Crystal field stabilization energies of almandine-pyrope and almandine-spessartine garnets determined by FTIR near infrared measurements

The band positions of three partially overlapping Fe²⁺ spin-allowed transitions located between 4000 and 9000 cm^–1 in almandine-pyrope and almandinespessartine garnets solid solutions were measured using near-infrared (NIR) spectroscopy. The crystal field stabilization energies (CFSE) along both binaries were calculated assuming a splitting of 1100 cm^–1 for the lower orbitals. The CFSE show a slight increase along the almandine-spessartine binary from 3730 to 3810 cm^–1 and a larger increase from 3730 to 3970 cm^–1 for the almandine-pyrope binary. Dodecahedral Fe²⁺-site distortion increases with an increase in spessartine component and decreases with increasing pyrope component, in agreement with average dodecahedral site distortions determined from diffraction experiments. The excess CFSE's along both joins are negative. For the almandinespessartine binary they are small, but are about 3.5 times larger in magnitude along the join almandine-pyrope, where an interaction parameter of W= -2.9 KJ/mole has been derived from a symmetric mixing model. The excess CFSE are relatively small compared to the magnitudes of the excess enthalpies of mixing that have been assigned to garnet solid solutions. Moreover, they give no indication which could support the positive and asymmetric excess enthalpies of mixing that have been proposed for almandine-pyrope solid solutions.     

The tectono‐stratigraphic evolution of the Austral Basin and adjacent areas against the background of Andean tectonics,southern Argentina,South America

The Austral Basin (or Magallanes Basin) in southern Argentina is situated in a highly active tectonic zone. The openings of the South Atlantic and the Drake Passage to the east and south, active subduction in the west, and the related rise of the Andes have massively influenced the evolution of this area. To better understand the impacts of these tectonic events on basin formation to its present‐day structure we analysed 2D seismic reflection data covering about 95 000 km² on‐ and 115 000 km² offshore (Austral ‘Marina’ and Malvinas Basin). A total of 10 seismic horizons, representing nine syn‐ and post‐ rift sequences, were mapped and tied to well data to analyse the evolution of sedimentary supply and depocenter migration through time. 1D well backstripping across the study area confirms three main tectonic stages, containing (i) the break‐up phase forming basement graben systems and the evolution of the Late Jurassic – Early Cretaceous ancient backarc Austral/Rocas Verdes Basin (RVB), (ii) the inversion of the backarc marginal basin and the development of the foreland Austral Basin and (iii) the recent foreland Austral Basin. Synrift sedimentation did not exceed the creation of accommodation space, leading to a deepening of the basin. During the Early Cretaceous a first impulse of compression due to Andes uplift caused rise also of parts of the basin. Controlling factors for the subsequent tectonic development are subduction, balanced phases of sedimentation, accumulation and erosion as well as enhanced sediment supply from the rising Andes. Further phases of rock uplift might be triggered by cancelling deflection of the plate and slab window subduction, coupled with volcanic activity. Calculations of sediment accumulation rates reflect the different regional tectonic stages, and also show that the Malvinas Basin acted as a sediment catchment after the filling of the Austral Basin since the Late Miocene. However, although the Austral and Malvinas Basin are neighbouring basin systems that are sedimentary coupled in younger times, their earlier sedimentary and tectonic development was decoupled by the Rio Chico basement high. Thereby, the Austral Basin was affected by tectonic impacts of the Andes orogenesis, while the Malvinas Basin was rather affected by the opening of the South Atlantic.     

Thermal evolution of an extensional detachment as constrained by organic metamorphic data and thermal modeling: Graz Paleozoic Nappe Complex (Eastern Alps)

Following Early Cretaceous nappe stacking, the Eastern Alps were affected by late-orogenic extension during the Late Cretaceous. In the eastern segment of this range, a Late Cretaceous detachment separates a very low- to low-grade metamorphic cover (Graz Paleozoic Nappe Complex, GPNC) above a low- to high-grade metamorphic basement. Synchronously, the Kainach Gosau Basin (KGB) collapsed and subsided on top of the section.Metamorphism of organic material within this section has been investigated using vitrinite reflectance data and Raman spectra of extracted carbonaceous material. In the southern part of the GPNC, vitrinite reflectance indicates a decrease in organic maturity towards the stratigraphic youngest unit. The remaining part of the GPNC is characterized by an aureole of elevated vitrinite reflectance values and Raman R2 ratios that parallels the margins of the GPNC. Vitrinite reflectance in the KGB shows a steep coalification gradient and increases significantly towards the western basin margin. The observed stratigraphic trend in the southern GPNC is a result of deep Paleozoic to Early Cretaceous burial. This maturity pattern was overprinted along the margins by advective heat and convective fluids during Late Cretaceous to Paleogene exhumation of basement rocks.During shearing, the fault zone was heated up to ca. 500 °C. This overprint is explained by a two-dimensional thermal model with a ramp-flat fault geometry and a slip rate of 1 to 1.5 cm/year during 5 Ma fault movement. The collapse basin above the detachment subsided in a thermal regime which was characterized by relaxing isotherms.     

Simulating the moderating effect of a lake on downwind temperatures

A steady-state, two-dimensional numerical model is used to simulate air temperatures and humidity downwind of a lake at night. Thermal effects of the lake were modelled for the case of moderate and low surface winds under the cold-air advective conditions that occur following the passage of a cold front. Surface temperatures were found to be in good agreement with observations. A comparison of model results with thermal imagery indicated the model successfully predicts the downwind distance for which thermal effects due to the lake are significant.     

The measurement and extraction of the <nu>6 atmospheric emission band of CFC-12 from interfering emission features

Ground-based thermal emission measurements of the zenith sky have been made at Peterborough, Ontario since January 1993. In this paper, the measurement of the ₆ band of atmospheric CFC-12, an important greenhouse gas, is presented for a cold, clear day in January 1994. A spectrum of the non-CFC-12 emission features has been simulated using the FASCD3P radiation code and measured radiosonde profiles of temperature, pressure and humidity. This has enabled a satisfactory subtraction of the interfering emission features from the CFC-12 emission spectrum. A comparison of the observed and simulated ₆-bands of CFC-12 shows good agreement at all frequencies of emission. From these spectra the total downward greenhouse radiative flux from the CFC-12 ₆ emission based for a very cold day has been estimated to be 0.27 W m⁻²±10%.