琼东南盆地华光凹陷天然气水合物稳定带厚度的影响因素

为了探讨琼东南盆地华光凹陷海底天然气水合物稳定带的分布规律,定量研究了静水压力、底水温度、地温梯度和气源组分对水合物稳定带的影响程度。在此基础上,分析了华光凹陷现今甲烷水合物稳定带的厚度分布。最后,综合各因素的历史演化过程,初步探讨了华光凹陷1.05 Ma BP以来天然气水合物稳定带的演化。结果表明:(1)气源组分和海底温度的变化对研究区内水合物稳定带的影响较大;水合物稳定带厚度与海底温度呈良好的线性负相关性。(2)水深超过600 m的海域具备形成天然气水合物的温压条件;超过600 m水深的海域水合物稳定带厚度大部分超过 100 m,其中西北部稳定带的最大厚度超过300 m,是有利的水合物勘探区。(3)华光凹陷1.05 Ma BP以来天然气水合物稳定带厚度经历了快速增厚–窄幅变化–快速减薄和恢复的过程。麻坑群与水合物稳定变化敏感区在空间上具有较好的叠合关系。结合前人的研究成果,推测其形成与天然气水合物的分解释放有关。     

Spatial distribution and behavior of dissolved selenium speciation in the South China Sea and Malacca Straits during spring inter-monsoon period

Selenium(Se) has been recognized as a key trace element that is associated with growth of primary producers in oceans. During March and May 2018, surface water(67 samples) was collected and measured by HG-ICP-MS to investigate the distribution and behavior of selenite [Se(IV)], selenate [Se(VI)] and dissolved organic selenides(DOSe) concentrations in the Zhujiang River Estuary(ZRE), South China Sea(SCS) and Malacca Straits(MS). It showed that Se(IV)(0.14–3.44 nmol/L) was the dominant chemical species in the ZRE, related to intensive manufacture in the watershed; while the major species shifted to DOSe(0.05–0.79 nmol/L) in the MS, associated with the wide coverage of peatland and intensive agriculture activities in the Malaysian Peninsula. The SCS was identified as the northern and southern sections(NSCS and SSCS) based on the variations of surface circulation.The insignificant variation of Se(IV) in the NSCS and SSCS was obtained in March, potentially resulting from the high chemical activity and related preferential assimilation by phytoplankton communities. Contrastively, the lower DOSe concentrations in the SSCS likely resulted from higher primary production and utilization during March. During May, the concentration of Se(IV) remained low in the NSCS and SSCS, while DOSe concentrations increased notably in the SSCS, likely due to the impact of terrestrial inputs from surface current reversal and subsequent accumulation. On a global scale, DOSe is the dominant Se species in tropical oceans, while Se(IV) and Se(VI) are major fractions in high-latitude oceans, resulting from changes in predominated phytoplankton and related biological assimilation.     

壳聚糖/纳米铜复合微球的制备及其对刚果红染料的脱色性能

以壳聚糖和CuCl₂·2H₂O为原料,分别采用直接负载法和吸附法成功制备了壳聚糖/纳米铜复合微球,运用傅里叶变换红外光谱(FT-IR)、X-射线衍射(XDR)和扫描电镜(SEM)对催化剂结构进行了表征。以刚果红(CR)染料为目标污染物,评价了催化剂的制备方法、制备条件及氢转移催化反应条件对其催化性能的影响。结果表明,由直接负载法(CS/CuNPs)和吸附法(CS/CuNPs-X)制备的壳聚糖/纳米铜复合微球在CR染料浓度为100 mg/L,催化剂投加量为0.05 g,供氢体浓度为0.05 mol/L的氢转移催化反应条件下,催化反应进行180和60 min时CR脱色率可分别达95.8%和96.8%。CS/CuNPs-X比CS/CuNPs表现了更高的对CR氢转移催化反应的催化速率。两种催化剂催化还原CR染料的反应均符合准一级动力学模型。在连续循环使用10次后,CS/CuNPs和CS/CuNPs-X对CR的脱色率分别为93.9%和89.4%,表明催化剂具有良好的重复使用性能。     

Removal rate and releases of polybrominated diphenyl ethers in two wastewater treatment plants,Korea

Wastewater treatment plants (WWTPs) play an important role in minimizing the release of many pollutants into the environment. Nineteen congeners in two WWTPs in Korea were determined to investigate the occurrence and fate of polybrominated diphenyl ethers (PBDEs) during wastewater treatment processes. The concentration of total PBDEs was 69.6 and 183 ng/L in influent, which declined to 1.59 and 2.34 ng/L in the final effluent, respectively (Tongyeong and Jinhae WWTPs). PBDEs were found to exist mostly in the particulate phase of wastewater, which rendered sedimentation efficient for the removal of PBDEs. BDE-209 was the predominant congener in the influent and sludge. Most of the PBDEs entering the WWTPs presumably ended up in the sludge, with < 2% being discharged with the final effluent. According to the mass loading estimation, every day 2.55–9.29 g PBDEs entered the two WWTPs, 2.8–10.4 g were disposed to landfill sites in sludge form and 0.06–0.12 g were discharged to the surrounding water through final effluent, respectively. Preliminary results indicated that the ecological risk to organisms in soil exposed to PBDEs through the usage of sludge application to agricultural land was relatively low. To our knowledge, this study is the first to report on the removal efficiency of PBDEs in a WWTP in Korea.     

A 2D numerical study of explosive events in the solar atmosphere

Two-dimensional (2D) compressible magnetohydrodynamic simulations are performed to explore the idea that the asymmetric reconnection between newly emerging intranetwork magnetic field flux and pre-existing network flux causes the explosive events in the solar atmosphere. The dependence of the reconnection rate as a function of time on the density and temperature of the emerging flux are investigated. For a Lundquist number of L _u= 5000 we find that the tearing mode instability can lead to the formation and growth of small magnetic islands. Depending on the temperature and density ratio of the emerging plasma, the magnetic island can be lifted upward and convected out of the top boundary, or is suppressed downward and convected out of the top boundary, or is suppressed downward nad submerged below the bottom boundary. The motions of the magnetic islands with different direction are accompanied respectively with upward or downward high velocity flow which might be associated with the red- and blue-shifted components detected in the explosive events.     

三江平原典型农垦区水土质量综合评价体系研究

本文基于对三江平原农垦区水土环境现状的分析,从地下水质量、土地质量2个方面入手构建了三江平原水土综合评价指标体系,筛选出地下水资源补给强度、土壤养分、土壤环境等16个三级指标,采用层次分析法计算了各个指标的权重,同时基于统计资料和前人研究数据,运用构建指标体系对蛤蟆通河灌区水土质量进行评价.结果表明,蛤蟆通河灌区有86.2%的耕地水土质量属于良好级别以上,只有在部分地下水质量较差地区,水土质量处于中等水平;与传统的土地质量调查评价相比,研究区内三等土地有明显增加,显示出地下水质量已经对当地农业生产产生了一定的制约性.     

层状侵入体的韵律层理成因

层状侵入体的一个典型的特征是具有隐导理和韵律层理，分析比较了前人提出的韵律层理形成的各种机制并结合对攀枝花层状侵入体的研究认为，层状侵入体的韵律层理的形成与成岩的压实作用关系密切，细粒韵律层理是由于颗粒大小的微小差别或矿物成分含量的逐渐增加和重复的再平衡所致，矿物成分含量的逐步增加和重复是通过在类似于奥斯特瓦尔德成熟的条件下循环溶解和晶体生长形成的，在影响层理形成的多种因素中，以对流作用，密度，粘度及岩浆房的几何形状等因素的研究较为详细，各研究者也存在较大分歧。     

太原地震台记录的四川汶川地震震相分析

四川汶川系列地震距太原基准地震台约1000km,介于近震与远震之间,震相特殊,识别困难。本文通过对汶川主、余震和四川其他地区远震波形的对照,及对主要震相周期、幅度及波形特点的分析,认为PN、SG两个震相是太原地震台记录四川汶川地震的主要定位震相。     

基于相关系数匹配的混合像元分解算法

遥感影像中的混合像元不仅影响地物识别和分类的精度,而且已成为遥感科学向定量化发展的主要障碍.为此,人们已经提出了多种混合像元分解算法,其中应用最为广泛的是最小二乘法.该方法虽然具有意义明确、简单易行等特点,但也易受局部噪声、大气效应、环境辐射等因素的影响.本文将混合像元分解问题归结为一个基于光谱匹配的非线性最优化问题,并针对最小二乘法的不足提出了一种新的基于相关系数匹配(spectral correlation matching, SCM)的混合像元分解技术.通过在北京市北三环及其以北区域内案例的研究表明:在城市区域内,利用图像选取终端端元的办法,基于相关系数匹配的混合像元分解算法的总体精度高于带全约束的最小二乘法(LS)的分解结果.对比分析表明:在目标光谱的绝对值整体放大或缩小而光谱形状得到了很好的保持、及局部噪声使得光谱值显著变化但光谱形状得到了一定程度保持时,基于光谱形状的相关系数法可以得到比基于光谱绝对值的最小二乘法精度更高的分解结果.     

电子信息化技术在地方资源介绍方面的应用

本文通过对灵宝市矿产资源电子信息化实施的工程实例 ,详细阐述了这种技术方法在介绍地方部门资源方面的优势 ,以及运用它所必须的软件、硬件环境等和实施这种技术的方法。