Assessment of Alaska’s North Slope Oil Field Capacity to Sequester CO2

The capacity of 21 major fields containing more than 95% of the North Slope of Alaska’s oil were investigated for CO₂ storage by injecting CO₂ as an enhanced oil recovery (EOR) agent. These fields meet the criteria for the application of miscible and immiscible CO₂-EOR methods and contain about 40 billion barrels of oil after primary and secondary recovery. Volumetric calculations from this study indicate that these fields have a static storage capacity of 3 billion metric tons of CO₂, assuming 100% oil recovery, re-pressurizing the fields to pre-fracturing pressure and applying a 50% capacity reduction to compensate for heterogeneity and for water invasion from the underlying aquifer. A ranking produced from this study, mainly controlled by field size and fracture gradient, identifies Prudhoe, Kuparuk, and West Sak as possessing the largest storage capacities under a 20% safety factor on pressures applied during storage to avoid over-pressurization, fracturing, and gas leakage. Simulation studies were conducted using CO₂ Prophet to determine the amount of oil technically recoverable and CO₂ gas storage possible during this process. Fields were categorized as miscible, partially miscible, and immiscible based on the miscibility of CO₂ with their oil. Seven sample fields were selected across these categories for simulation studies comparing pure CO₂ and water-alternating-gas injection. Results showed that the top two fields in each category for recovery and CO₂ storage were Alpine and Point McIntyre (miscible), Prudhoe and Kuparuk (partially miscible), and West Sak and Lisburne (immiscible). The study concludes that 5 billion metric tons of CO₂ can be stored while recovering 14.2 billion barrels of the remaining oil.     

Unveiling the Launching Region of YSO Jets with AMBER

The interplay between accretion and ejection in the environment of young stellar objects (YSOs) is believed to be a crucial element in the star formation process. Since most of the properties of the models are set up in the first few AUs from the source (below the so-called Alfvèn surface), to validate and constrain the models observationally we need very high angular resolution. With HST (resolution ∼ 0.'1, i.e. about 14 AU in Taurus)we have been able to access the external border of the acceleration region, for jets in the Taurus-Auriga cloud. Here we see an onion-like kinematic structure in the first 200 AU of the flow, and indications for rotation around the symmetry axis for the resolved low/moderate velocity component. We have now planned observations with AMBER on the VLTI to investigate at 1 mas resolution (in J) the core of the central engine, down to 0.1 AU from the source. Here we describe a joint project by several Institutes in the AMBER consortium dedicated to the study of the morphology and detailed kinematics of a few selected targets. On one hand we will use the large UV coverage of the ATs to explore at medium spectral resolution the structure of the flow. On the other hand the large collection area of the UTs combined with the high resolution mode (R=10000) of AMBER will allow us to search for interesting kinematic features, among which signatures of rotation around the axis, that would constitute an important validation of the proposed models for the jet launching. This revised version was published online in July 2006 with corrections to the Cover Date.     

Behaviour of chemical solutes during a storm in a rainforested headwater catchment

The aim of this study is to identify, in a small catchment area located within a tropical forest, the pedological compartments in which the export of nutrients and chemical erosion of solutes occur during a stormflow event. The catchment area displays two types of lateral flow: (i) overland flow at the surface of the soil in the litter and root mat and (ii) groundwater flow in a macroporous subsurface horizon. We interpret the variations of stream‐water chemistry during a storm‐flow event using the separation of storm‐flow hydrograph data between overland and groundwater flow, and (Cl^?) as a chemical parameter characterizing the residence time of water in the soil. It appears that K⁺ especially was released into the throughfall, whereas Ca⁺⁺, Mg⁺⁺ and Na⁺ were clearly released from the litter. K⁺ disappeared rapidly from soil solution, whereas Ca⁺⁺ and Mg⁺⁺ were more progressively absorbed by the vegetation. The Ca⁺⁺ and Mg⁺⁺ contents in groundwater increased with increasing residence time owing to the transpiration of trees. The export of H₄SiO₄ in the overland flow was moderate, i.e. 24% of total H₄SiO₄ export in the stream flow, as overland flow represented 39% of total runoff. The subsurface horizon—where active groundwater flow occurs—was successively affected by chemical erosion during the storm‐flow peak, and then by neoformation of kaolinite favoured by increasing water residence time. Copyright © 2003 John Wiley & Sons, Ltd.     

Proper Motions and Velocity Asymmetries in the RW Aur Jet

We present adaptive optics spectro-imaging observations of the RW Aur jet in optical forbidden lines, at an angular resolution of 0.4″. Comparison with HST data taken 2 yr later shows that proper motions in the blueshifted and redshifted lobes are in the same ratio as their radial velocities, a direct proof that the velocity asymmetry in this jet is real and not an emissivity effect. The inferred jet inclination to the line of sight is i = 46±3°. The inner knot spacing appears best explained by time variability with at least two modes: one irregular and asymmetric (possibly random) on timescales of ≤3–10 yr, and another more regular with ?20 yr period. We also report indirect evidence for correlated velocity and excitation gradients in the redshifted lobe, possibly related to the blue/red velocity and brightness asymmetry in this system.     

Multi‐generational carbonate assemblages in martian meteorite Allan Hills 84001: Implications for nucleation,growth, and alteration

Abstract— The carbonate mineralogy of several complex carbonate‐rich regions in Allan Hills (ALH) 84001 has been examined. These regions contain familiar forms of carbonate, as well as textural forms previously unreported including carbonate rosettes, planiform “slab” carbonates, distinct “post‐slab” magnesites, and carbonates interstitial to feldspathic glass and orthopyroxene. Slab carbonates reveal portions of the carbonate growth sequence not seen in the rosettes and suggest that initial nucleating compositions were calcite‐rich. The kinetically controlled growth of rosettes and slab carbonates was followed by an alteration event that formed the magnesite‐siderite layers on the exterior surfaces of the carbonate. Post‐slab magnesite, intimately associated with silica glass, is compositionally similar to the magnesite in these exterior layers but represents a later generation of carbonate growth. Feldspathic glasses had little or no thermal effect on carbonates, as indicated by the lack of thermal decomposition or any compositional changes associated with glass/carbonate contacts.     

High‐calcium pyroxene as an indicator of igneous differentiation in asteroids and meteorites

Abstract— Our analyses of high quality spectra of several S‐type asteroids (17 Thetis, 847 Agnia, 808 Merxia, and members of the Agnia and Merxia families) reveal that they include both low‐ and high‐calcium pyroxene with minor amounts of olivine (<20%). In addition, we find that these asteroids have ratios of high‐calcium pyroxene to total pyroxene of >～0.4. High‐calcium pyroxene is a spectrally detectable and petrologically important indicator of igneous history and may prove critical in future studies aimed at understanding the history of asteroidal bodies. The silicate mineralogy inferred for Thetis and the Merxia and Agnia family members requires that these asteroids experienced igneous differentiation, producing broadly basaltic surface lithologies. Together with 4 Vesta (and its smaller “Vestoid” family members) and the main‐belt asteroid 1489 Magnya, these new asteroids provide strong evidence for igneous differentiation of at least five asteroid parent bodies. Based on this analysis of a small subset of the near‐infrared asteroid spectra taken to date with SpeX at the NASA IRTF, we expect that the number of known differentiated asteroids will increase, consistent with the large number of parent bodies inferred from studies of iron meteorites.     

Olivine‐dominated asteroids and meteorites: Distinguishing nebular and igneous histories

Abstract— Melting models indicate that the composition and abundance of olivine systematically co‐vary and are therefore excellent petrologic indicators. However, heliocentric distance, and thus surface temperature, has a significant effect on the spectra of olivine‐rich asteroids. We show that composition and temperature complexly interact spectrally, and must be simultaneously taken into account in order to infer olivine composition accurately. We find that most (7/9) of the olivine‐dominated asteroids are magnesian and thus likely sampled mantles differentiated from ordinary chondrite sources (e.g., pallasites). However, two other olivine‐rich asteroids (289 Nenetta and 246 Asporina) are found to be more ferroan. Melting models show that partial melting cannot produce olivine‐rich residues that are more ferroan than the chondrite precursor from which they formed. Thus, even moderately ferroan olivine must have non‐ordinary chondrite origins, and therefore likely originate from oxidized R chondrites or melts thereof, which reflect variations in nebular composition within the asteroid belt. This is consistent with the meteoritic record in which R chondrites and brachinites are rare relative to pallasites.     

Application of Aqua MODIS sensor data for estimating chlorophyll a in the turbid Case 2 waters of Lake Erie using bio-optical models

There is considerable interest in accurately estimating water quality parameters in turbid (Case 2) and eutrophic waters such as the Western Basin of Lake Erie (WBLE). Lake Erie is a large, open freshwater body that supports diverse ecosystem, and over 12 million people in the mid-western part of the United States depend on it for drinking water, fisheries, navigational, and recreational purposes. The increasing utilization of the freshwater has deteriorated the water severely and currently the lake is experiencing recurring harmful algal blooms (HABs). Improving the water quality of Lake Erie requires the use of robust monitoring tools that help water quality managers understand sources and pathways of influxes that trigger HABs. Satellite-based remote sensing sensor such as the moderate resolution imaging spectroradiometer (MODIS) may provide frequent and synoptic view of the water quality indices. In this study, data set from field measurements was used to evaluate the performance of 14 existing ocean color algorithms. Results indicated that MODIS data consistently underestimated the chlorophyll a concentrations in the WBLE, with the largest source of errors from dissolved organic matter and xanthophyll accessory pigments in this data set. Most of the global algorithms, including OC4v4 and the Baltic model, generated near-identical statistical parameters with an average R² of ~0.57 and RMSE ~2.9 μg/l. MODIS performed poorly (R² ~0.18) when its NIR/red bands were used. A slightly improved model was developed using similar band ratio approach generating R² of ~0.62 and RMSE ~1.8 μg/l.