Stable isotope study of the Archaean rocks of the Vredefort impact structure,central Kaapvaal Craton,South Africa

The Vredefort dome in the Kaapvaal Craton was formed as a result of the impact of a large meteorite at 2.02 Ga. The central core of Archaean granitic basement rocks is surrounded by a collar of uplifted and overturned strata of the Witwatersrand Supergroup, exposing a substantial depth section of the Archaean crust. Orthogneisses of the core show little variation in whole-rock δ ¹⁸O value, with the majority being between 8 and 10‰, with a mean of 9.2‰ (n = 35). Quartz and feldspar have per mil differences that are consistent with O-isotope equilibrium at high temperatures, suggesting minimal interaction with fluids during subsequent cooling. These data refute previous suggestions that the Outer Granite Gneiss (OGG) and Inlandsee Leucogranofels (ILG) of the core represent middle and lower crust, respectively. Granulite-facies greenstone remnants from the ILG have δ ¹⁸O values that are on average 1.5‰ higher than the ILG host rocks and are unlikely, therefore, to represent the residuum from the partial melting event that formed the host rock. Witwatersrand Supergroup sedimentary rocks of the collar, which were metamorphosed at greenschist-to amphibolite-facies conditions, generally have lower δ ¹⁸O values than the core rocks with a mean value for metapelites of 7.7‰ (n = 45). Overall, through an ∼20 km thick section of crust, there is a general increase in whole-rock δ ¹⁸O value with increasing depth. This is the reverse of what is normal in the crust, largely because the collar rocks have δ ¹⁸O values that are unusually low in comparison with metamorphosed sedimentary rocks worldwide. The collar rocks have δD values ranging from −35 to −115‰ (average −62‰, n = 29), which are consistent with interaction with water of meteoric origin, having a δD of about −25 to −45‰. We suggest that fluid movement through the collar rocks was enhanced by impact-induced secondary permeability in the dome structure. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Modeling and observations of high-frequency flow variability and internal waves at a Caribbean reef spawning aggregation site

The characteristics and forcing mechanisms of high-frequency flow variations (periods of minutes to days) were investigated near Gladden Spit, a reef promontory off the coast of Belize. Direct field observations and a high-resolution (50-m grid size) numerical ocean model are used to describe the flow variations that impact the initial dispersion of eggs and larvae from this site, which serves as a spawning aggregation site for many species of reef fishes. Idealized sensitivity model experiments isolate the role of various processes, such as internal waves, wind, tides, and large-scale flow variations. The acute horizontal curvature and steep topography of the reef intensify the flow, create small-scale convergence and divergence zones, and excite high-frequency oscillations and internal waves. Although the tides in this area are relatively small (∼10-cm amplitude), the model simulations show that tides can excite significant high-frequency flow variations near the reef, which suggests that the preference of fish to aggregate and spawn in the days following the time of full moon may not be coincidental. Even small variations in remote flows (2–5 cm s⁻¹) due to say, meso-scale eddies, are enough to excite near-reef oscillations. Model simulations and the observations further suggest that the spawning site at the tip of the reef provides initial strong dispersion for eggs, but then the combined influence of the along-isobath flow and the westward wind will transport the eggs and larvae downstream of Gladden Spit toward less turbulent region, which may contribute to enhanced larval survival.     

Papua New Guinea Highlands: palaeomagnetic constraints on terrane tectonics

Oblique convergence since the Early Cenozoic between the northward-moving Australian plate, westward-moving Pacific plate and almost stationary Eurasian plate has created a world-ranking tectonic zone in the eastern Indonesia–New Guinea–Southwest Pacific region (Tonga–Sulawesi megashear) that is notorious for its complex mix of tectonic styles and terrane juxtapositions. Unlike an ancient analog—the Mesozoic–Cenozoic Cordillera of North America—palaeomagnetic constraints on terrane motions in the zone are few. To improve the framework of quantitative control on such motions and therefore our understanding of the development of the zone, results of a palaeomagnetic study in the Highlands region of Papua New Guinea (PNG), in the southern part of the New Guinea Orogen, are reported. The study yields new insights into terrane tectonics along the Australian craton's active northern margin and confirms the complexity of block rotations to be expected at the local scale in tectonically intricate zones. The study is based on more than 500 samples (21 localities) collected from an interior and an exterior zone of New Guinea's central cordillera. The two zones are separated by the Tahin and Stolle–Lagaip–Kaugel Fault zones and collectively represent the para-autochthonous northern margin of the Australian craton. Samples from the interior zone, which in the study area comprises a cratonic spur of uncertain—probably displaced—origin, come from Triassic to Miocene sediments and subordinate volcanics of the Kubor Anticline, Jimi Terrane, and Yaveufa Syncline (16 localities) in the central and eastern Highlands. Samples from the exterior zone, which represent a basement-involved, Pliocene foreland fold-and-thrust belt, come from Middle Eocene to Middle Miocene carbonates and clastics (five localities) in the southern Highlands of the Papuan Fold Belt. Results permit us to constrain the tectonic evolution of the two zones palaeomagnetically. Using mainly thermal demagnetization techniques, three main magnetic components have been identified in the collection: (1) a recent field overprint of both normal and reverse polarity; (2) a pervasive overprint of mainly normal polarity that originated during extensive Middle to Late Miocene intrusive activity in the central cordillera; and (3) a primary component which has been identified in only 7 of the 21 localities (5 of 11 stratigraphic units represented in the collection). All components show patterns of rotation that are consistent within the zones, but differ between them. In the interior zone (central and eastern Highlands), large-scale counterclockwise rotations of between 30°+ and 100°+ have been established throughout the Kubor Anticline and Jimi Terrane, with some clockwise rotation present in the southern part of the Yaveufa Syncline. In contrast, in the Mendi area of the exterior zone (southern Highlands), clockwise rotations of between 30°+ and 50°+ can be recognized. These contrasting rotation patterns across the Tahin and Stolle–Lagaip–Kaugel Fault zones indicate decoupling of the two tectonic zones, probably along basement-involved faults. The clockwise rotations in the southern Highlands of the Papuan Fold Belt are to be expected from its structural grain, and are probably governed by regional basement faults and transverse lineaments. In contrast, the pattern of counterclockwise rotations in the Kubor Anticline–Jimi Terrane cratonic spur of the central and eastern Highlands was unexpected. The pattern is interpreted to result from non-rigid rotation of continental terranes as they were transported westward across the northeastern margin of the Australian craton. This margin became reorganised after the Middle Miocene, when the steadily northward-advancing Australian craton impinged into the westward-moving Pacific plate/buffer-plate system. Transpressional reorganisation under the influence of the sinistral Tonga–Sulawesi megashear became enhanced with Mio-Pliocene docking, and subsequent southward overthrusting, of the Finisterre Terrane onto the northeastern margin of the Australian craton.     

Onshore and offshore seismic and lithostratigraphic analysis of a deeply incised Quaternary buried valley system in the Northern Netherlands

High-resolution seismic data (onshore and offshore), geophysical borehole data as well as detailed lithofacies from airlift boreholes were acquired in northern Netherlands on and around the island of Ameland. Marine and land seismic data combined with information from land boreholes have been explored with the objective of providing a sedimentary model. Qualitative seismic facies analysis of the valley fill commonly shows a thin unit with high amplitude reflectors at the base. Thick units of variable seismic facies (transparent to high amplitude) occur higher up in the sequence. Onlap is common at mid–upper levels within the sandy valley fill (with clay in mm layering), and a transparent seismic facies, corresponding to firm clays, is common at the top. Almost all lithological unit boundaries recognised within core parameters correspond with seismic unconformities within error margins. Subunits contain multiple cyclical trends in gamma ray and grain size. Cyclical trends show lower order fluctuations in gamma radiation on a scale of less than 1 m. Gamma-ray pattern variability between units, e.g. in general coarsening-up or fining-up units, suggests migration of subaqueous outwash fans or ice margin fluctuations. Seismic results could support a headward excavation and backfilling process suggested by Praeg [Morphology, stratigraphy and genesis of buried Elsterian tunnel valleys in the southern North Sea basin [PhD thesis]: University of Edinburgh, 207 pp.; Journal of Applied Geophysics, (this volume)] as being responsible for the formation of buried valleys. On a lithological scale, a more complicated, detailed and cyclical pattern arises. Catastrophic processes are considered unlikely as being responsible for the infill sequence because of the observed small-scale facies variability and because of the presence of diamicton layers. Diamicton layers at the base of basal unconformities as well as higher in sequence could suggest subglacial deformation by grounded ice before and during the valley-fill process.     

Monitoring litter interception of rainfall using leaf wetness sensor under controlled and field conditions

Leaf litter interception of water is an integral component of the water budget for some vegetated ecosystems. However, loss of rainfall to litter receives considerably less attention than canopy interception due to lack of suitable sensors to measure changes in litter water content. In this study, a commercially available leaf wetness sensor was calibrated to the gravimetric water content of eastern redcedar (Juniperus virginiana ) litter and used to estimate litter interception in a subhumid eastern redcedar woodland in north‐central Oklahoma. Under controlled laboratory conditions, a strong positive correlation between the leaf wetness sensor output voltage (mV) and measured gravimetric litter water content (? _g) was determined: ? _g = (.0009 × mV²) ? (0.14 × mV) ? 11.41 (R ² = .94, p  < .0001). This relationship was validated with field sampling and the output voltage (mV) accounted for 48% of the observed variance in the measured water content. The maximum and minimum interception storage capacity ranged between 1.16 and 12.04 and 1.12 and 9.62 mm, respectively. The maximum and minimum amount of intercepted rain was positively correlated to rainfall amount and intensity. The continuous field measurements demonstrated that eastern redcedar litter intercepted approximately 8% of the gross rainfall that fell between December 16, 2014 and May 31, 2015. Therefore, rainfall loss to litter can constitute a substantial component of the annual water budget. Long‐term in situ measurement of litter interception loss is necessary to gain a better estimate of water availability for streamflow and recharge. This is critical to manage water resources in the south‐central Great Plains, USA where grasslands are rapidly being transformed to woodland or woody dominated savanna.     

Gaseous mercury emissions from urban surfaces: Controls and spatiotemporal trends

The spatial and temporal variability of Hg emissions from urban paved surfaces was assessed through repeated measurements under varying environmental conditions at six sample sites in Toronto, Ontario, Canada. The results show significant spatial variability of the Hg emissions with median values ranging from below detection limit to 5.2 ng/m²/h. Two of the sites consistently had higher Hg emissions (on several occasions >20 ng/m²/h) than the other 4, which were equivalently low (maximum emission: 2.1 ng/m²/h). A surrogate measure of the pavement Hg concentrations was obtained during each day of sampling through the collection of street dust. The median street dust concentration also showed significant spatial variability (ranging from 9.6 to 44.5 ng/g). Regression analysis showed that the spatial variability of the Hg emissions was significantly related to the street dust concentrations. Controlled experiments using Hg amended street dust confirmed the relationship between Hg surface concentration and emission magnitude. Within a given sample site, Hg emissions varied temporally and multiple regression analysis showed that within-site variability was significantly influenced by changes in solar radiation with only a minor effect from surface temperature. Controlled experiments using shade cloths confirmed that solar radiation can have a large influence on the magnitude of Hg emissions within a given site. The emissions measured in Toronto were contextualized through comparison sampling in Austin, Texas. The Hg emissions measured in Austin were within the range detected in Toronto and also showed significant correlation with Hg street dust concentrations between sites. To provide a holistic assessment of Hg emissions from urban environments, samples were also collected from other common urban surfaces (soil, roofs, and windows). Soils consistently had higher emissions than all the other surfaces (7.3 ng/m²/h, n = 39).     

Efstadalsvatn – a multi-proxy study of a Holocene lacustrine sequence from NW Iceland

Multi-proxy data, both lithostratigraphic and biostratigraphic, are presented from Efstadalsvatn, a lake in NW Iceland. The sequence covers the period 10,000 to 3500 ¹⁴C yr B.P. The biostratgraphic data include the first Icelandic chironomid-based reconstruction of Holocene mean July air temperatures, using a Norwegian training set in the absence of modern Icelandic data. The results show that deglaciation and ecosystem development probably began before 10,000 ¹⁴C yr B.P. and that July temperatures were around 4°C at ca. 9500 ¹⁴C yr B.P. Temperatures then rose to ca. 8°C at the time of the deposition of the Saksunarvatn tephra (9100 ¹⁴C yr B.P.), reaching ca. 10°C by 8500 ¹⁴C yr B.P., high enough for the growth of tree birch, although successful birch colonisation did not take place until 6750 ¹⁴C yr B.P. There is some evidence for cooling immediately preceding 9100 ¹⁴C yr B.P. There is little firm biostratigraphic evidence for the 8200 cal. B.P. event, although this may be due to a relatively low resolution pollen sampling interval, but there are changes at this time in the total carbon (TC) and mass susceptibility (MS) data. Optimal temperatures and relative vegetation stability may have occurred between 8000–6100 ¹⁴C yr B.P. but the chironomid assemblages indicate higher temperatures after 5000 ¹⁴C yr B.P. This latter interpretation may, however, reflect delayed colonisation of thermophilous taxa and requires further investigation. There is evidence in the lithostratigraphy for greater local terrestrial instability after 6100 ¹⁴C yr B.P. but it seems unlikely that this led to the redevelopment of ice in the catchment. The biostratigraphic records appear to show a degree of resistence to climate forcing throughout the early and middle Holocene. The new chironomid-based temperature reconstruction needs to be refined by further studies in Iceland, particularly the development of an Icelandic training set, but has already demonstrated the problems of paleoclimatic interpretations based on pollen and/or macrofossil evidence alone.