Synthetic gedrite: a stable phase in the system MgO-Al2O3-SiO2-H2O (MASH) at 800 °C and 10 kbar water pressure, and the influence of FeNaCa impurities

Seeded, solid-media piston-cylinder runs of unusually long duration up to 31 days indicate growth or persistence of synthetic gedrite of the composition □Mg₆Al[AlSi₇O₂₂](OH)₂(=6:1:7), prepared from the purest chemicals available, at 10 kbar water pressure and 800 °C. Conversely, breakdown was observed at 11 kbar and 850 °C to aluminous enstatite, Al₂SiO₅, and a melt of the composition MgO·Al₂O₃·8SiO₂. Thus, pure gedrite free of iron, sodium, and calcium is likely to have only a small PT stability field in the MASH system, estimated as 10 ± 1 kbar, 800 ± 20 °C, even though metastable growth of gedrite can be observed over a larger PT range. A second starting material with the anhydrous composition 5MgO · 2Al₂O₃ · 6SiO₂ also yielded gedrite of the composition 6:1:7, together with more aluminous phases such as kyanite, corundum or sapphirine, thus suggesting that the end-member gedrite defined as □Mg₅Al₂[Al₂Si₆O₂₂](OH)₂(=5:2:6) by the IMA Commission on New Minerals and Mineral Names probably does not exist. With the use of this second starting material, which contains FeNaCa impurities, growth of 6:1:7-gedrite was observed over a still wider PT-range. Seeded runs indicate that the true stability field of such slightly impure 6:1:7-gedrites may also be larger than that of the pure MASH phase and extend at least to 15 kbar, 800 °C. There is, thus, a remarkable stabilization effect on the orthoamphibole structure by impurities amounting only to a total of less than one weight percent of oxides in the starting material. The gedrites synthesized are structurally well ordered amphiboles nearly free of chain multiplicity faults, as revealed by HRTEM. The X-ray diffraction work on the gedrites synthesized yielded the smallest cell volume yet reported for this phase. The small stability field of the pure MASH gedrite is intersected by the upper pressure stability limit of hydrous cordierite for excess-H₂O conditions, thus leading to complicated phase relations for both gedrite and cordierite involving the additional phases aluminous enstatite, talc, quartz, Al₂SiO₅, melt and perhaps boron-free kornerupine. Received: 29 July 1998 / Accepted: 7 January 1999     

The Western Bohemia/Vogtland Region in the Light of the Webnet Network

The local network of digital seismic stations WEBNET monitors the seismic activitv of practically the whole region of Western Bohemia/Vogtland swarms. The network consists of ten short-period stations and one very broadband station. The paper describes the configuration of the network, instrumental equipment and the basic parameters of the stations. The method of and formula for computing the local magnitudes from the WEBNET and KRASLICE seismograms are also given. Based on continuous WEBNET observations in the period 1995-1999, we were able to improve the model of temporal and spatial energy release in the region, the principal characteristics of which are summarised in the paper. Apart from direct P and S waves, the WEBNET seismograms also contain other significant P- and S-type waves, provisionally interpreted as reflected PxP, SxS and SxP waves. The fundamental characteristics of these waves are given in the paper, and tentative mechanisms of their origination are discussed. The large residua in the travel times of the P and S waves, and the discrepancies in the seismograms recorded at stations located east of the principal focal zone are pointed out.     

Refined Locations of The Swarm Earthquakes In The Nový Kostel Focal Zone and Spatial Distribution of The January 1997 Swarm In Western Bohemia,Czech Republic

In order to improve the accuracy of the spatial distribution of earthquake foci in the principal Novy Kostel focal zone, refined focal locations of about 1500 micro-earthquakes of the 1991 – 1997 period were determined using the relative Master-Event location method. To estimate the reduction in the scatter of located hypocentres, the results were compared with those obtained by routinely used FASTHYPO method and cluster analysis (the nearest-neighbour method) was applied to the located foci to evaluate the spatial distribution of the foci. Based on the results of refined location and of the cluster analysis, a concept of seismic energy release in space and time in the main focal zone was developed. Especially the January 1997 earthquake swarm was studied in detail: 946 events were located with the Master-Event location method, and the dimensions and geometry of focal clusters were determined. Type analysis was applied to waveforms to divide approximately 800 located events into eight multiplet groups to each of which a characteristic source mechanism was assigned. The spatial distribution of the foci as well as of the eight types of source mechanisms was revealed in this way and also the planes fitting the clusters of foci with two predominant source mechanisms were determined fairly well.     

A comparison of analytic and numerical results for a two-dimensional control model in electromagnetic induction – I. B-polarization calculations

Summary. A conducting slab of finite thickness divided into three segments of different conductivities and overlying a perfect conductor is proposed as a suitable two-dimensional 'control' model for testing the accuracy of the various numerical modelling programs that are available for calculating the fields induced in the Earth by an external, time-varying magnetic source. An analytic solution is obtained for this control model for the case of the magnetic field everywhere parallel to the conductivity boundaries ( B -polarization). Values of the field given by this solution for a particular set of model parameters are calculated at selected points on the surface and on a horizontal plane inside the conductor, and are tabulated to three figure accuracy for reference. They are used to check the accuracy of the results given by the finite difference program of Brewitt-Taylor & Weaver and the finite element program of Kisak & Silvester for the same model. Improved formulae for calculating the derived electric field components in B -polarization are first developed for incorporation in the finite difference program, and these give surface electric fields within 1 per cent of the analytic values, while all three field components inside the conductor are calculated to better than 96 per cent accuracy by the finite difference program. The results given by the finite element program are not quite so satisfactory. Errors somewhat greater than 10 per cent are present and although the program requires much less disk space it takes rather more CPU time to complete the calculations.     

Electromagnetic response of an ocean-coast model to E-polarization induction

summary . An ocean-coast model which consists of a uniformly conducting half-space screened by a perfectly conducting half-plane (the model ocean) is studied. On the land the electric field decreases continuously to zero as the coast is approached. The horizontal magnetic field component is found to vary rapidly, but remains finite; the vertical component on the other hand, increases to infinity at the coast. On the surface of the model ocean as well as on the sea floor, electric field and vertical magnetic field are both nil, but the horizontal magnetic field becomes singular as the seashore is approached. This horizontal magnetic field however, is different on the sea floor and at the ocean surface, because the integrated ocean current is finite, even growing to infinity as the shore is approached. The very large ocean currents near the shore act as an extremely long line antenna, which radiates far afield. This antenna feature explains the very long range of the ocean-coast effects observed under E -polarization induction, compared to the corresponding H -polarization effects where no such antenna-like feature occurs. A similarly large difference of ranges can be expected for all shallow structures with large lateral conductivity contrasts. The present study may therefore be of some interest in relation to geomagnetic depth soundings by the inductive and magnetotelluric methods, as well as in understanding the ocean-coast effect known for some time from records of coastal observatories.     

Connection between the upper ionospheric region of VLF chorus occurrence and the plasmapause position

Summary The occurrence zone of the VLF chorus in the upper ionosphere appears at L-shells lower than plasmapause position L_pp; with increasing geomagnetic activity the spatial dimension of the zone diminishes, its upper boundary being shifted in correspondence with the plasmapause position, the lower remaining practically without change(L=2.0÷2.5). Calculations of propagation paths have shown that the similarity of the VLF chorus spectrum at different upper-ionospheric latitudes as well as the large spatial dimension of the zone of observation can be explained as special features in the propagation of VLF waves from an equatorial source, starting in the vicinity of the plasmapause with different initial normal angles.

---

a umauu u ana amu L-, u L_pp (L_pp — nu nana); uu aum amumu nmam a am, nu aua am mmmuu uu nu nana, a u mam namuu u(L=2.0÷2.5). am mamu naam, m n¶rt;u nm a au uma u, ma a nmam ama a¶rt;u, m m mu anmau m amua umua, an amu nana, uu au au.

     

On the possibilities of observing ballistic plasma wave processes in the magnetosphere

Summary The conditions are studied under which ballistic effects of transmission of waves through opacity barriers can be observed in magnetospheric experiments on board satellites. The mechanism of this effect consists of the regeneration of the radiation beyond the barrier by resonance electrons, modulated by a quasimonochromatic wave incident and reflected from the barrier. Ballistic processes in continuously inhomogeneous plasma are studied. Detailed analysis has been carried out for a barrier with a parabolic density profile. Recommendations are presented as to experimental procedures in circumterrestrial space and data processing. The possibilities are studied of observing ballistic effects in the course of active space experiments with sources of intensive broadband turbulence such as beam of charged particles, injected into the magnetosphere.

---

¶rt;a u, nu m ¶rt; nmu num aum na m a¶rt;am aumuu m n¶rt;u a namu, au m mum auu uu a a au mau, n¶rt;uau auamu , na¶rt;a a a u maa m . am aumuu n na¶rt;¶rt; na. ma u n¶rt; ¶rt; aa naauu nu nmmu. a ¶rt;auu n n¶rt;u numa nmam u n am ¶rt;a. ¶rt;am m a¶rt;u aumuu m ¶rt; amu uu num umuau umu un mmmu, mauu, a nu a amu umu aum.