A New Interlaboratory Characterisation of Silicon,Rare Earth Elements and Twenty‐Two Other Trace Element Concentrations in the Natural River Water Certified Reference Material SLRS‐6 (NRC‐CNRC)

The natural river water reference material SLRS‐6 (NRC‐CNRC) is the newest batch of a quality control material routinely used in many international environmental laboratories. This work presents a nine‐laboratory compilation of measurements of major and trace element concentrations and their related uncertainties, unavailable in the NRC‐CNRC certificate (B, Cs, Li, Ga, Ge, Hf, Nb, P, Rb, Rh, Re, S, Sc, Se, Si, Sn, Th, Ti, Tl, W, Y, Y, Zr and REEs). Measurements were mostly made using inductively coupled plasma‐mass spectrometry. The results are compared with equivalent data for the last batch of the material, SLRS‐5, measured simultaneously with SLRS‐6 in this study. In general, very low concentrations, close to the quantification limits, were found in the new batch. The Sr isotopic ratio is also reported.     

Predictions for the LCROSS mission

Abstract— We describe the results of a variety of model calculations for predictions of observable results of the LCROSS mission to be launched in 2009. Several models covering different aspects of the event are described along with their results. Our aim is to bracket the range of expected results and produce a useful guide for mission planning. In this paper, we focus on several different questions, which are modeled by different methods. The questions include the size of impact crater, the mass, velocity, and visibility of impact ejecta, and the mass and temperature of the initial vapor plume. The mass and velocity profiles of the ejecta are of primary interest, as the ejecta will be the main target of the S‐S/C observations. In particular, we focus on such quantities as the amount of mass that reaches various heights. A height of 2 km above the target is of special interest, as we expect that the EDUS impact will take place on the floor of a moderate‐sized crater ?30 km in diameter, with a rim height of 1–2 km. The impact ejecta must rise above the crater rim at the target site in order to scatter sunlight and become visible to the detectors aboard the S‐S/C. We start with a brief discussion of crater scaling relationships as applied to the impact of the EDUS second stage and resulting estimated crater diameter and ejecta mass. Next we describe results from the RAGE hydrocode as applied to modeling the short time scale (t 0.1 s) thermal plume that is expected to occur immediately after the impact. We present results from several large‐scale smooth‐particle hydrodynamics (SPH) calculations, along with results from a ZEUS‐MP hydrocode model of the crater formation and ejecta mass‐velocity distribution. We finish with two semi‐analytic models, the first being a Monte Carlo model of the distribution of expected ejecta, based on scaling models using a plausible range of crater and ejecta parameters, and the second being a simple model of observational predictions for the shepherding spacecraft (S‐S/C) that will follow the impact for several minutes until its own impact into the lunar surface. For the initial thermal plume, we predict an initial expansion velocity of ?7 km s^?1, and a maximum temperature of ?1200 K. Scaling relations for crater formation and the SPH calculation predict a crater with a diameter of ?15 m, a total ejecta mass of ?10⁶kg, with ?10⁴kg reaching an altitude of 2 km above the target. Both the SPH and ZEUS‐MP calculations predict a maximum ejecta velocity of ?1 km s^?1. The semi‐analytic Monte Carlo calculations produce more conservative estimates (by a factor of ?5) for ejecta at 2 km, but with a large dispersion in possible results.     

Modeling the impacts of bottom trawling and the subsequent recovery rates of sponges and corals in the Aleutian Islands, Alaska

The abundance of some marine fish species are correlated to the abundance of habitat-forming benthic organisms such as sponges and corals. A concern for fisheries management agencies is the recovery of these benthic invertebrates from removal or mortality from bottom trawling and other commercial fisheries activities. Using a logistic model, observations of available substrate and data from bottom trawl surveys of the Aleutian Islands, Alaska, we estimated recovery rates of sponges and corals following removal. The model predicted the observed sponge and coral catch in bottom trawl surveys relatively accurately (R²=0.38 and 0.46). For sponges, the results show that intrinsic growth rates were slow (r=0.107 yr⁻¹). Results show that intrinsic growth rates of corals were also slow (r=0.062 yr⁻¹). The best models for corals and sponges were models that did not include the impacts of commercial fishing removals. Subsequent recovery times for both taxa were also predicted to be slow. Mortality of 67% of the initial sponge biomass would recover to 80% of the original biomass after 20 years, while mortality of 67% of the coral biomass would recover to 80% of the original biomass after 34 years. The modeled recovery times were consistent with previous studies in estimating that recovery times were of the order of decades, however improved data from directed studies would no doubt improve parameter estimates and reduce the uncertainty in the model results. Given their role as a major ecosystem component and potential habitat for marine fish, damage and removal of sponges and corals must be considered when estimating the impacts of commercial bottom trawling on the seafloor.     

Virtual moralities: The mainstreaming of Fairtrade in Kenyan tea fields

Fairtrade was founded to alleviate poverty and economic injustice through a market-based form of solidarity exchange. Yet with the increasing participation of transnational food corporations in Fairtrade sourcing, new questions are emerging on the extent to which the model offers an alternative to the inimical tendencies of neoliberalism. Drawing on a qualitative research project of Kenyan Fairtrade tea, this paper examines how the process of corporate mainstreaming influences the structure and outcomes of Fairtrade, and specifically the challenges it poses for the realization of Fairtrade’s development aspirations. It argues firstly that whilst tea producers have experienced tangible benefits from Fairtrade’s social premium, these development ‘gifts’ have been conferred through processes marked less by collaboration and consent than by patronage and exclusion. These contradictions are often glossed by the symbolic force of Fairtrade’s key tenets - empowerment, participation, and justice - which simultaneously serve to neutralize critique and mystify the functions that Fairtrade performs for the political economy of development and neoliberalism. Second, building on recent critiques of corporate social responsibility, the paper explores how certain neoliberal rationalities are emboldened through Fairtrade, as a process of mainstreaming installs new metrics of governance (standards, certification, participation) that are at once moral and technocratic, voluntary and coercive, and inclusionary and marginalizing. The paper concludes that these technologies have divested exchange of mutuality, as the totemic features of neoliberal regulation - standards, procedures and protocols - increasingly render north south partnerships ever more virtual and depoliticized.     

The IAU 2009 system of astronomical constants: the report of the IAU working group on numerical standards for Fundamental Astronomy

In the 2006?C2009 triennium, the International Astronomical Union (IAU) Working Group on Numerical Standards for Fundamental Astronomy determined a list of Current Best Estimates (CBEs). The IAU 2009 Resolution B2 adopted these CBEs as the IAU (2009) System of Astronomical Constants. Additional work continues to define the process of updating the CBEs and creating a standard electronic document.     

Effects of salinity on sublethal toxicity of atrazine to mummichog (Fundulus heteroclitus) larvae

In coastal marshes, fish larvae may be exposed simultaneously to extreme salinities and to atrazine, a widely used herbicide. To assess the effects of salinity on the toxicity of atrazine, newly-hatched mummichog (Fundulus heteroclitus) were exposed to atrazine (0, 5, 50 and 500 microg/L) at three salinities (3, 15 and 35PSU). Whole body cortisol was measured after 24 h. Body length, condition factor, whole body proteins, lipids, residual masses and water contents were assessed after 96 h. Significants effects were found for both condition factor and water content. Condition factors were lower at salinity 3 and 35 compared to near isoosmotic salinity, 15PSU. In addition, atrazine decreased condition factor at 500 microg/L. Reduction in condition was likely due to retardation in axial growth since body length, percentages of proteins or lipids were not affected. In the absence of atrazine, salinity had no effect on the prevalence of dehydrated (81% water) or hyperhydrated (85% water) larvae. In larvae exposed to atrazine, the prevalence of hyperhydrated larvae increased at 3PSU and 5 microg/L atrazine and that of dehydrated larvae increased at 15 and 35PSU and 5 microg/L atrazine. Severity of dehydratation increased with atrazine concentration at salinity 35PSU. Thus, a short-term exposure to environmentally realistic concentrations of atrazine affects osmotic control in mummichog larvae with possible effects on buoyancy, survival and recruitment.     

Sedimentary fabric characterized by X-ray tomography: A case-study from tsunami deposits on the Marquesas Islands,French Polynesia

X-ray tomography is used to analyse the grain size and sedimentary fabric of two tsunami deposits in the Marquesas Islands (French Polynesia, Pacific Ocean) which are particularly exposed to trans-Pacific tsunamis. One site is located on the southern coast of Nuku Hiva Island (Hooumi) and the other one is on the southern coast of Hiva Oa Island (Tahauku). Results are compared with other techniques such as two-dimensional image analysis on bulk samples (particle analyser) and anisotropy of magnetic susceptibility. The sedimentary fabric is characterized through three-dimensional stacks of horizontal slices (following a vertical step of 2·5 mm along the cores), while grain-size distribution is estimated from two-dimensional vertical slices (following a step of 2 mm). Four types of fabric are distinguished: (a) moderate to high angle (15 to 75°); (b) bimodal low-angle (<15°); (c) low to high angle with at least two different orientations; and (d) dispersed fabric. The fabric geometry in a tsunami deposit is not only controlled by the characteristics of the flow itself (current strength, flow regime, etc.) but also sediment concentration, deposition rate and grain-size distribution. There is a notable correlation between unimodal high-angle fabric – type (a) – and finely-skewed grain-size distribution. The two tsunami deposits studied represent two different scenarios of inundation. As demonstrated here, X-ray tomography is an essential method for characterizing past tsunamis from their deposits. The method can be applied to many other types of sediments and sedimentary rocks.