Magnetic properties and neutron diffraction study of two manganese sulfosalts: monoclinic MnSb<Subscript>2</Subscript>S<Subscript>4</Subscript> and benavidesite (MnPb<Subscript>4</Subscript>Sb<Subscript>6</Subscript>S<Subscript>14</Subscript>)

Mn²⁺Sb₂S₄, a monoclinic dimorph of clerite, and benavidesite (Mn²⁺Pb₄Sb₆S₁₄) show well-individualized single chains of manganese atoms in octahedral coordination. Their magnetic structures are presented and compared with those of iron derivatives, berthierite (Fe²⁺Sb₂S₄) and jamesonite (Fe²⁺Pb₄Sb₆S₁₄). Within chains, interactions are antiferromagnetic. Like berthierite, MnSb₂S₄ shows a spiral magnetic structure with an incommensurate 1D propagation vector [0, 0.369, 0], unchanged with temperature. In berthierite, the interactions between identical chains are antiferromagnetic, whereas in MnSb₂S₄ interactions between chains are ferromagnetic along c-axis. Below 6 K, jamesonite and benavidesite have commensurate magnetic structures with the same propagation vector [0.5, 0, 0]: jamesonite is a canted ferromagnet and iron magnetic moments are mainly oriented along the a-axis, whereas for benavidesite, no angle of canting is detected, and manganese magnetic moments are oriented along b-axis. Below 30 K, for both compounds, one-dimensional magnetic ordering or correlations are visible in the neutron diagrams and persist down to 1.4 K.     

粤中三水盆地构造-岩浆事件与矿集区形成

粤中三水盆地喜山期银矿化粗面质凝灰岩中锆石LA-ICP-MS U-Pb年龄90～3175 Ma.火山岩中锆石主要为其在形成及上升过程中捕获围岩中的碎屑锆石.火山岩中锆石U-Pb年龄表明粤中三水盆地基底含太古宙的残余错石(2489 Ma±30 Ma,3175 Ma±38 Ma),华夏陆块元古宙基底存在与Grenville造山运动相对比的构造岩浆事件(955～1148 Ma)及在新元古代(798 Ma±12 Ma,883 Ma±10 Ma)发生了较强烈的岩浆活动.粤中三水盆地经历了加里东期构造岩浆事件(438.0 Ma±6.8 Ma),之后至少经历了燕山早期(-160 Ma)、燕出境期(98.2Ma±1.1Ma)及喜山期3次构造岩浆事件.三水盆地多期次构造岩浆活动与成矿事件有一定的耦合关系,是控制矿床形成的主要因素.华南褶皱带岩浆活动强烈,经历新生代成矿作用,中新生代盆地边缘是找矿有利靶区.     

Regional stratigraphy and subsidence of Orphan Basin near the time of breakup and implications for rifting processes

The stratigraphic, subsidence and structural history of Orphan Basin, offshore the island of Newfoundland, Canada, is described from well data and tied to a regional seismic grid. This large (400 by 400 km) rifted basin is part of the non‐volcanic rifted margin in the northwest Atlantic Ocean, which had a long and complex rift history spanning Middle Jurassic to Aptian time. The basin is underlain by variably thinned continental crust, locally <10‐km thick. Our work highlights the complex structure, with major upper crustal faults terminating in the mid‐crust, while lower crustal reflectivity suggests ductile flow, perhaps accommodating depth‐dependent extension. We describe three major stratigraphic horizons connected to breakup and the early post‐rift. An Aptian–Albian unconformity appears to mark the end of crustal rifting in the basin, and a second, more subdued Santonian unconformity was also noted atop basement highs and along the proximal margins of the basin. Only minor thermal subsidence occurred between development of these two horizons. The main phase of post‐rift subsidence was delayed until post‐Santonian time, with rapid subsidence culminating in the development of a major flooding surface in base Tertiary time. Conventional models of rifting events predict significant basin thermal subsidence immediately following continental lithospheric breakup. In the Orphan Basin, however, this subsidence was delayed for about 25–30 Myr and requires more thinning of the mantle lithosphere than the crust. Models of the subsidence history suggest that extreme thinning of the lithospheric mantle continued well into the post‐rift period. This is consistent with edge‐driven, small‐scale convective flow in the mantle, which may thin the lithosphere from below. A hot spot may also have been present below the region in Aptian–Albian time.     

Geological structure and kinematics of normal faults in the Otway Basin,Australia, based on quantitative analysis of 3‐D seismic reflection data

The Otway Basin in the south of Victoria, Australia underwent three phases of deformation during breakup of the southern Australian margin. We assess the geometry and kinematics of faulting in the basin by analysing a 3‐D reflection seismic volume. Eight stratigraphic horizons and 24 SW‐dipping normal faults as well as subordinate antithetic faults were interpreted. This resulted in a high‐resolution geological 3‐D model (ca. 8 km × 7 km × 4 km depth) that we present as a supplementary 3‐D PDF (Data S1). We identified hard‐ and soft‐linking fault connections over the entire area, such as antithetic faults and relay ramps, respectively. Most major faults were continuously active from Early to Late Cretaceous, with two faults in the northern part of the study area active until at least the Oligocene. Allan maps of faults show tectonic activity continuously waned over this time period. Isopach maps of stratigraphic volumes quantify the amount of syn‐sedimentary movement that is characteristic of passive margins, such as the Otway Basin. We show that the faults possess strong corrugations (with amplitudes above the seismic resolution), which we illustrated by novel techniques, such as cylindricity and curvature. We argue that the corrugations are produced by sutures between sub‐vertical fault segments and this morphology was maintained during fault growth. Thus, they can be used to indicate the kinematics vector of the fault movement. This evidences, together with left‐stepping relay ramps, that 40% of the faults had a small component (up to 25°) of dextral oblique slip as well as normal (dip‐slip) movement.     

Characterizing Atmospheric Aerosols off the Atlantic Canadian Coast During C-FOG

Boundary-Layer Meteorology - Marine aerosols play an important role in the Earth’s climate, but their effects remain highly uncertain due to a poor understanding of their sources, properties,...     

A Lagrangian Cloud Model for the Study of Marine Fog

A large-eddy simulation model is coupled with a Lagrangian cloud model to study marine fog. In this model, aerosols and droplets are treated from a Lagrangian frame of reference, in contrast to the traditional bulk and bin microphysical models. Droplet growth via condensation is governed by Köhler theory and environmental conditions local to the droplet. Coupling to the vapour and temperature fields of the flow ensures mass, momentum, and energy conservation between the air and droplet phases. Based on the recent C-FOG field campaign, a simulation is performed which highlights the benefits and potential of this type of model. By initializing the simulation with the measured aerosol size distribution and making assumptions about the chemical composition of the multiple peaks, the simulations provide a clear explanation for the observed bimodal droplet distribution during C-FOG: high supersaturation levels cause condensational growth of nearly all coarse-mode aerosols (presumed to be composed of marine salt), as well as a large number of accumulation model aerosols (presumed to be of continental origin with a lower hygroscopicity). The largest peak in the resulting droplet distribution is created from coarse-mode aerosols with high hygroscopicity, while the secondary peak is only possible due to the limited impact of the largest peak on saturation levels inside the fog. Thus, for the simulated levels of supersaturation, it is the limited number of coarse-mode aerosols which is responsible for the emergence of a larger second peak.

     

The onset of the Messinian salinity crisis in the deep Eastern Mediterranean basin

Astronomical tuning of the Messinian pre‐salt succession in the Levant Basin allows for the first time the reconstruction of a detailed chronology of the Messinian salinity crisis (MSC) events in deep setting and their correlation with marginal records that supports the CIESM ( 2008 ) 3‐stage model. Our main conclusions are (1) MSC events were synchronous across marginal and deep basins, (2) MSC onset in deep basins occurred at 5.97 Ma, (3) only foraminifera‐barren, evaporite‐free shales accumulated in deep settings between 5.97 and 5.60 Ma, (4) deep evaporites (anhydrite and halite) deposition started later, at 5.60 Ma and (5) new and published ⁸⁷Sr/⁸⁶Sr data indicate that during all stages, evaporites precipitated from the same water body in all the Mediterranean sub‐basins. The wide synchrony of events and ⁸⁷Sr/⁸⁶Sr homogeneity implies inter‐sub‐basin connection during the whole MSC and is not compatible with large sea‐level fall and desiccation of the Mediterranean.     

Petrography and provenance of Upper Cretaceous – Palaeogene sandstones in the foreland basin system of Central Nepal

Sedimentary deposits of the Cretaceous to Miocene Tansen Group of Lesser Himalayan association in central Nepal record passive-margin sedimentation of the Indian Continent with direct deposition onto eroded Precambrian rocks (Sisne Formation onto Kaligandaki Supergroup rocks), succeeded by the appearance of orogenic detritus as the Indian continent collided with Asia on a N-dipping subduction zone. Rock samples from two field traverses were examined petrographically and through detrital zircon U–Pb dating, one traverse being across the Tansen Group and another across the Higher and Tethyan Himalaya (TH). The Tansen Group depositional ages are well known through fossil assemblages. We examined samples from three units of the Tansen Group (Amile, Bhainskati, and Dumri Formations). The Sedimentary petrographic data and Qt F L and Qm F Lt plots indicate their ‘Quartzose recycled’ nature and classify Tansen sedimentary rocks as ‘recycled orogenic’, suggesting Indian cratonic and Lower Lesser Himalayan (LLH) sediments as the likely source of sediments for the Amile Formation (Am), the TH and the Upper Lesser Himalaya (ULH) as the source for the Bhainskati Formation (Bk), and both the Tethyan and Higher Himalaya (HH) as the major sources for the Dumri Formation (Dm). The Cretaceous–Palaeocene pre-collisional Am is dominated by a broad detrital zircon U–Pb ~1830 Ma age peak with neither Palaeozoic nor Neoproterozoic zircons grains, but hosts a significant proportion (23%) of syndepositional Cretaceous zircons (121–105 Ma) would be contributions from the LLH volcanosedimentary arc, Gangdese batholith (including the Xigaze forearc). The other formations of the Tansen Group are more similar to Tethyan units than to Higher Himalaya Crystalline (HHC). From the analysed samples, there is a lack of distinctive evidence or HH detritus in the Tansen basin. Furthermore, the presence of ~23±1 Ma zircons from the HH unit suggests that they could not have been exposed until the earliest Miocene time.     

Characterization of a landslide-triggered debris flow at a rainforest-covered mountain region in Brazil

Natural Hazards - Debris flows represent great hazard to humans due to their high destructive power. Understanding their hydrogeomorphic dynamics is fundamental in hazard assessment studies,...