An alternative interpretation of the Cayman trough evolution from a reidentification of magnetic anomalies

Magnetic data were collected during the Wilkes (1973) and Seacarib II (1987) cruises to the Cayman trough. A new interpretation of magnetic data is carried out. An isochron pattern is drawn up from our anomaly identifications. An early Eocene age (49 Ma, Ypresian) for Cayman trough opening is proposed instead of the late Oligocene or middle Eocene ages suggested by previous studies. Our plate tectonic reconstruction is simpler and fits the on-land geology (Jamaica and Cuba) and the tectonics. Our reconstruction shows a southward propagation of the spreading centre between magnetic anomalies 8 and 6 (26 and 20 Ma). The trough width increases by 30 km in this period. The southward propagation of the Cayman spreading centre from the Middle Oligocene to the Early Miocene induced the development of the restraining bend of the Swan Islands, the formation of a 1 km high scarp on the eastern trace of the Cayman trough transform fault (Walton fault) and the formation of a pull-apart basin (Hendrix pull-apart). Magnetic anomalies and magnetization maps give information about the deformation and the rocks. The proposed evolutionary model of the Cayman trough from the inception of seafloor spreading to the present configuration is presented in relation to the tectonic escape of the northern boundary of the Caribbean plate from the Maastrichtian to the Present.     

Structural and tectonothermal evolution of the ultrahigh-temperature Bakhuis Granulite Belt,Guiana Shield,Surinam:Palaeoproterozoic to recent

We constrain the multistage tectonic evolution of the Palaeoproterozoic UHT metamorphic(P=0.9–1.0 GPa,T>1000℃,t=2088–2031 Ma)Bakhuis Granulite Belt(BGB)in Surinam on the Guiana Shield,using large-to small-scale structures,Al-in-hornblende thermobarometry and published fluid inclusion and zircon geochronological data.The BGB forms a narrow,NE–SW striking belt between two formerly connected,~E–W oriented granite-greenstone belts,formed between converging Amazonian and West African continental masses prior to collision and Transamazonian orogeny.Inherited detrital zircon in BGB metasediments conforms agewise to Birimian zircon of West Africa and suggests derivation from the subsequently subducted African passive margin.Ultrahigh-temperature metamorphism may have followed slab break-off and asthenospheric heat advection.Peak metamorphic structures result from layer-parallel shearing and folding,reflecting initial transtensional exhumation of the subducted African margin after slab break-off.A second HT event involves intrusion,at ca.0.49 GPa,of charnockites and metagabbros at 1993–1984 Ma and a layered anorthosite at 1980 Ma,after the BGB had already cooled to<400℃.The event is related to northward subduction under the greenstone belts,along a new active margin to their south.A pronounced syntaxial bend in the new margin points northward towards the BGB and is likely the result of indentation by an anticlinorial flexural bulge of the subducting plate.Tearing of the subducting oceanic plate along this bulge explains why the charnockites are restricted to the BGB.The BGB subsequently experienced doming under an extensional detachment exposed in its southwestern border zone.Exhumation was focused in the BGB as a result of the flexural bulge in the subducting plate and localised heating of the overriding plate by charnockite magmatism.The present,straight NE–SW long-side boundaries of the BGB are superimposed mylonite zones,overprinted by pseudotachylites,previously dated at ca.1200 Ma and 950 Ma,respectively.The 1200 Ma mylonites reflect transpressional popping-up of the BGB,caused by EW-directed intraplate principal compressive stresses from Grenvillian collision preserved under the eastern Andes.Further exhumation of the BGB involved the 950 Ma pseudotachylite decorated faulting,and Phanerozoic faulting along reactivated Meso-and Neoproterozoic lineaments.     

山东淄博地区奥陶系层序地层划分和层序界面的识别标志

研究区为华北地台东部奥陶系发育最全的地区之一。区内出露下、中奥陶统 (两河口阶至宝塔阶 ,时限 4 95～ 4 4 5Ma)。岩石地层划分为三山子组和马家沟组。通过对野外剖面系统的观测 ,按碳酸盐岩台地层序地层的研究方法 ,识别出区内奥陶系 8个三级层序 (OSq1-OSq8)和 4种层序界面标志。平均每个三级层序延限约 6Ma ,OSq1由三山子组B段 (TST)和A段 (HST)组成。马家沟组含东黄山段、北庵庄段、土峪段、五阳山段、阁庄段、八陡段和新汶段。东黄山段至土峪段含 2个层序 (OSq2和OSq3 )。五阳山段和阁庄段包含 3个层序(OSq4 -OSq7)。八陡段 (TST)和新汶段 (HST)组成最上部一个层序 (OSq8)。通过与河北唐山等地区同期地层的对比 ,提出华北地台下、中奥陶统 (两河口阶至宝塔阶 )可划分为 11个三级层序 ,探讨了华北地台下、中奥陶统层序差异性的可能的控制因素。     

Enhanced bioremoval of refractory compounds from dyeing wastewater using optimized sequential anaerobic/aerobic process

The upflow anaerobic sludge blanket process followed by the biological aerated filter process was employed to improve the removal of color and recalcitrant compounds from real dyeing wastewater. The highest removal efficiency for color was observed in the anaerobic process, at 8-h hydraulic retention time, seeded with the sludge granule. In the subsequent aerobic process packed with the microbe-immobilized polyethylene glycol media, the removal efficiency for chemical oxygen demand increased significantly to 75 %, regardless of the empty bed contact time. The average influent non-biodegradable soluble chemical oxygen demand was 517 mg/L, and the average concentration in effluent from the anaerobic reactor was 363 mg/L, suggesting the removal of some recalcitrant matters together with the degradable ones. The average non-biodegradable soluble chemical oxygen demand in effluent from the aerobic reactor was 87, 93, and 118 mg/L, with the removal efficiency of 76, 74, and 67 %, at 24-, 12-, and 8-h empty bed contact time, respectively. The combined anaerobic sludge blanket and aerobic cell-entrapped process was effective to remove the refractory compounds from real dyeing wastewater as well as in reducing organic loading to meet the effluent discharge limits. This integrated process is considered an effective and economical treatment technology for dyeing wastewater.     

Preliminary magnetic susceptibility characteristics of the Bharati promontory (Grovness Peninsula), Larsemann Hills,Prydz Bay region,East Antarctica

The coastal tract of the Prydz Bay region in the East Antarctica exposes Archean to Late Proterozoic magmatic and medium- to high grade (amphibolite — granulite facies) metamorphic rocks. The para- and ortho gneisses from the Bharati promontory (Grovness Peninsula) forming a part of the Larsemann Hills in the southern segment of Prydz Bay were investigated for magnetic characterization. In this small peninsula the upper amphibolite facies gneisses occur as NE-trending bands. The para-gneisses show a range of mineral assemblages (± cordierite ± sillimanite ±garnet) while ortho-gneiss mineralogy includes quartz, feldspar, biotite, garnet. All the lithological units in Bharati promontory contain ubiquitous magnetite, however, with wide variation in the volume proportions. This has resulted in a wide range in magnetic susceptibility (10^?4 to 10^?2 SI). Magnetic foliations show a correspondence with the general trend of lithounits (050° NE) and define a resulting geometry of mainly D₁ and D₂ foliations. The magnetic lineations show a preferred orientation with moderate easterly plunge (mean vector 093/36). The findings have implications for the magnetic field survey because such fabrics would impart a strong horizontal component of induced magnetization.     

Fluid inclusion studies of the Abawso gold prospect,near the Ashanti Belt,Ghana

The major Ghanaian lode gold deposits are preferentially aligned along the western and eastern contacts of the Kumasi Basin with the Ashanti and Sefwi Belts, respectively. The investigated area of the Abawso small-scale concession, covering the workings of the old Ettadom mine, is situated 3 km west of the lithological contact of the Birimian metavolcanic rocks of the Akropong Belt in the east with the Birimian metasedimentary rocks of the Kumasi Basin in the west. The rocks of the Abawso concession represent a steeply NW-dipping limb of a SE-verging anticline with an axis plunging to the SW. Quartz veining occurs predominantly in the form of en échelon dilatational veins along NNE–SSW-striking shear zones of a few metres width and shows evidence of brittle and ductile deformation. Also stockwork-style quartz veining occurs in the vicinity of the main shaft of the old Ettadom mine. Hydrothermal alteration includes sericitisation, sulphidation and locally carbonatisation. The auriferous quartz veins mainly follow the trend of brittle to ductile deformed quartz veins; however, some occur in stockwork. Fluid inclusion studies reveal a large number of H₂O inclusions along intragranular trails in auriferous quartz vein samples, as well as an overall dominance of H₂O and H₂O-CO₂ inclusions over CO₂ inclusions. Textural observations and physico-chemical fluid inclusion properties indicate post-entrapment modifications for all quartz vein samples due to grain boundary migration recrystallisation. This process is interpreted to be responsible for the generation of the CO₂ inclusions from a H₂O-CO₂ parent fluid. In comparison with mineralisation at the Ashanti and Prestea deposits, which are characterised by CO₂±N₂ inclusions, the observed inclusion assemblage may be due to a shallower crustal level of mineralisation, or different degrees and styles of recrystallisation, or a less pronounced development of laminated quartz veins due to comparably restricted pressure fluctuations. Furthermore, the microthermometric observations allow the reconstruction of a possible retrograde P-T path, depicting near-isothermal decompression in the P-T range of the brittle/ductile transition.Editorial handling: E. Frimmel     

Oxidation of the Kaapvaal lithospheric mantle driven by metasomatism

The oxidation state, reflected in the oxygen fugacity (fO₂), of the subcratonic lithospheric mantle is laterally and vertically heterogeneous. In the garnet stability field, the Kaapvaal lithospheric mantle becomes progressively more reducing with increasing depth from Δlog fO₂ FMQ-2 at 110 km to FMQ-4 at 210 km. Oxidation accompanying metasomatism has obscured this crystal-chemical controlled depth-fO₂ trend in the mantle beneath Kimberley, South Africa. Chondrite normalized REE patterns for garnets, preserve evidence of a range in metasomatic enrichment from mild metasomatism in harzburgites to extensive metasomatism by LREE-enriched fluids and melts with fairly unfractionated LREE/HREE ratios in phlogopite-bearing lherzolites. The metasomatized xenoliths record redox conditions extending up to Δlog fO₂ = FMQ, sufficiently oxidized that magnesite would be the stable host of carbon in the most metasomatized samples. The most oxidized lherzolites, those in or near the carbonate stability field, have the greatest modal abundance of phlogopite and clinopyroxene. Clinopyroxene is modally less abundant or absent in the most reduced peridotite samples. The infiltration of metasomatic fluids/melts into diamondiferous lithospheric mantle beneath the Kaapvaal craton converted reduced, anhydrous harzburgite into variably oxidized phlogopite-bearing lherzolite. Locally, portions of the lithospheric mantle were metasomatized and oxidized to an extent that conversion of diamond into carbonate should have occurred. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

矿物学文献中未定名矿物的编码系统:国际矿物学协会新矿物与命名和分类委员会“未定名矿物”小组报告

国际矿物学协会新矿物与命名和分类委员会(IMA-CNMMN)的未定名矿物小组(SUM),开发了一个编码系统,对已经发表但尚未定名的矿物进行编码。在文献中存在两类未定名矿物。一是"有效"未定名矿物,是指未定名矿物没有对应的已知矿物种,但如果它们有其他产地或能够在其他样品中被发现,那么已发表的相关矿物描述允许得到认可。二是"无效"未定名矿物,是指未定名矿物已经有对应的已知矿物种;或者相关矿物描述不足以获得认可。未定名矿物的名单是由IMA保管。该编码系统提供了一个永久的UM号码。中国的矿物学文献的数量和重要性有必要用中文阐述未定名矿物的编码系统。     

Residual Exchange Flows in Subtropical Estuaries

Observations of residual exchange flows at the entrance to four subtropical estuaries, two of them semiarid, indicate that these flows are mainly tidally driven, as they compare favorably with theoretical patterns of tidal residual flows. In every estuary examined, the tidal behavior was that of a standing or near-standing wave, i.e., tidal elevation and tidal currents were nearly in quadrature. The pattern of exchange flow that persisted at every estuary exhibited inflow in the channel and outflow over the shoals. Curiously, but also fortuitously, this pattern coincides with the exchange pattern driven by density gradients in other estuaries. The tidal stresses and the residual elevation slopes should be the dominant mechanisms that drive such tidal residual pattern because the Stokes transport mechanism is negligible for standing or near-standing waves. Time series measurements from the semiarid estuaries showed fortnightly modulation of the residual flow by tidal forcing in such a way that the strongest net exchange flows developed with the largest tidal distortions, i.e., during spring tides. This modulation is opposite to the modulation that typically results in temperate estuaries, where the strongest net exchange flows tend to develop during neap tides. The fortnightly modulation on tidal residual currents could be inferred from previous theoretical results because residual currents arise from tidal distortions but is made explicit in this study. The findings advanced herein should allow the drawing of generalities about exchange flow patterns in subtropical estuaries where residual flows are mainly driven by tides.     

Origin of fluids in iron oxide–copper–gold deposits: constraints from δ 37Cl, 87Sr/86Sri and Cl/Br

The origin of the hypersaline fluids (magmatic or basinal brine?), associated with iron oxide (Cu–U–Au–REE) deposits, is controversial. We report the first chlorine and strontium isotope data combined with Cl/Br ratios of fluid inclusions from selected iron oxide–copper–gold (IOCG) deposits (Candelaria, Raúl–Condestable, Sossego), a deposit considered to represent a magmatic end member of the IOCG class of deposit (Gameleira), and a magnetite–apatite deposit (El Romeral) from South America. Our data indicate mixing of a high δ ³⁷Cl magmatic fluid with near 0‰ δ ³⁷Cl basinal brines in the Candelaria, Raúl–Condestable, and Sossego IOCG deposits and leaching of a few weight percent of evaporites by magmatic-hydrothermal (?) fluids at Gameleira and El Romeral. The Sr isotopic composition of the inclusion fluids of Candelaria, Raúl–Condestable, and El Romeral confirms the presence of a non-magmatic fluid component in these deposits. The heavy chlorine isotope signatures of fluids from the IOCG deposits (Candelaria, Raúl–Condestable, Sossego), reflecting the magmatic-hydrothermal component of these fluids, contrast with the near 0‰ δ ³⁷Cl values of porphyry copper fluids known from the literature. The heavy chlorine isotope compositions of fluids of the investigated IOCG deposits may indicate a prevailing mantle Cl component in contrast to porphyry copper fluids, an argument also supported by Os isotopes, or could result from differential Cl isotope fractionation processes (e.g. phase separation) in fluids of IOCG and porphyry Cu deposits.