Geochemical controls on sediment reactivity and buffering processes in a heterogeneous aquifer

The injection and recovery of oxic water into deep anoxic aquifers may help to alleviate short- and long-term imbalance between freshwater supply and demand. The extent and structure of physical and geochemical heterogeneity of the aquifer will impact the water quality evolution during injection, storage and recovery. Water–sediment interactions within the most permeable parts of the aquifer, where the bulk of the injectant will penetrate, may dominate, however, water quality may also be impacted by interactions within the finer-grained, less permeable but potentially highly reactive media. In this study, the heterogeneity of the reductive capacity of an aquifer selected for water reuse projects was characterised, the amount, type and reactivity of the sedimentary reductants present determined, and the relationship between reductive capacity and sedimentary lithologies quantified. The average potential reductive capacities (PRC_TOT), based on total organic C and pyrite concentrations of the sediment, were quantified for sands (382 μmol O₂ g⁻¹), clays (1522 μmol O₂ g⁻¹), and silts (1957 μmol O₂ g⁻¹). Twenty-seven samples, spanning the three different lithologies, were then incubated for 50 days and the measured reductive capacities (MRC) determined for the sands (29.2 μmol O₂ g⁻¹), silts (136 μmol O₂ g⁻¹), and clays (143 μmol O₂ g⁻¹). On average, the MRC were 10% of the PRC_TOT. The main consumers of O₂ were pyrite (20–100%), sedimentary organic matter (SOM; 3–56%), siderite (3–28%) and Fe(II)-aluminosilicates (8–55%). The incubation data plus hydrogeochemical modelling, indicated that pH-buffering was controlled firstly by dissolution of trace level carbonates, followed by dissolution of feldspars. Zinc, Co, Ni, Cd and Pb were readily mobilized during incubation.     

Preheat Issues in Hydrodynamic Hedla Experiments

Hydrodynamic experiments have become a very active area within High Energy Density Laboratory Astrophysics. In such experiments, preheat of an interior surface due to heating prior to shock arrival can alter the initial conditions for further evolution and can change the nature of the experiment (Olson et al., 2003). Unfortunately, preheat cannot typically be detected without undertaking dedicated experiments for this purpose. We have designed such experiments, relevant to hydrodynamic instability experiments using Omega Laser at intensities of ~10¹⁵ W/cm². Simulations using the HYADES code suggest that radiative preheat alone causes the interface to move approximately 2 μm before the blast wave reaches it. Hot-electron preheat could cause much larger motions. These experiments will use VISAR to examine the motion of an aluminum sample layer at the rear interface of a standard hydrodynamic target during the period before the shock reaches it (Allen and Burton, 1993).     

Waves in Jupiter's atmosphere observed by the Cassini ISS and CIRS instruments

The Cassini Imaging Science Subsystem (ISS) and Composite Infrared Spectrometer (CIRS) reported a North Equatorial Belt (NEB) wave in Jupiter's atmosphere from optical images [Porco, C.C., and 23 colleagues, 2003. Science 299, 1541-1547] and thermal maps [Flasar, F.M., and 39 colleagues, 2004. Nature 427, 132-135], respectively. The connection between the two waves remained uncertain because the two observations were not simultaneous. Here we report on simultaneous ISS images and CIRS thermal maps that confirm that the NEB wave shown in the ISS ultraviolet (UV1) and strong methane band (MT3) images is correlated with the thermal wave in the CIRS temperature maps, with low temperatures in the CIRS maps (upwelling) corresponding to dark regions in the UV1 images (UV-absorbing particles) and bright regions in the MT3 images (high clouds and haze). The long period of the NEB wave suggests that it is a planetary (Rossby) wave. The combined observations from the ISS and CIRS are utilized to discuss the vertical and meridional propagation of the NEB wave, which offers a possible explanation for why the NEB wave is confined to specific latitudes and altitudes. Further, the ISS UV1 images reveal a circumpolar wave centered at 48.5° S (planetocentric) and probably located in the stratosphere, as suggested by the ISS and CIRS observations. The simultaneous comparison between the ISS and CIRS also implies that the large dark oval in the polar stratosphere of Jupiter discovered in the ISS UV1 images [Porco, C.C., and 23 colleagues, 2003. Science 299, 1541-1547] is the same feature as the warm regions at high northern latitudes in the CIRS 1-mbar temperature maps [Flasar, F.M., and 39 colleagues, 2004. Nature 427, 132-135]. This comparison supports a previous suggestion that the dark oval in the ISS UV1 images is linked to auroral precipitation and heating [Porco, C.C., and 23 colleagues, 2003. Science 299, 1541-1547].     

Assessing Mix Layer Amplitude in 3D Decelerating Interface Experiments

We present data from recent high-energy-density laboratory experiments designed to explore the Rayleigh–Taylor instability under conditions relevant to supernovae. The Omega laser is used to create a blast wave structure that is similar to that of the explosion phase of a core-collapse supernova. An unstable interface is shocked and then decelerated by the planar blast wave, producing Rayleigh–Taylor growth. Recent experiments were performed using dual, side-on, x-ray radiography to observe a 3D “egg crate” mode and an imposed, longer-wavelength, sinusoidal mode as a seed perturbation. This paper explores the method of data analysis and accurately estimating the position of important features in the data.     

What drives national adaptation? A global assessment

That the climate is changing and societies will have to adapt is now unequivocal, with adaptation becoming a core focus of climate policy. Our understanding of the challenges, needs, and opportunities for climate change adaptation has advanced significantly in recent years yet remains limited. Research has identified and theorized key determinants of adaptive capacity and barriers to adaptation, and more recently begun to track adaptation in practice. Despite this, there is negligible research investigating whether and indeed if adaptive capacity is translating into actual adaptation action. Here we test whether theorized determinants of adaptive capacity are associated with adaptation policy outcomes at the national level for 117 nations. We show that institutional capacity, in particular measures of good governance, are the strongest predictors of national adaptation policy. Adaptation at the national level is limited in countries with poor governance, and in the absence of good governance other presumed determinants of adaptive capacity show limited effect on adaptation. Our results highlight the critical importance of institutional good governance as a prerequisite for national adaptation. Other elements of theorized adaptive capacity are unlikely to be sufficient, effective, or present at the national level where national institutions and governance are poor.     

Design and Production of an Atlas for Diplomacy in Zimbabwe and The Southern African Development Community

Abstract

An atlas of Zimbabwe and the Southern African Development Community was designed and produced for use by American diplomats in Zimbabwe. Two copies of the bound atlas are used by the Embassy of the United States of America (U.S. Embassy) and the Mission of the U.S. Agency for International Development (USAID) in Harare, Zimbabwe, to orient visitors and discuss matters of diplomacy and development in Zimbabwe and the Southern African Development Community. The atlas contains maps derived from satellite images showing features of the physical geography of Southern Africa and Zimbabwe and plastic overlays showing rivers and lakes and manmade features, such as major roads, railroads, and cities. The atlas is an important tool that American diplomats can use to orient participants in discussions of the environment and to develop agreements for management of the environment in Zimbabwe and Southern Africa.     

A soil moisture monitoring network to assess controls on runoff generation during atmospheric river events

Soil moisture is a key modifier of runoff generation from rainfall excess, including during extreme precipitation events associated with Atmospheric Rivers (ARs). This paper presents a new, publicly available dataset from a soil moisture monitoring network in Northern California's Russian River Basin, designed to assess soil moisture controls on runoff generation under AR conditions. The observations consist of 2-min volumetric soil moisture at 19 sites and 6 depths (5, 10, 15, 20, 50, and 100 cm), starting in summer 2017. The goals of this monitoring network are to aid the development of research applications and situational awareness tools for Forecast-Informed Reservoir Operations at Lake Mendocino. We present short analyses of these data to demonstrate their capability to characterize soil moisture responses to precipitation across sites and depths, including time series analysis, correlation analysis, and identification of soil saturation thresholds that induce runoff. Our results show strong inter-site Pearson's correlations (>0.8) at the seasonal timescale. Correlations are strong (>0.8) during events with high antecedent soil moisture and during drydown periods, and weak (<0.5) otherwise. High event runoff ratios are observed when antecedent soil moisture thresholds are exceeded, and when antecedent runoff is high. Although local heterogeneity in soil moisture can limit the utility of point source data in some hydrologic model applications, our analyses indicate three ways in which soil moisture data are valuable for model design: (1) sensors installed at 6 depths per location enable us to identify the soil depth below which evapotranspiration and saturation dynamics change, and therefore choose model soil layer depths, (2) time series analysis indicates the role of soil moisture processes in controlling runoff ratio during precipitation, which hydrologic models should replicate, and (3) spatial correlation analysis of the soil moisture fluctuations helps identify when and where distributed hydrologic modelling may be beneficial.     

Conflicts at sea between artisanal and industrial fishers: Inter-sectoral interactions and dispute resolution in Senegal

Conflicts between artisanal and industrial fishermen—targeting increasingly scarce resources in Senegal—are posing a serious threat to human security and are only symbolically addressed by the country's fisheries governance regime. Severely outmatched in terms of political influence and size, artisanal fishermen are more vulnerable to the fallout of conflicts at sea. The loss of fishing materials threatens the livelihoods of fishermen and their families; collisions and violence between members of the two sectors often result in injury and death. This study examines at-sea interactions between Senegal's artisanal and industrial sectors and the formal and informal mechanisms in place for managing them. Conflictive interactions are found to co-exist alongside cooperative ones and both emerge in response to changes in marine resource abundance and management. Formal systems in place to mediate at-sea conflicts are ineffective and seldom used by artisanal fishermen, who either accept their losses, attempt to informally resolve conflicts with industrial actors or resort to violence.