Response of suspended sediment particle size distributions to changes in water chemistry at an Andean mountain stream confluence receiving arsenic rich acid drainage

Acid drainage is an important water quality issue in Andean watersheds, affecting the sustainability of urban, agricultural, and industrial activities. Mixing zones receiving acid drainage are critical sites where changes in pH and chemical environment promote the formation and dissolution of iron and aluminum oxy/hydroxides. These particles can significantly change the speciation of toxic metals and metalloids throughout drainage networks via sorption, desorption, and settling processes. However, little is known about the behavior of particle size distributions (PSDs) in streams affected by acid drainage and their relationship to metal speciation. This work studied: (a) the PSDs for a wide range of mixing ratios found at a fluvial confluence affected by acid drainage, and (b) the response of PSDs and arsenic speciation to environmental changes found when the particles approach complete mixing conditions. The confluence between the Azufre River (pH ~ 2, high concentration of dissolved metals) and Caracarani River (pH = 8.6, low concentration of dissolved metals) was used as a representative model for study. Field measurements show a bimodal PSD with modal diameters of ~50 and 300 μm. At shorter distances from the junction, the smaller modes with smaller particle volumes were dominant across the stream cross‐sections. A systematic shift towards larger particle sizes and larger particle volumes occurred downstream. The analysis of laboratory PSDs for Azufre/Caracarani mixing ratios between 0.01 and 0.5 (pH from 6.2 to 2.3) showed a bimodal trend with ~15 and 50 μm characteristic diameters; larger particles formed at pH>4. When particle suspensions were transferred in laboratory experiments from very low pH to full mixing conditions (pH ~ 2.8 and mixing ratio ~ 0.25) particle sizes varied, and the dissolved arsenic concentration decreased. The observed reaction kinetics were slow compared to the time scale of advective transport, creating opportunities for engineered controls for arsenic. This work contributes to a better understanding of the chemical‐hydrodynamic interactions in watersheds affected by mining, and identifying opportunities to improve water quality at points of use.     

Anthropogenic debris on beaches in the SE Pacific (Chile): Results from a national survey supported by volunteers

Anthropogenic marine debris (AMD) is an ubiquitous problem, which has motivated public participation in activities such as beach surveys and clean-up campaigns. While it is known that beaches in the SE Pacific are also affected by this problem, the quantities and types of AMD remain largely unknown. In the context of an outreach project, volunteers (1500 high-school students) participated in a nation-wide survey of AMD on 43 beaches distributed randomly along the entire Chilean coast (18°S to 53°S). The mean density of AMD was 1.8 items m⁻² and the major types were plastics, cigarette butts and glass. Densities in central Chile were lower than in northern and southern Chile, which could be due to different attitudes of beach users or to intense beach cleaning in central regions. We suggest that public participation in surveys and cleaning activities will raise awareness and thereby contribute to an improvement of the situation.     

Tectonic implications of the earthquake swarm of 1997 in the Michoacan Triangle, Mexico

An earthquake swarm occurred during February and March 1997 in the vicinity of the Tancitaro Volcano, in the southern part of the tectonically complex Michoacan Triangle. A study of these events provides an opportunity to map the active faults in the area and to learn if the orientation and the sense of motion on these faults are consistent with the mapped faults and the alignment of cinder cones in the region. The foci of 230 earthquakes, which could be located, are distributed between 10 and 18 km depth, and show an alignment in, roughly, a NE direction. The focal mechanisms and seismic moments of the 27 best-recorded events were determined by waveform modeling of P and S waves. These mechanisms show two distinct patterns. More than 50% of the solutions are left-lateral strike–slip mechanisms with a normal component. The preferred fault plane strikes NE. Another group of events, probably caused by triggered seismicity on the Chapala–Oaxaca fault zone, shows left-lateral strike–slip mechanisms with a large-thrust component on NW-trending faults. S wave splitting shows 1–2.5% crustal-anisotropy. The direction of the anisotropy coincides with the NE alignment of events, and the preferred nodal plane. This is also the alignment of cinder cones, suggesting that preexisting fractures and cracks are responsible for the seismicity and anisotropic behavior of the crust. The resulting stress orientation, NE compression, is the one expected for the fore-arc region. We conclude that although Michoacan Triangle lies in the Trans-Mexican Volcanic Belt, it does not form part of this stress province where the stress orientation is NS extension.     

Tree growth response to the 1913 eruption of Volcán de Fuego de Colima, Mexico

The impact of volcanic eruptions on forest ecosystems can be investigated using dendrochronological records. While long-range effects are usually mediated by decreased air temperatures, resulting in frost rings or reduced maximum latewood density, local effects include abrupt suppression of radial growth, occasionally followed by greater than normal growth rates. Annual rings in Mexican mountain pine (Pinus hartwegii Lindl.) on Nevado de Colima, at the western end of the Mexican Neovolcanic Belt, indicate extremely low growth in 1913 and 1914, following the January 1913 Plinian eruption of Volcán de Fuego, 7.7 km to the south. That event, which is listed among the largest explosive eruptions since A.D. 1500, produced ashflow deposits up to 40 m thick and blanketed our study area on Nevado de Colima with a tephra fallout 15–30 cm deep. Radial growth reduction in 1913–14 was ≥30% in 73% of the sampled trees. We geostatistically investigated the ecological impact of the eruption by mapping the decrease in xylem increment and found no evidence of a spatial structure in growth reduction. Little information has been available to date on forest species as biological archives of past environments in the North American tropics, yet this historical case study suggests that treeline tropical sites hold valuable records of prehistoric phenomena, including volcanic eruptions.     

Testing the modified Press–Schechter model against N-body simulations

A modified version of the extended Press–Schechter model for the growth of dark-matter haloes was introduced in two previous papers, with the aim of explaining the mass–density relation shown by haloes in high-resolution cosmological simulations. In this model, major mergers are well separated from accretion, thereby allowing a natural definition of halo formation and destruction. This makes it possible to derive analytic expressions for halo formation and destruction rates, the mass accretion rate and the probability distribution functions of halo formation times and progenitor masses. The stochastic merger histories of haloes can be readily derived and easily incorporated into semi-analytical models of galaxy formation, thus avoiding the usual problems encountered in the construction of Monte Carlo merger trees from the original extended Press–Schechter formalism. Here we show that the predictions of the modified Press–Schechter model are in good agreement with the results of N -body simulations for several scale-free cosmologies.     

ISA-Hypoplasticity accounting for cyclic mobility effects for liquefaction analysis

Acta Geotechnica - The hypoplastic model for sands proposed by Wolffersdorff (Mech Cohes Frict Mater 1: 251–271, 1996) combined with the intergranular strain anisotropy by Fuentes and...     

Vegetation dynamics during the late Pleistocene in the Barreirinhas region, Maranhão State, northeastern Brazil, based on carbon isotopes in soil organic matter

The study place is in the Barreirinhas region, Maranhão State, northeastern Brazil. A vegetation transect of 78 km was studied among four vegetation types: Restinga (coastal vegetation), Cerrado (woody savanna), Cerradão (dense woody savanna), and Forest, as well as three forested sites around Lagoa do Caçó, located approximately 10 km of the transect. Soil profiles in this transect were sampled for δ¹³C analysis, as well as buried charcoal fragments were used for ¹⁴C dating. The data interpretation indicated that approximately between 15,000 and ∼9000 ¹⁴C yr B.P., arboreal vegetation prevailed in the whole transect, probably due to the presence of a humid climate. Approximately between ∼9000 and 4000-3000 ¹⁴C yr B.P., there was the expansion of the savanna, probably related to the presence of drier climate. From ∼4000-3000 ¹⁴C yr B.P. to the present, the results indicated an increase in the arboreal density in the area, due to the return to a more humid and probably similar climate to the present. The presence of buried charcoal fragments in several soil depths suggested the occurrence of palaeofires during the Holocene. The vegetation dynamic inferred in this study for northeastern Brazil is in agreement with the results obtained in areas of Amazon region, based on pollen analysis of lake sediments and carbon isotope analysis of soil organic matter (SOM), implying than similar climatic conditions have affected these areas during the late Pleistocene until the present.     

Ocean–atmosphere coupling and the boreal winter MJO

The influence of ocean–atmosphere coupling on the simulation and prediction of the boreal winter Madden–Julian Oscillation (MJO) is examined using the Seoul National University coupled general circulation model (CGCM) and atmospheric—only model (AGCM). The AGCM is forced with daily SSTs interpolated from pentad mean CGCM SSTs. Forecast skill is examined using serial extended simulations spanning 26 different winter seasons with 30-day forecasts commencing every 5 days providing a total of 598 30-day simulations. By comparing both sets of experiments, which share the same atmospheric components, the influence of coupled ocean–atmosphere processes on the simulation and prediction of MJO can be studied. The mean MJO intensity possesses more realistic amplitude in the CGCM than in AGCM. In general, the ocean–atmosphere coupling acts to improve the simulation of the spatio-temporal evolution of the eastward propagating MJO and the phase relationship between convection (OLR) and SST over the equatorial Indian Ocean and the western Pacific. Both the CGCM and observations exhibit a near-quadrature relationship between OLR and SST, with the former lagging by about two pentads. However, the AGCM shows a less realistic phase relationship. As the initial conditions are the same in both models, the additional forcing by SST anomalies in the CGCM extends the prediction skill beyond that of the AGCM. To test the applicability of the CGCM to real-time prediction, we compute the Real-time Multivariate MJO (RMM) index and compared it with the index computed from observations. RMM1 (RMM2) falls away rapidly to 0.5 after 17–18 (15–16) days in the AGCM and 18–19 (16–17) days in the CGCM. The prediction skill is phase dependent in both the CGCM and AGCM.     

Goethite surface reactivity: III. Unifying arsenate adsorption behavior through a variable crystal face - Site density model

We developed a model that describes quantitatively the arsenate adsorption behavior for any goethite preparation as a function of pH and ionic strength, by using one basic surface arsenate stoichiometry, with two affinity constants. The model combines a face distribution-crystallographic site density model for goethite with tenets of the Triple Layer and CD-MUSIC surface complexation models, and is self-consistent with its adsorption behavior towards protons, electrolytes, and other ions investigated previously. Five different systems of published arsenate adsorption data were used to calibrate the model spanning a wide range of chemical conditions, which included adsorption isotherms at different pH values, and adsorption pH-edges at different As(V) loadings, both at different ionic strengths and background electrolytes. Four additional goethite-arsenate systems reported with limited characterization and adsorption data were accurately described by the model developed. The adsorption reaction proposed is: