Limnic Responses to Increased Effective Humidity during the 8200 cal. yr BP Cooling Event in Southern Sweden

Highly resolved sediment stratigraphic and stable isotope records from a lake in south-central Sweden give evidence of relatively humid summers during the wide-spread cold event at c. 8200 cal. BP. A transient lake-level rise led to increased catchment erosion followed by enhanced phytoplankton production and disturbance of the Chara-dominated algal community. An associated increase in the deposition of organic material resulted in hypolimnetic oxygen deficit and methane formation as inferred from elevated sulphur content of the sediments and strong depletion in ¹³C of bulk organic material. In combination with dry and cold winter conditions as revealed by other proxy records, these data suggest the development of a strongly seasonal climate in northwestern Europe in response to altered atmospheric circulation at this stage. Enhanced zonal circulation with frequent cyclonic activity and increased effective humidity probably characterized the summer climate of southern and central Scandinavia, consistent with conditions inferred for continental Europe. In contrast, the winter climate was dominated by blocking high-pressure circulation, giving rise to cold and dry conditions.     

Post‐orogenic evolution of the southern Pyrenees: constraints from inverse thermo‐kinematic modelling of low‐temperature thermochronology data

The late‐stage evolution of the southern central Pyrenees has been well documented but controversies remain concerning potential Neogene acceleration of exhumation rates and the influence of tectonic and/or climatic processes. A popular model suggests that the Pyrenees and their southern foreland were buried below a thick succession of conglomerates during the Oligocene, when the basin was endorheic. However, both the amount of post‐orogenic fill and the timing of re‐excavation remain controversial. We address this question by revisiting extensive thermochronological datasets of the Axial Zone. We use an inverse approach that couples the thermo‐kinematic model Pecube and the Neighbourhood inversion algorithm to constrain the history of exhumation and topographic changes since 40 Ma. By comparison with independent geological data, we identified a most probable scenario involving rapid exhumation (>2.5 km Myr^?1) between 37 and 30 Ma followed by a strong decrease to very slow rates (0.02 km Myr^?1) that remain constant until the present. Therefore, the inversion does not require a previously inferred Pliocene acceleration in regional exhumation rates. A clear topographic signal emerges, however: the topography has to be infilled by conglomerates to an elevation of 2.6 km between 40 and 29 Ma and then to remain stable until ca. 9 Ma. We interpret the last stage of the topographic history as recording major incision of the southern Pyrenean wedge, due to the Ebro basin connection to the Mediterranean, well before previously suggested Messinian ages. These results thus demonstrate temporally varying controls of different processes on exhumation: rapid rock uplift in an active orogen during late Eocene, whereas base‐level changes in the foreland basin control the post‐orogenic evolution of topography and exhumation in the central Pyrenees. In contrast, climate changes appear to play a lesser role in the post‐orogenic topographic and erosional evolution of this mountain belt.     

Relating remotely sensed forest damage data to wind data: storms Lothar (1999) and Vivian (1990) in Switzerland

This study compares the surface wind speed and forest damage data of two exceptionally severe winter storms, Vivian 1990 and Lothar 1999. The study area comprises the region that suffered damage in Switzerland. The wind speed data were derived from simulations of MeteoSwiss (Federal Office of Meteorology and Climatology), measurements during the storm periods and expert analyses of the data. The remotely sensed forest damage data were provided by the Federal Office for the Environment and the forest cover data by Swiss Federal Statistical Office. We compared data on the peak gust and maximum average wind speed, with data on the spatially related forest area and forest damage area, and found some clear differences in the correlations between the different wind data and forest damage. Our results point generally to the damage-causing role of near-surface gusts at maximum wind speeds during the storm. These tended to be spatially distributed on a fine scale. In only a few cases were the results statistically significant. However, these results could probably be improved with better wind data. For example, gust measurements spatially closer to forests or simulations of gusts at maximum wind speed could be produced with a spatially higher resolution.     

An investigation of the controls on Irish precipitation δ18O values on monthly and event timescales

This two-year study investigates the relative influence of meteorological variables (precipitation amount and temperature), atmospheric circulation, air mass history, and moisture source region on Irish precipitation oxygen isotopes (δ¹⁸O_p) on event and monthly timescales. Single predictor correlations reveal that on the event scale, 20% of δ¹⁸O_p variability is attributable to the amount effect and 7% to the temperature effect while on the monthly timescale the North Atlantic Oscillation accounts for up to 20% of δ¹⁸O_p variability and the amount and temperature effects are not significant. In comparison, multivariate linear regression reveals that the interaction of temperature and precipitation amount explains up to 40% of δ¹⁸O_p variance at event and monthly timescales. Five-day kinematic back trajectories suggest that the amount-weighted mean δ¹⁸O_p value of southerly- and northerly-derived events are lower by 2‰ relative to events derived from the west. Because air mass history and atmospheric circulation appear to influence δ¹⁸O_p in Ireland, Irish paleo-δ¹⁸O_p proxy records are best interpreted as reflecting a combination of parameters, not just paleotemperature or paleorainfall.     

Optical attenuation in fog at a wavelength of 1.55 micrometers

As part of a series of studies on laser propagation for terrestrial free space optical (FSO) telecommunications or laser telecommunications, an experiment was conducted to determine the relationship between visibility in fog and optical attenuation (dB/km) at a laser wavelength of 1.55 μm. In the telecommunications industry, a semi-empirical equation, called the Kruse formula [Kruse, P.W., McGlauchlin, L., McQuistan, R.B., 1962. Elements of infrared technology: generation, transmission, and detection. John Wiley and Sons, New York] is typically used to calculate expected attenuation for a given meteorological visibility. The Kruse formula, however, was developed to relate meteorological visibility to optical attenuation over wavelengths from the visible to the near infrared (IR), and for dust and small particle aerosols with dimensions much smaller than the wavelength. Typically, suspended small aerosols have diameters that average about 0.1 μm while fog droplets have diameters that range upward from 2.5 μm with mean diameters that exceed 10 μm in some fogs. Therefore, application of the Kruse formula to attenuation in fog is not appropriate since fogs consist mainly of particles much larger than the laser wavelength. As part of the experiment, a transmissometer with an 85-m baseline and a dynamic range of 60 dB operated for thirteen months in an area prone to radiation fog. A commercial visibility sensor, similar to those used at airports, was located near the middle of the optical path of the transmissometer and operated over the same period. The largest attenuation measured at this site was just over 300 dB/km, corresponding to a visibility of 32 m. The key finding of the study is that the generally accepted Kruse formula relating visibility and optical attenuation may be too pessimistic at low visibilities, and actual attenuation values for a given visibility may be more than 20% lower than previously thought. At visibilities exceeding about 650 m, the Kruse formula gives a good estimate of optical attenuation.     

Solubility of Pt in sulphide mattes: Implications for the genesis of PGE-rich horizons in layered intrusions

The partitioning of Pt in sulphide melt (matte) has been studied as a function of fS₂ and fO₂ at 1200 and 1300 °C. The results show that the solubility of Pt in mattes increases strongly with increasing fS₂ and decreases weakly with increasing fO₂. The increase in Pt solubility with increasing fS₂ is attributed to Pt dissolving in the melt as a sulphide species and the weak inverse dependence of Pt solubility on fO₂ to the diluting effect of increasing O in the melt at high fO₂. These results, coupled with measurements of Pt solubility in silicate melts taken from the literature, allow the calculation of Pt matte/silicate-melt partition coefficients () for a range of conditions pertinent to the formation of Pt-rich horizons in layered intrusions. The calculated values range between 10⁷ and 10¹¹, depending on fO₂ and fS₂, several orders of magnitude higher than previously published values. Our preferred value for for conditions appropriate to the Merensky Reef is 10⁷ and for the Stillwater Pt-rich horizon 10⁸. The new results are consistent with the magmatic hypothesis for Pt-rich horizons in layered intrusions.     

Rate of growth of the preserved North American continental crust: Evidence from Hf and O isotopes in Mississippi detrital zircons

Detrital zircons from the Mississippi River have been analyzed for U-Th-Pb, Lu-Hf and O isotopes to constrain the rate of growth of the preserved North American continental crust. One hundred and forty two concordant zircon U/Pb dates on grains mounted in epoxy, obtained by Excimer laser ablation ICP-MS method, resolved six major periods of zircon crystallization: 0-0.25, 0.3-0.6, 0.95-1.25, 1.3-1.5, 1.65-1.95 and 2.5-3.0 Ga. These age ranges match the ages of the recognized lithotectonic units of the North American continent in the hinterland of the Mississippi River. Ninety-six zircons mounted on tape, which show no age zonation and were within 7.5% of concordance, were selected to represent the six U/Pb age time intervals and analyzed for Lu-Hf and O isotope by laser ablation MC-ICP-MS and SHRIMP II, respectively. The δ¹⁸O values of the zircons show a small step increase in the maximum δ¹⁸O values at the Archean-Proterozoic boundary from 7.5‰ in the Archean to 9.5‰, and rarely 13‰, in the Proterozoic and Phanerozoic. However, the average value of δ¹⁸O in zircons changes little with time, showing that the increase in the maximum δ¹⁸O values between 2.5 and 2.0 Ga, which can be attributed to an increase in the sediment content of the source regions of younger granitoids, is largely balanced by an increase in zircons with anomalously low δ¹⁸O, which can be attributed to hydrothermally altered crust in the granitoid source region.εHf_i values for the zircons range from 13.1 to −26.9. Zircons derived from juvenile crust, which we define as having mantle δ¹⁸O (4.5-6.5‰) and lying within error of the Hf depleted mantle growth curve, are rare or absent in the Mississippi basin. The overwhelming majority of zircons crystallized from melted pre-existing continental crust, or mantle-derived magmas that were contaminated by continental crust. The average time difference between primitive crust formation and remelting for each of the recognized lithotectonic time intervals, which is defined as crustal incubation time in this study, is 890 ± 460 Myr. There is also a suggestion that the crustal incubation time increases with decreasing age in the Mississippi basin, which is consistent with the declining role of radioactive heat production in the lower crust with time.The average Hf model age (1.94 Ga), weighted by fraction of zircons in the river load is in reasonable agreement with the Nd model age (1.7 Ga) for the Mississippi River. However, if the zircons are weighted by the area of North America covered by the six recognized periods of zircon crystallization the average model age is 2.35 Ga, which compares favorably with an area weighted Nd model age of 2.36 Ga. Our preferred approach is to use the measured O isotope values to constrain variations in the ¹⁷⁶Lu/¹⁷⁷Hf ratio of the granitic source region from which the zircons crystallized, making the assumption that zircons with mantle-like O isotopic ratios have higher ¹⁷⁶Lu/¹⁷⁷Hf than zircons with higher O isotope values. This method gives an average Hf model age of 2.53 Ga, which is 180 Myr older than the constant ¹⁷⁶Lu/¹⁷⁷Hf calculation.The area weighted zircon Hf model ages show two distinct periods of crust formation for the North American continent, 1.6-2.2 and 2.9-3.4 Ga. At least 50% of the preserved North American continental crust was extracted from the mantle by 2.9 Ga and 90% by 1.6 Ga. Two similar periods of crustal growth are also recognized in Gondwana (Hawkesworth C. J. and Kemp A. I. S. (2006) Using hafnium and oxygen isotopes in zircons to unravel the record of crustal evolution. Chem. Geol.226, 144-162.), suggesting that these may be periods of global continental crustal growth. However, we stress that more data from other continents are required before the hypothesis of episodic global continental growth can be accepted with confidence.     

Diurnal variation of electron density in Saturn’s ionosphere: Model comparisons with Saturn Electrostatic Discharge (SED) observations

Using the Saturn Thermosphere Ionosphere Model (STIM), we present a study of the diurnal variation of electron density, with a focus on comparisons with peak electron densities (N_MAX) inferred from the low-frequency cutoff of radio emission due to lightning in the lower atmosphere, called Saturn Electrostatic Discharges (SEDs). It is demonstrated that photochemistry in Saturn’s ionosphere cannot reproduce the SED-inferred diurnal variation in N_MAX unless additional production and loss sources outside of the current best estimates are considered. Additional explanations of the SED-inferred diurnal variation of N_MAX are presented and analyzed, such as the possibility that the low-frequency cutoff seen in SEDs is due to the presence of sharp low-altitude layers of plasma, as frequently seen in radio occultation measurements. Finally, we outline the observational constraints that must be fulfilled by any candidate explanations of the SED-inferred diurnal variation of N_MAX.