The infrared dielectric properties of maghemite, γ-Fe2O3, from reflectance measurement on pressed powders

The infrared complex permittivity functions of three varieties of maghemite, γ-Fe₂O₃, having different degrees of vacancy ordering, have been determined from their IR reflectance spectra, measured at near to normal incidence on pressed powder pellets. The optical constants therefrom obtained have been verified by using them in the simulation of the corresponding absorption spectra for KBr-diluted pellets, and these are in excellent agreement with the experimental spectra. All calculations are based on a procedure for the estimation of the effective dielectric function of a mixture, which incorporates percolation features, recently developed by the authors.     

Comparison of statistically downscaled precipitation in terms of future climate indices and daily variability for southern Ontario and Quebec,Canada

Given the coarse resolution of global climate models, downscaling techniques are often needed to generate finer scale projections of variables affected by local-scale processes such as precipitation. However, classical statistical downscaling experiments for future climate rely on the time-invariance assumption as one cannot know the true change in the variable of interest, nor validate the models with data not yet observed. Our experimental setup involves using the Canadian regional climate model (CRCM) outputs as pseudo-observations to estimate model performance in the context of future climate projections by replacing historical and future observations with model simulations from the CRCM, nested within the domain of the Canadian global climate model (CGCM). In particular, we evaluated statistically downscaled daily precipitation time series in terms of the Peirce skill score, mean absolute errors, and climate indices. Specifically, we used a variety of linear and nonlinear methods such as artificial neural networks (ANN), decision trees and ensembles, multiple linear regression, and k-nearest neighbors to generate present and future daily precipitation occurrences and amounts. We obtained the predictors from the CGCM 3.1 20C3M (1971–2000) and A2 (2041–2070) simulations, and precipitation outputs from the CRCM 4.2 (forced with the CGCM 3.1 boundary conditions) as predictands. Overall, ANN models and tree ensembles outscored the linear models and simple nonlinear models in terms of precipitation occurrences, without performance deteriorating in future climate. In contrast, for the precipitation amounts and related climate indices, the performance of downscaling models deteriorated in future climate.     

Response of single benthic metrics and multi-metric methods to anthropogenic pressure gradients, in five distinct European coastal and transitional ecosystems

In recent times many benthic indices have been proposed to assess the ecological quality of marine waters worldwide. In this study we compared single metrics and multi-metric methods to assess coastal and transitional benthic status along human pressure gradients in five distinct environments across Europe: Varna bay and lake (Bulgaria), Lesina lagoon (Italy), Mondego estuary (Portugal), Basque coast (Spain) and Oslofjord (Norway). Hence, 13 single metrics (abundance, number of taxa, and several diversity and sensitivity indices) and eight of the most common indices used within the European Water Framework Directive (WFD) for benthic assessment were selected: index of size spectra (ISS), Benthic assessment tool (BAT), Norwegian quality index (NQI), Multivariate AMBI (M-AMBI), Benthic quality index (BQI), (Benthic ecosystem quality index (BEQI), Benthic index based on taxonomic sufficiency (BITS), and infaunal quality index (IQI). Within each system, sampling sites were ordered in an increasing pressure gradient according to a preliminary classification based on professional judgement. The different indices are largely consistent in their response to pressure gradient, except in some particular cases (i.e. BITS, in all cases, or ISS when a low number of individuals is present). Inconsistencies between indicator responses were most pronounced in transitional waters (i.e. IQI, BEQI), highlighting the difficulties of the generic application of indicators to all marine, estuarine and lagoonal environments. However, some of the single (i.e. ecological groups approach, diversity, richness) and multi-metric methods (i.e. BAT, M-AMBI, NQI) were able to detect such gradients both in transitional and coastal environments, being these multi-metric methods more consistent in the detection than single indices. This study highlights the importance of survey design and good reference conditions for some indicators. The agreement observed between different methodologies and their ability to detect quality trends across distinct environments constitutes a promising result for the implementation of the WFD’s monitoring plans. Moreover, these results have management implications, regarding the dangers of misclassification, uncertainty in the assessment, use of conflicting indices, and testing and validation of indices.     

Possible climatic impacts of tropical deforestation

Large-scale conversion of tropical forests into pastures or annual crops will likely lead to changes in the local microclimate of those regions. Larger diurnal fluctuations of surface temperature and humidity deficit, increased surface runoff during rainy periods and decreased runoff during the dry season, and decreased soil moistrue are to be expected.It is likely that evapotranspiration will be reduced because of less available radiative energy at the canopy level since grass presents a higher albedo than forests, also because of the reduced availability of soil moisture at the rooting zone primarily during the dry season. Recent results from general circulation model (GCM) simulations of Amazonian deforestation seem to suggest that the equilibrium climate for a grassy vegetation in Amazonia would be one in which regional precipitation would be significantly reduced.Global climate changes probably will occur if there is a marked change in rainfall patterns in tropical forest regions as a result of deforestation. Besides that, biomass burning of tropical forests is likely adding CO₂ into the atmosphere, thus contributing to the enhanced greenhouse warming.     

Estimating Buoyancy Heat Flux Using the Surface Renewal Technique over Four Amazonian Forest Sites in Brazil

The surface renewal (SR) method was applied for the first time to measurements of air temperature over four Amazonian forest sites and different seasons in order to obtain estimates of buoyancy heat flux. The required calibration of this method against eddy covariance resulted in a value for a specific parameter that is close to the range reported in other studies, contributing to the generalization of the SR method to different kinds of canopies. The comparison with fluxes obtained using the eddy covariance technique revealed a good match between the two methods for different sites, heights and seasons. Sites with high levels of non-stationarity in the signals of temperature and wind speed presented higher scatter in the regression with fluxes from eddy covariance. For a particular site with previously reported influence of low-frequency motions, the regression was only satisfactory, i.e., slope parameter close to unity and small offset, when oscillations with periods longer than $\approx $ ≈ 13 min were filtered out. The SR method has a great potential due to the simplicity of the instrumentation required. However, care should be taken when measuring under the influence of mesoscale motions, which can lead to high levels of non-stationarity, compromising the fundamental concepts of the SR theory.     

Application of Distributed Temperature Sensing for coupled mapping of sedimentation processes and spatio‐temporal variability of groundwater discharge in soft‐bedded streams

The delineation of groundwater discharge areas based on Distributed Temperature Sensing (DTS) data of the streambed can be difficult in soft‐bedded streams where sedimentation and scouring processes constantly change the position of the fibre optic cable relative to the streambed. Deposition‐induced temperature anomalies resemble the signal of groundwater discharge while scouring will cause the cable to float in the water column and measure stream water temperatures. DTS applied in a looped layout with nine fibre optic cable rows in a 70 × 5 m section of a soft‐bedded stream made it possible to detect variability in streambed temperatures between October 2011 and January 2012. Detailed monthly streambed elevation surveys were carried out to monitor the position of the fibre optic cable relative to the streambed and to quantify the effect of sedimentation processes on streambed temperatures. Based on the simultaneous interpretation of streambed temperature and elevation data, a method is proposed to delineate potential high‐groundwater discharge areas and identify deposition‐induced temperature anomalies in soft‐bedded streams. Potential high‐discharge sites were detected using as metrics the daily minimum, maximum and mean streambed temperatures as well as the daily amplitude and standard deviation of temperatures. The identified potential high‐discharge areas were mostly located near the channel banks, also showing temporal variability because of the scouring and redistribution of streambed sediments, leading to the relocation of pool‐riffle sequences. This study also shows that sediment deposits of 0.1 m thickness already resulted in an increase in daily minimum streambed temperatures and decrease in daily amplitude and standard deviation. Scouring sites showed lower daily minimum streambed temperatures and higher daily amplitude and standard deviation compared with areas without sedimentation and scouring. As a limitation of the approach, groundwater discharge occurring at depositional and scouring areas cannot be identified by the metrics applied. Copyright © 2015 John Wiley & Sons, Ltd.     

Improved algorithms for generalized finite element simulations of three-dimensional hydraulic fracture propagation

This paper reports improvements to algorithms for the simulation of 3-D hydraulic fracturing with the Generalized Finite Element Method (GFEM). Three optimizations are presented and analyzed. First, an improved initial guess based on solving a 3-D elastic problem with the pressure from the previous step is shown to decrease the number of Newton iterations and increase robustness. Second, an improved methodology to find the time step that leads to fracture propagation is proposed and shown to decrease significantly the number of iterations. Third, reduced computational cost is observed by properly recycling the linear part of the coupled stiffness matrix. Two representative examples are used to analyze these improvements. Additionally, a methodology to include the leak-off term is presented and verified against asymptotic analytical solutions. Conservation of mass is shown to be well satisfied in all examples.     

Coastal Occupations in Tierra del Fuego,Southernmost South America: A Late Holocene Hunter‐Gatherer Context at Marazzi 2

This paper focuses on the late Holocene occupation of hunter‐gatherers at the Marazzi 2 site located on the northwestern steppe of Tierra del Fuego, Chile. Our aim is to understand stratigraphy, formation processes, and pedogenesis with respect to human occupation over the last 3000 years. Based on archaeological excavations on a fluvial terrace of the Torcido River, we integrate soil micromorphology, mineralogy, geochemistry, magnetic susceptibility, and geomorphology, as well as the micro‐ and macrofrequency distributions of archaeological material. A micro‐taphonomical perspective is also applied to anthropogenic components recorded in sedimentary thin sections. We discuss various events in the interplay between soil development and human occupation through time. Marazzi 2 was witness to aggradation and pedogenesis with an episode of surface stability coincident with a phase of more intense human occupation at about 860 BC. Taphonomic analysis suggests that there are multiple occupation events mixed together, probably by biomechanical processes, resulting in a palimpsest with poor temporal resolution.