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861.
Karl?Hans?Wedepohl Klaus?SimonEmail author 《Contributions to Mineralogy and Petrology》2012,164(4):693-696
During the Variscan orogeny in Central Europe, partial melting in the lower continental crust formed granitic magmas, which intruded into the upper crust and left compounds of Ca (plus Eu2+), Mg, etc. in the lower crust. From the late Paleozoic decomposition of the tonalitic upper crust, sedimentary graywackes were produced reflecting the composition of this crust. The repeated reworking of the sedimentary cover caused the formation of sands. Sandstones as their products of consolidation contain increasing fractions of quartz and decreasing feldspar from Carboniferous and Triassic to Cretaceous age. A distinct negative Eu anomaly characterizes the majority of these rocks. The latter is imprinted by the Variscan magmatism. Quartz as used for numerous Medieval wood ash glasses is marked for its Central European origin by a distinct negative Eu anomaly in contrast to many soda glasses produced outside Germany mostly with a small or none Eu anomaly. 相似文献
862.
Ana Luisa Outa Mori Paulo Alves de Souza Juliana Charão Marques Ricardo da Cunha Lopes 《Gondwana Research》2012,21(2-3):654-669
Index species useful for correlations with the International Stratigraphical Column are rare or absent in the Pennsylvanian–Permian strata of the Paraná Basin in Brazil, preventing accuracy in geochronologic assignments. Besides, absolute datings are very scarce in comparison with other Gondwana basins. This paper presents palynological data from an outcrop on the surroundings of the Candiota coal mine, southmost Brazil, from several levels of the Rio Bonito and Palermo formations. The presence of certain index species of spore–pollen allowed the recognition of two Permian palynozones: the Vittatina costabilis and the Lueckisporites virkkiae zones. Furthermore, U–Pb in zircons from a volcaniclastic level interbedded in the coal strata of the former unit was analyzed through LA-MC-ICP-MS method, providing a new absolute age dating of 281.4 ± 3.4 Ma (Cisuralian, Early Permian). This dating is assumed as the oldest occurrence of the L. virkkiae Zone in Paraná Basin, which contains index species that are widespread in other Gondwana basins. A well distributed surface boundary occurs in this section also, allowing local and regional correlations. These new biostratigraphical and geochronological data are integrated, in order to offer a deep analysis on the stratigraphical significance for correlations across the Occidental Gondwana. 相似文献
863.
Pharmaceuticals as indictors of sewage-influenced groundwater 总被引:1,自引:0,他引:1
Beate Müller Traugott Scheytt Martin Asbrand Andrea Mross de Casas 《Hydrogeology Journal》2012,20(6):1117-1129
A set of human pharmaceuticals enables identification of groundwater that is influenced by sewage and provides information on the time of recharge. As the consumption rates of the investigated pharmaceuticals have changed over time, so too has the composition of the sewage. At the study area, south of Berlin (Germany), irrigation was performed as a method of wastewater clean-up at sewage irrigation farms until the early 1990s. Today, treated wastewater is discharged into the surface-water-stream Nuthegraben. Groundwater and surface-water samples were analyzed for the pharmaceutical substances clofibric acid, bezafibrate, diclofenac, carbamazepine and primidone, the main ions and organic carbon. The pharmaceutical substances were detected at concentrations up to microgram-per-liter level in groundwater and surface-water samples from the Nuthegraben Lowland area and from the former irrigation farms. Concentrations detected in groundwater are generally much lower than in surface water and there is significant variation in the distribution of pharmaceutical concentrations in groundwater. Groundwater influenced by the irrigation of sewage water shows higher primidone and clofibric-acid concentrations. Groundwater influenced by recent discharge of treated sewage water into the surface water shows high carbamazepine concentrations while concentrations of primidone and clofibric acid are low. 相似文献
864.
865.
Since 1991, the Caernarvon Freshwater Diversion has been reintroducing Mississippi River water into a previously hydrologically isolated estuary in an effort to restore wetlands. To determine the effect of freshwater inflow on estuarine nekton community structure, a Before?CAfter?CControl?CImpact study design was applied. As a result of the opening, salinities in the impact area decreased, and the nekton community structure in the estuary changed significantly. Species of economical or ecological importance either increased in biomass or exhibited no response to the opening of the diversion. Higher abundances of small fish were observed in the area receiving freshwater flow, which is an indication that the area serves as a refuge from large marine predators. Because a salinity gradient was established, as opposed to a uniform but lower salinity regime, aquatic habitat was available to nekton species from a wide spectrum of salinity tolerances. 相似文献
866.
The scopes of this work are to study the mechanisms of load transfer and the deformations of the ground during slurry trenching and concreting in dry sand and to evaluate their effects on service structural loads, wall deflections and ground displacements behind the wall caused by subsequent excavation. A series of three-dimensional finite element analyses was carried out modelling the installation of diaphragm walls consisting of panels of different length. The soil was modelled as either linearly elastic-perfectly plastic or incrementally non-linear (hypoplastic) with elastic strain range. Plane strain analyses of diaphragm walls of identical cross section were also carried out in which wall installation was either modelled or the wall was wished in place (WIP). The analyses predict ground movements consistent with the experimental observations both in magnitude and trend. The results also show that the maximum horizontal wall deflections and structural loads reduce with increasing panel aspect ratio towards a minimum which is about twice the value computed for WIP analyses. Panel aspect ratios should be larger than about three to take advantage of the three-dimensional effects. The pattern and magnitude of surface vertical displacements obtained from linearly elastic-perfectly plastic analyses, no matter whether three- or two-dimensional, are unrealistic. 相似文献
867.
Jens-Olaf?DelfsEmail author Frank?Blumensaat Wenqing?Wang Peter?Krebs Olaf?Kolditz 《Environmental Earth Sciences》2012,65(5):1439-1457
This paper presents the hydrological coupling of the software framework OpenGeoSys (OGS) with the EPA Storm Water Management
Model (SWMM). Conceptual models include the Saint Venant equation for river flow, the 2D Darcy equations for confined and
unconfined groundwater flow, a two-way hydrological coupling flux in a compartment coupling approach (conductance concept),
and Lagrangian particles for solute transport in the river course. A SWMM river–OGS aquifer inter-compartment coupling flux
is examined for discharging groundwater in a systematic parameter sensitivity analysis. The parameter study involves a small
perturbation (first-order) sensitivity analysis and is performed for a synthetic test example base-by-base through a comprehensive
range of aquifer parametrizations. Through parametrization, the test cases enables to determine the leakance parameter for
simulating streambed clogging and non-ocillatory river-aquifer water exchange rates with the sequential (partitioned) coupling
scheme. The implementation is further tested with a hypothetical but realistic 1D river–2D aquifer model of the Poltva catchment,
where discharging groundwater in the upland area affects the river–aquifer coupling fluxes downstream in the river course
(propagating feedbacks). Groundwater contribution in the moving river water is numerically determined with Lagrangian particles.
A numerical experiment demonstrates that the integrated river–aquifer model is a serviceable and realistic constituent in
a complete compartment model of the Poltva catchment. 相似文献
868.
869.
Frank?DethlefsenEmail author Christoph?Haase Markus?Ebert Andreas?Dahmke 《Environmental Earth Sciences》2012,65(4):1105-1117
One of the uncertainties in the field of carbon dioxide capture and storage (CCS) is caused by the parameterization of geochemical
models. The application of geochemical models contributes significantly to calculate the fate of the CO2 after its injection. The choice of the thermodynamic database used, the selection of the secondary mineral assemblage as
well as the option to calculate pressure dependent equilibrium constants influence the CO2 trapping potential and trapping mechanism. Scenario analyses were conducted applying a geochemical batch equilibrium model
for a virtual CO2 injection into a saline Keuper aquifer. The amount of CO2 which could be trapped in the formation water and in the form of carbonates was calculated using the model code PHREEQC.
Thereby, four thermodynamic datasets were used to calculate the thermodynamic equilibria. Furthermore, the equilibrium constants
were re-calculated with the code SUPCRT92, which also applied a pressure correction to the equilibrium constants. Varying
the thermodynamic database caused a range of 61% in the amount of trapped CO2 calculated. Simultaneously, the assemblage of secondary minerals was varied, and the potential secondary minerals dawsonite
and K-mica were included in several scenarios. The selection of the secondary mineral assemblage caused a range of 74% in
the calculated amount of trapped CO2. Correcting the equilibrium constants with respect to a pressure of 125 bars had an influence of 11% on the amount of trapped
CO2. This illustrates the need for incorporating sensitivity analyses into reaction pathway modeling. 相似文献
870.
This paper presents a method for transforming the information of an engineering geological map into useful information for
non-specialists involved in land-use planning. The method consists of classifying the engineering geological units in terms
of land use capability and identifying the legal and the geologic restrictions that apply in the study area. Both informations
are then superimposed over the land use and a conflict areas map is created. The analysis of these data leads to the identification
of existing and forthcoming land use conflicts and enables the proposal of planning measures on a regional and local scale.
The map for the regional planning was compiled at a 1:50,000 scale and encompasses the whole municipal land area where uses
are mainly rural. The map for the local planning was compiled at a 1:10,000 scale and encompasses the urban area. Most of
the classification and operations on maps used spatial analyst tools available in the Geographical Information System. The
regional studies showed that the greater part of Analandia’s territory presents appropriate land uses. The local-scale studies
indicate that the majority of the densely occupied urban areas are in suitable land. Although the situation is in general
positive, municipal policies should address the identified and expected land use conflicts, so that it can be further improved. 相似文献