Some thermodynamical and microphysical aspects of monsoon clouds

The thermodynamical and microphysical characteristics of monsoon clouds in the Poona, Bombay and Rihand regions were investigated using extensive aircraft in-cloud observations. The number of clouds sampled at Poona, Bombay and Rihand is 2199, 169 and 104 respectively. The temperatures inside the cloud are colder than its environment at Poona and Rihand. The maximum difference is about 3°C at the cloud base level and the difference decreased with height. At Bombay the difference is less than 1°C and at some levels the temperatures inside the cloud are warmer than its environment. The lapse rates of temperatures inside the cloud are slightly less than those in the immediate environment of the cloud. The environmental lapse rates are nearly equal to the saturated adiabatic value. The positive increments in liquid water content (LWC) are associated with the increments in temperature inside the cloud. Similarly positive increments in temperatures inside the cloud are associated with the increments in temperature of its immediate environment at the same level or the layer immediately above. The maximum cloud lengths observed at Poona and Bombay respectively are 14 and 3 km. The horizontal cross-section of LWC showed a maximum number of 13 peaks in clouds at Poona while only 7 peaks were observed at Bombay. The location of maximum LWC in the horizontal cross-section is more or less at the centre of the cloud. The LWC profile showed an increase with height from the base of the cloud at Poona and Bombay. There is no marked variation of LWC with height at Rihand. The total droplet concentration at different altitudes at Poona and Bombay is in the range 28–82 cm^?3. The size distribution of cloud droplets experienced a broadening effect with increase in height from the cloud base at Poona. The broadening effect at Bombay is not as marked as that at Poona.     

Generation of correlated properties in heterogeneous porous media

The spatial distribution of rock properties in porous media, such as permeability and porosity, often is strongly variable. Therefore, these properties usefully may be considered as a random field. However, this variability is correlated frequently on length scales comparable to geological lengths (for example, scales of sand bodies or facies). To solve various engineering problems (for example, in the oil recovery process) numerical models of a porous medium often are used. A need exists then to understand correlated random fields and to generate them over discretized numerical grids. The paper describes the general mathematical methods required to do this, with one particular method (the nearest neighbor model) described in detail. How parameters of the mathematical model may be related to rock property statistics for the nearest neighbor model is shown. The method is described in detail in one, two, and three dimensions. Examples are given of how model parameters may be determined from real data.     

The Coolgardie Goldfied,Western Australia: district-scale controls on an Archaean gold camp in an amphibolite facies terrane

Archaean lode gold deposits in the Coolgardie Goldfield, Western Australia, occur in mafic and ultramafic rocks which have been metamorphosed to the amphibolite facies. Mineralisation was broadly synchronous with peak metamorphism, the main phase of granitoid emplacement, and regional deformation. Several different structural styles are represented by the deposits of the Coolgardie Goldfield. Mineralisation occurs along sheared felsic porphyry-ultramafic rock contacts, in gabbro-hosted quartz-vein sets, in fault-bounded quartzvein sets, and in laminated quartz reefs sited in brittleductile shear zones. The structures hosting mineralisation formed in response to a progressive deformation event, related to granitoid emplacement in an east-west compressional far-field stress régime, but with local heterogeneous stress orientations. This occurred after an earlier period of thrust-stacking, with probable north-south directed tectonic transport. Two contrasting styles of goldrelated wallrock alteration are associated with the auriferous lodes of the Coolgardie Goldfield. A high-temperature assemblage (formation temperature >500°C), characterised by the proximal alteration assemblage garnet+ hornblende + plagioclase + pyrrhotite, contrasts with a medium-temperature assemblage (formation temperature <500°C), consisting of calcic amphibole + biotite + plagioclase + calcite + arsenopyrite + pyrrhotite. The distribution of the two styles of gold-related alteration is controlled by distance from voluminous syntectonic granitoids located to the west of the Coolgardie Goldfield, with the high-temperature style of alteration more proximal to the granitoid-greenstone contact than the medium-temperature style. The occurrence of gold deposits that formed under amphibolite facies conditions throughout the Coolgardie Goldfield supports a crustal continuum model for Archaean lode-gold deposits, which proposes that gold is deposited in metamorphic environments that range from the sub-greenschist to granulite facies. In addition, the data from Coolgardie suggest that syntectonic, synmineralisation granitic plutons may play a significant role in controlling the style of gold associated wallrock-alteration at deep crustal levels.     

Source(s) and cycling of the nonhydrolyzable organic fraction of oceanic particles

A major fraction of particulate organic carbon (POC) in the deep ocean remains molecularly uncharacterized. In an effort to determine the chemical characteristics and source(s) of sinking POC, we studied a nonhydrolyzable fraction of sinking POC using ¹³C NMR (nuclear magnetic resonance) spectroscopy and analytical pyrolysis. ¹³C NMR spectra and products from analytical pyrolysis of the nonhydrolyzable fraction exhibit a strongly aliphatic character that is distinct from that of bulk POC. The aliphatic nature of this fraction is consistent with its low stable carbon isotope values. We hypothesize that the nonhydrolyzable fraction derives to a significant extent from a refractory component of organisms that selectively accumulates, resulting in its manifestation as a major part of POC sinking to the deep ocean and in underlying sediments.     

The geochemistry of uranium occurrences and speciation in groundwater of Chinnar sub basin,South India

An attempt has been made in Chinnar sub basin of Dharmapuri district, South India to isolate the geochemistry of uranium occurrences in groundwater. The geology of the area is mainly of charnockite and granite gneiss. Groundwater samples were collected for two different seasons post and pre monsoon in two different litho units (granite gneiss and charnockite) and analysed for major, minor and uranium concentrations. Higher uranium (18.45 μg L^?1) has been recorded during pre monsoon season in granite gneiss with increasing pH. The saturation index calculation for the groundwater isolated minerals like uaraninite, coffinite, haiweeite and soddyite to be precipitating and uranium oxides like UO_2.25, UO_2.25beta, UO_2.33beta as oversaturated. The Eh-pH diagram attempted represents solubility of uraninite within the pH range of 6.0 to 8.0. The study isolate uranium in groundwater of the study area is controlled by the presence of (U₄O₉) uranium oxide.     

Factors controlling the adsorption of acid blue 113 dye from aqueous solution by dried <Emphasis Type="Italic">C. edulis</Emphasis> plant as natural adsorbent

Contamination of surface water and groundwater by organic pollutants is a serious problem due to their persistence, bioaccumulation and biomagnification through food webs. Since the removal of dyes from wastewater is considered an environmental challenge and government legislation requires textile wastewater to be treated, therefore there is a constant need to have an effective process that can efficiently remove these dyes. The aim of the present study is to evaluate the potentiality of dried Carpobrotus edulis plant as low-cost adsorbent for the removal of the industrial acid blue 113 dye from aqueous solutions using the batch equilibration technique. The effects of different physicochemical parameters such as adsorbent dose, contact time, initial dye concentration, solution pH and temperature on adsorption rate of anionic AB113 dye on microparticles of dried C. edulis plant were investigated. The experimental data were analyzed by using mathematical models to determine the thermodynamic parameters. The negative values of free energy change indicated the spontaneous nature of the adsorption and negative value of enthalpy change suggested the exothermic nature of the adsorption process. These results indicate that dried C. edulis plant as an environmentally friendly adsorbent could be potentially used for the removal of anionic dyes from aqueous solutions.     

Hydrothermal bitumen generated from sedimentary organic matter of rift lakes – Lake Chapala, Citala Rift, western Mexico

Lake Chapala is in the Citala Rift of western Mexico, which in association with the Tepic-Zacoalco and Colima Rifts, form the well-known neotectonic Jalisco continental triple junction. The rifts are characterized by evidence for both paleo- and active hydrothermal activity. At the south shore of the lake, near the Los Gorgos sublacustrine hydrothermal field, there are two tar emanations that appear as small islands composed of solid, viscous and black bitumen. Aliquots of tar were analyzed by GC-MS and the mixtures are comprised of geologically mature biomarkers and an UCM. PAH and n-alkanes are not detectable. The biomarkers consist mainly of hopanes, gammacerane, tricyclic terpanes, carotane and its cracking products, steranes, and drimanes. The biomarker composition and bulk C isotope composition (δ¹³C = −21.4%) indicate an organic matter source from bacteria and algae, typical of lacustrine ecosystems. The overall composition of these tars indicates that they are hydrothermal petroleum formed from lacustrine organic matter in the deeper sediments of Lake Chapala exceeding 40 ka (¹⁴C) in age and then forced to the lakebed by tectonic activity. The absence of alkanes and the presence of an UCM with mature biomarkers are consistent with rapid hydrothermal oil generation and expulsion at temperatures of 200–250 °C. The occurrence of hydrothermal petroleum in continental rift systems is now well known and should be considered in future energy resource exploration in such regions.     

Multi-isotopic (Li,B, Sr,Nd) approach for geothermal reservoir characterization in the Limagne Basin (Massif Central,France)

A multi-isotopic study of thermo-mineral waters from the Limagne Basin (French Massif Central) is reported. Lithium, B, Sr and Nd isotopic signatures in thermo-mineral waters and bedrocks were combined in order to determine the origin of these fluids from a reservoir point of view. Strontium and Nd isotopic systems showed that the thermo-mineral waters are mostly derived from a granitic reservoir type, with the exception of a few water samples having Sr and Nd isotopic signatures also reflecting a volcanic contribution (basalts). In a second step, Li and B isotopes were investigated, given that Li and B isotopic systematics are potentially affected by mass dependent fractionation during water/rock interaction and could provide some information on what takes place during this process. A great diversity of thermo-mineral waters within the Aigueperse area was clearly observed, which is directly related to the origin of these thermal waters in terms of reservoirs. These different geothermal reservoirs are characterized by different geological settings and intensity of water/rock interaction (i.e. depth and temperature).