The behavior of trace elements during schwertmannite precipitation and subsequent transformation into goethite and jarosite

Schwertmannite is a ubiquitous mineral formed from acid rock drainage (ARD), and plays a major role in controlling the water chemistry of many acid streams. The formation of schwertmannite was investigated in the acid discharge of the Monte Romero abandoned mine (Iberian Pyrite Belt, SW, Spain). Schwertmannite precipitated from supersaturated solutions mainly owing to the oxidation of Fe(II) to Fe(III) and transformed with time into goethite and jarosite. In a few hours, schwertmannite precipitation removed more than half of the arsenic load from solution, whereas the concentration of divalent trace metals (Zn, Cu, Pb, Cd, Ni, and Co) remained almost unchanged. In the laboratory, natural schwertmannite was kept in contact with its coexisting acid water in a flask with a solid-liquid mass ratio of 1:5 for 353 days. During this time, the pH of the solution dropped from 3.07 to 1.74 and the concentrations of sulfate and Fe increased. During the first 164 days, schwertmannite transformed into goethite plus H₃O-jarosite but, subsequently, goethite was the only mineral to form. Some of the trace elements, such as Al, Cu, Pb, and As were depleted in solution during the first stage as schwertmannite transformed into goethite plus H₃O-jarosite. On the contrary, the transformation of schwertmannite to goethite (with no jarosite) during the second stage released Al, Cu, and As to the solution. Despite the variation in their concentrations in solution, approximately 80% of the total Al and Cu inventories and more than 99% As and Pb remained in the solid phase throughout the entire aging process.     

Modeling nonlinear seagrass clonal growth: Assessing the efficiency of space occupation across the seagrass flora

The clonal growth of 9 seagrass species was modeled using a simulation model based on observed clonal growth rules (i.e., spacer length, rhizome elongation rates, branching rates, branching angle) and shoot mortality rates for seagrass species. The results of the model confirmed the occurrence of complex, nonlinear growth of seagrass clones derived from internal dynamics of space occupation. The modeled clones progressed from a diffuse-limited aggregation (DLA), dendritic growth, identified with a guerrilla strategy of space occupation, to a compact (Eden) growth, comparable to the phalanx strategy of space occupation, once internal recolonization of gaps, left by dead shoots within the clone, begins. The time at which seagrass clones shifted from diffuse limited to compact growth was predictable from the branching angle and frequency of the species and varied from 1 yr to several decades among species. As a consequence the growth behavior and the apparent growth strategy of the species changes with the development of the clones. The results of the model demonstrate that the emergent complexity of seagrass clonal growth is contained within the simple set of growth rules that can be used to represent clonal growth.     

Daily Meteorological Observations in Cádiz – San Fernando. Analysis of the Documentary Sources and the Instrumental Data Content (1786–1996)

Meteorological observations in the city of Cádiz are acknowledged as having been made from the middle of the 18th century onwards although they were only recorded and preserved in documentary form from 1789 onwards. Data readings were taken at the new Naval Observatory in San Fernando, ten kilometres from Cádiz, from 1797 onwards. Continuous series for temperature and atmospheric pressure at a daily resolution have been compiled and constructed from 1817 until 1996. The data series is composed of thrice daily observations made at Cádiz (1821–1880) by local observers and hourly data from Naval Observatory at San Fernando (1870–1996).     

Groundwater-flow modeling in the Yucatan karstic aquifer, Mexico

The current conceptual model of the unconfined karstic aquifer in the Yucatan Peninsula, Mexico, is that a fresh-water lens floats above denser saline water that penetrates more than 40 km inland. The transmissivity of the aquifer is very high so the hydraulic gradient is very low, ranging from 7–10 mm/km through most of the northern part of the peninsula. The computer modeling program AQUIFER was used to investigate the regional groundwater flow in the aquifer. The karstified zone was modeled using the assumption that it acts hydraulically similar to a granular, porous medium. As part of the calibration, the following hypotheses were tested: (1) karstic features play an important role in the groundwater-flow system; (2) a ring or belt of sinkholes in the area is a manifestation of a zone of high transmissivity that facilitates the channeling of groundwater toward the Gulf of Mexico; and (3) the geologic features in the southern part of Yucatan influence the groundwater-flow system. The model shows that the Sierrita de Ticul fault, in the southwestern part of the study area, acts as a flow barrier and head values decline toward the northeast. The modeling also shows that the regional flow-system dynamics have not been altered despite the large number of pumping wells because the volume of water pumped is small compared with the volume of recharge, and the well-developed karst system of the region has a very high hydraulic conductivity. Electronic Publication     

Spatial and temporal variation of the nekton and hyperbenthos from a temperate European estuary with regulated freshwater inflow

The aquatic macrofauna of the Guadalquivir estuary were sampled (1 mm mesh persiana net) at 5 sampling sites located along the entire (except the tidal freshwater region) estuarine gradient of salinity (outer 50 km). A total of 134 fish and macroinvertebrate species was collected but only 62 were considered common or regularly present in the estuary. Univariate measures of the community structure showed statistically significant differences among sampling sites: species richness, abundance, and biomass decreased in the upstream direction, being positively correlated with the salinity. Temporal differences of these three variables were also statistically significant. While a clear seasonal pattern (minimum densities in winter and maximum in spring-summer) was observed for abundance and biomass, no such pattern existed for the number of species. Mysids was the most dominant group throughout the estuary (96% to 99% of abundance; 49% to 85% of biomass), although fish biomass was also important at the outer estuary (36% to 38%). Multivariate analyses indicated highly significant spatial variation in the macrofaunal communities observed along the salinity gradient. These analyses suggest that the underlying structure was a continuum with more or less overlapping distributions of the species dependent on their ability to tolerate different physicochemical conditions. There were also significant temporal (intermonthly + interannual) variation of the estuarine community; the relative multivariate dispersion indicated that monthly variation was more considerable (relative multivariate dispersion >1) at the outer part of the estuary during the wet year (last 20 km) and was higher in the inner stations during the dry year (32 to 50 km from the river mouth). Since a clear negative exponential relationship was observed between the freshwater input (from a dam located 110 km upstream) and water salinity at all sampling stations, it is concluded that the human freshwater management is probably affecting the studied estuarine communities. While the higher seasonal (long-term) stability of the salinity gradient, due to the human control of the freshwater input, may facilitate the recruitment of marine species juveniles during the meteorologically unstable early-spring, the additional (short-term) salinity fluctuations during the warm period may negatively affect species that complete their lifecycle within the estuary.     

A 1500-year record of climatic and environmental change in ElkLake, Minnesota I: Varve thickness and gray-scale density

The deepest part (29.5 m) of Elk Lake, ClearwaterCounty, northwestern Minnesota, contains a complete Holocene section that iscontinuously varved. The varve components are predominantly autochthonous(CaCO₃, organic matter, biogenic silica, and several iron andmanganese minerals), but the varves do contain a minor detrital-clastic(aluminosilicate) component that is predominantly wind-borne (eolian) andprovides an important record of atmospheric conditions. Singular spectrumanalysis (SSA) and wavelet analysis of varve thickness recognized significantperiodicities in the multicentennial and multidecadal bands that varied inpower (i.e., variable significance) and position (i.e., variable period) withinthe periodic bands. Persistent periodicities of about 10, 22, 40, and 90 years,and, in particular, multicentennial periodicities in varve thickness and otherproxy variables are similar to those in spectra of radiocarbon production, aproxy for past solar activity. This suggests that there may be a solar control,perhaps through geomagnetic effects on atmospheric circulation. Multicentennialand multidecadal periodicities also occur in wavelet spectra of relativegray-scale density. However, gray-scale density does not appear to correlatewith any of the measured proxy variables, and at this point we do not know whatcontrolled gray scale.     

Alpujarride attribution of the supposed ‘Almagride Complex’ (Betic Internal Zone,Almerı́a Province,Spain)Appartenance Alpujarride du prétendu « Complexe almagride » (Zones internes bétiques,province d'Almeria,Espagne)

The differentiation of units in the Sierra de Almagro has been a source of controversy. There were defined the Almagride and Ballabona–Cucharón complexes, the former considered by several authors as part of a Subbetic metamorphosed and outcropping in a tectonic window. In this study, the units of Ballabona, Almagro and Cucharón are integrated into a single one, that of Tres Pacos, because they correspond to different parts of the same stratigraphic series. This unit is tectonically over the Nevado–Filabride Complex. The existence of the Almagride and Ballabona–Cucharón complexes is discarded and their units form part of the Alpujarride Complex. To cite this article: C. Sanz de Galdeano, F.J. Garc??a Tortosa, C. R. Geoscience 334 (2002) 355–362.     

The interpretation of reaction textures in Fe‐rich metapelitic granulites of the Musgrave Block,central Australia: constraints from mineral equilibria calculations in the system K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3

Fe‐rich metapelitic granulites of the Musgrave Block, central Australia, contain several symplectic and coronal reaction textures that post‐date a peak S2 metamorphic assemblage involving garnet, sillimanite, spinel, ilmenite, K‐feldspar and quartz. The earliest reaction textures involve spinel‐ and quartz‐bearing symplectites that enclose garnet and to a lesser extent sillimanite. The symplectic spinel and quartz are in places separated by later garnet and/or sillimanite coronas. The metamorphic effects of a later, D3, event are restricted to zones of moderate to high strain where a metamorphic assemblage of garnet, sillimanite, K‐feldspar, magnetite, ilmenite, quartz and biotite is preserved. Quantitative mineral equilibria calculations in the system K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (KFMASHTO) using Thermocalc 3.0 and the accompanying internally consistent dataset provide important constraints on the influence of TiO₂ and Fe₂O₃ on biotite‐bearing and spinel‐bearing equilibria, respectively. Biotite‐bearing equilibria are shifted to higher temperatures and spinel‐bearing equilibria to higher pressures and lower temperatures in comparison to the equivalent equilibria in K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (KFMASH). The sequence of reaction textures involving spinel is consistent with a D2 P–T path that involved a small amount of decompression followed predominantly by cooling within a single mineral assemblage stability field. Thus, the reaction textures reflect changes in modal proportions within an equilibrium assemblage rather than the crossing of a univariant reaction. The D3 metamorphic assemblage is consistent with lower temperatures than those inferred for D2.