹⁴C yr B.P. but it seems unlikely that this led to the redevelopment of ice in the catchment. The biostratigraphic records appear to show a degree of resistence to climate forcing throughout the early and middle Holocene. The new chironomid-based temperature reconstruction needs to be refined by further studies in Iceland, particularly the development of an Icelandic training set, but has already demonstrated the problems of paleoclimatic interpretations based on pollen and/or macrofossil evidence alone.     

Post-peak,fluid-mediated modification of granulite facies zircon and monazite in the Trivandrum Block,southern India

The quarry at Kottavattom in the Trivandrum Block of southern India contains spectacular examples of fluid-assisted alteration of high-grade metamorphic rocks. Garnet-biotite gneiss has undergone a change in mineral assemblage to form submetre scale orthopyroxene-bearing patches, later retrogressed to form an amphibole-bearing lithology. These patches, often referred to as arrested or incipient charnockite, crosscut the original metamorphic foliation and are typically attributed to passage of a low aH₂O fluid through the rock. Whilst this conversion is recognised as a late stage process, little detailed chronological work exists to link it temporally to metamorphism in the region. Zircon and monazite analysed from Kottavattom not only record metamorphism in the Trivandrum Block but also show internal, lobate textures crosscutting the original zoning, consistent with fluid-aided coupled dissolution-reprecipitation during formation of the orthopyroxene-bearing patches. High-grade metamorphism at the quarry occurred between the formation of metamorphic monazite at ~585 Ma and the growth of metamorphic zircon at ~523 Ma. The fluid-assisted alteration of the garnet-biotite gneiss is poorly recorded by altered zircon with only minimal resetting of the U–Pb system, whereas monazite has in some cases undergone complete U–Pb resetting and records an age for fluid infiltration at ~495 Ma. The fluid event therefore places the formation of the altered patches at least 25 Myr after the zircon crystallisation in the garnet-biotite gneiss. The most likely fluid composition causing the modification and U–Pb resetting of zircon and monazite is locally derived hypersaline brine.     

Relationship among titanium,rare earth elements,U–Pb ages and deformation microstructures in zircon: Implications for Ti-in-zircon thermometry

A zircon grain in an orthopyroxene–garnet–phlogopite–zircon–rutile-bearing xenolith from Udachnaya, Siberia, preserves a pattern of crystallographic misorientation and subgrain microstructure associated with crystal–plastic deformation. The zircon grain records significant variations in titanium (Ti) from 2.6 to 30 ppm that corresponds to a difference in calculated Ti-in-zircon temperatures of over several hundred degrees Celsius. The highest Ti concentration is measured at subgrain centres (30 ppm), and Ti is variably depleted at low-angle boundaries (down to 2.6 ppm). Variations in cathodoluminescence coincide with the deformation microstructure and indicate localised, differential enrichment of rare earth elements (REE) at low-angle boundaries. Variable enrichment of U and Th and systematic increase of Th/U from 1.61 to 3.52 occurs at low-angle boundaries. Individual SHRIMP-derived U–Pb ages from more deformed zones (mean age of 1799 ± 40, n = 22) are systematically younger than subgrain cores (mean age of 1851 ± 65 Ma, n = 7), and indicate that open system behaviour of Ti–Th–U occurred shortly after zircon growth, prior to the accumulation of significant radiogenic Pb. Modelling of trace-element diffusion distances for geologically reasonable thermal histories indicates that the observed variations are ~ 5 orders of magnitude greater than can be accounted for by volume diffusion. The data are best explained by enhanced diffusion of U, Th and Ti along deformation-related fast-diffusion pathways, such as dislocations and low-angle (< 5°) boundaries. These results indicate chemical exchange between zircon and the surrounding matrix and show that Ti-in-zircon thermometry and U–Pb geochronology from deformed zircon may not yield information relating to the conditions and timing of primary crystallisation.     

Evidence of Self‐Organized Criticality in riverbank mass failures: a matter of perspective?

A growing body of field, theoretical and numerical modelling studies suggests that predicting river response to even major changes in input variables is difficult. Rivers are seen to adjust rapidly and variably through time and space as well as changing independently of major driving variables. Concepts such as Self‐Organized Criticality (SOC) are considered to better reflect the complex interactions and adjustments occurring in systems than traditional approaches of cause and effect. This study tests the hypothesis that riverbank mass failures which occurred both prior to, and during, an extreme flood event in southeast Queensland (SEQ) in 2011 are a manifestation of SOC. Each wet‐flow failure is somewhat analogous to the ‘avalanche’ described in the initial sand‐pile experiments of Bak et al. (Physical Review Letters, 1987, 59(4), 381–384) and, due to the use of multitemporal LiDAR, the time period of instability can be effectively constrained to that surrounding the flood event. The data is examined with respect to the key factors thought to be significant in evaluating the existence of SOC including; non‐linear temporal dynamics in the occurrence of disturbance events within the system; an inverse power‐law relation between the magnitude and frequency of the events; the existence of a critical state to which the system readjusts after a disturbance; the existence of a cascading processes mechanism by which the same process can initiate both low‐magnitude and high‐magnitude events. While there was a significant change in the frequency of mass failures pre‐ and post‐flood, suggesting non‐linear temporal dynamics in the occurrence of disturbance events, the data did not fit an inverse power‐law within acceptable probability and other models were found to fit the data better. Likewise, determining a single ‘critical’ state is problematic when a variety of feedbacks and multiple modes of adjustment are likely to have operated throughout this high magnitude event. Overall, the extent to which the data supports a self‐organized critical state is variable and highly dependent upon inferential arguments. Investigating the existence of SOC, however, provided results and insights that are useful to the management and future prediction of these features. Copyright © 2014 John Wiley & Sons, Ltd.     

Sedimentology of the continental end‐Permian extinction event in the Sydney Basin,eastern Australia

Upper Permian to Lower Triassic coastal plain successions of the Sydney Basin in eastern Australia have been investigated in outcrop and continuous drillcores. The purpose of the investigation is to provide an assessment of palaeoenvironmental change at high southern palaeolatitudes in a continental margin context for the late Permian (Lopingian), across the end‐Permian Extinction interval, and into the Early Triassic. These basins were affected by explosive volcanic eruptions during the late Permian and, to a much lesser extent, during the Early Triassic, allowing high‐resolution age determination on the numerous tuff horizons. Palaeobotanical and radiogenic isotope data indicate that the end‐Permian Extinction occurs at the top of the uppermost coal bed, and the Permo‐Triassic boundary either within an immediately overlying mudrock succession or within a succeeding channel sandstone body, depending on locality due to lateral variation. Late Permian depositional environments were initially (during the Wuchiapingian) shallow marine and deltaic, but coastal plain fluvial environments with extensive coal‐forming mires became progressively established during the early late Permian, reflected in numerous preserved coal seams. The fluvial style of coastal plain channel deposits varies geographically. However, apart from the loss of peat‐forming mires, no significant long‐term change in depositional style (grain size, sediment‐body architecture, or sediment dispersal direction) was noted across the end‐Permian Extinction (pinpointed by turnover of the palaeoflora). There is no evidence for immediate aridification across the boundary despite a loss of coal from these successions. Rather, the end‐Permian Extinction marks the base of a long‐term, progressive trend towards better‐drained alluvial conditions into the Early Triassic. Indeed, the floral turnover was immediately followed by a flooding event in basinal depocentres, following which fluvial systems similar to those active prior to the end‐Permian Extinction were re‐established. The age of the floral extinction is constrained to 252.54 ± 0.08 to 252.10 ± 0.06 Ma by a suite of new Chemical Abrasion Isotope Dilution Thermal Ionization Mass Spectrometry U‐Pb ages on zircon grains. Another new age indicates that the return to fluvial sedimentation similar to that before the end‐Permian Extinction occurred in the basal Triassic (prior to 251.51 ± 0.14 Ma). The character of the surface separating coal‐bearing pre‐end‐Permian Extinction from coal‐barren post‐end‐Permian Extinction strata varies across the basins. In basin‐central locations, the contact varies from disconformable, where a fluvial channel body has cut down to the level of the top coal, to conformable where the top coal is overlain by mudrocks and interbedded sandstone–siltstone facies. In basin‐marginal locations, however, the contact is a pronounced erosional disconformity with coarse‐grained alluvial facies overlying older Permian rocks. There is no evidence that the contact is everywhere a disconformity or unconformity.     

西藏恰功铁矿岩浆演化序列及斑岩出溶流体特征

冈底斯成矿带是碰撞造山过程形成的最重要的成矿带,恰功矽卡岩铁(铜)矿床即位于冈底斯成矿带中部.本文在详细的野外地质填图和室内研究基础上确定了恰功铁矿与成矿有关的斑岩体为二长花岗斑岩,锆石的U-Pb定年结果为68.8±2.2 Ma,明显早于冈底斯东部与后碰撞伸展有关的斑岩型矿床和主碰撞期形成的矽卡岩型矿床,其应代表了冈底斯一次尚未被充分认识到的成矿事件.通过对成矿斑岩的岩石学、岩石化学、岩浆出溶流体的包裹体岩相学、显微测温分析及包裹体成分的LRM、LA-ICP-MS和PIXE分析,本文探讨了与该矽卡岩矿床有关的斑岩的岩浆起源、斑岩侵位机制及出溶流体特征.结果表明,成矿斑岩为矿区最早的侵入岩单元,具有壳幔源混源特征,其常量元素组成与冈底斯东部斑岩铜矿带的埃达克质岩相近,但稀土和微量元素组成与东部斑岩明显不同,为地幔物质上涌并诱发角闪岩相下地壳熔融的产物,岩体侵位深度大(>7 km)、剥蚀程度高.早期岩浆出溶的流体为高温、高压、高盐度流体,其中富含Fe、Pb、Zn、Cu等成矿金属,与世界其他斑岩铜矿床相比,相对富铁、铅而贫铜.流体的沸腾作用发生于钾硅化阶段,形成了一套富气、高盐、高固相和气液包裹体组合,不同于早期出溶流体的包裹体组合.从岩浆起源和出溶流体性质可以看出,该斑岩具有形成与斑岩有关的铁铅多金属矿床的成矿潜力,但从该矿区地表出露的蚀变和包裹体测压结果可以看出,该斑岩体目前剥蚀深度较大,对斑岩型矿床保存不利,对该斑岩体及与成矿关系的认识对理解该区内的矿床成因和指导区域找矿具有重要的指示意义.