Persistence of mantle lithospheric Re–Os signature during asthenospherization of the subcontinental lithospheric mantle: insights from in situ isotopic analysis of sulfides from the Ronda peridotite (Southern Spain)

The western part of the Ronda peridotite massif (Southern Spain) consists mainly of highly foliated spinel-peridotite tectonites and undeformed granular peridotites that are separated by a recrystallization front. The spinel tectonites are interpreted as volumes of ancient subcontinental lithospheric mantle and the granular peridotites as a portion of subcontinental lithospheric mantle that underwent partial melting and pervasive percolation of basaltic melts induced by Cenozoic asthenospheric upwelling. The Re–Os isotopic signature of sulfides from the granular domain and the recrystallization front mostly coincides with that of grains in the spinel tectonites. This indicates that the Re–Os radiometric system in sulfides was highly resistant to partial melting and percolation of melts induced by Cenozoic lithospheric thermal erosion. The Re–Os isotopic systematics of sulfides in the Ronda peridotites thus mostly conserve the geochemical memory of ancient magmatic events in the subcontinental lithospheric mantle. Os model ages record two Proterozoic melting episodes at ~1.6 to 1.8 and 1.2–1.4 Ga, respectively. The emplacement of the massif into the subcontinental lithospheric mantle probably coincided with one of these depletion events. A later metasomatic episode caused the precipitation of a new generation of sulfides at ~0.7 to 0.9 Ga. These Proterozoic Os model ages are consistent with results obtained for several mantle suites in Central/Western Europe and Northern Africa as well as with the Nd model ages of the continental crust of these regions. This suggests that the events recorded in mantle sulfides of the Ronda peridotites reflect different stages of generation of the continental crust in the ancient Gondwana supercontinent.     

Goethite surface reactivity: III. Unifying arsenate adsorption behavior through a variable crystal face - Site density model

We developed a model that describes quantitatively the arsenate adsorption behavior for any goethite preparation as a function of pH and ionic strength, by using one basic surface arsenate stoichiometry, with two affinity constants. The model combines a face distribution-crystallographic site density model for goethite with tenets of the Triple Layer and CD-MUSIC surface complexation models, and is self-consistent with its adsorption behavior towards protons, electrolytes, and other ions investigated previously. Five different systems of published arsenate adsorption data were used to calibrate the model spanning a wide range of chemical conditions, which included adsorption isotherms at different pH values, and adsorption pH-edges at different As(V) loadings, both at different ionic strengths and background electrolytes. Four additional goethite-arsenate systems reported with limited characterization and adsorption data were accurately described by the model developed. The adsorption reaction proposed is:

     

High‐Resolution Photography for Soil Micromorphology Slide Documentation

It is common practice today in soil micromorphology to scan slides with a flatbed scanner for slide documentation as well as for mesoscopic scale observation. However, the imagery produced by flatbed scanners often results in boundaries becoming diffuse when zooming in, a side effect of the continuously changing refraction of light caused by the moving scan head. This can be restricting or even unsatisfactory to specialists who rely on such imagery and while alternatives exist, their availability or suitability is not always guaranteed. This paper describes two variations on a static high‐resolution image acquisition method using a professional camera and common attributes of a standard photography studio. Minor postphotography processing too can be done with commonly used software packages. The presented method results in pictures with a resolution of 36 million pixels per image, providing high enough quality and resolution (approximately 4200 dpi) to allow the soil micromorphology practitioner to navigate the entire mesoscopic spectrum and as such offers a continuum of observation from the macroscopic scale to the optical microscopic observation at low (40×) magnification.     

Web-oriented GIS system for monitoring, conservation and law enforcement of the Brazilian Amazon

A web GIS (WGIS) system for the Brazilian Amazon, named ImazonGeo and based on open source and public domain data, is presented. ImazonGeo was built following three principles. First, the system is based on Spatial Data Infrastructure architecture and web interface built using free software and public domain data. Second, we went beyond visualization of maps and spatial queries by providing information obtained with spatial analysis models. To do that, we designed a database that stores the results of previously defined spatial analyses and developed customized reports and query tools to facilitate fast access of information by end-users. Finally, the system is application-oriented in the areas of forest monitoring, conservation and forest law enforcement, meaning that it aims to contribute to support the protection of Brazilian Amazon forests. We illustrate these principles by presenting ImazonGeo’s technology, architecture, content and tools. Moreover, we present two successful cases to demonstrate how the system is being used. We conclude the paper discussing the challenges and potential solutions to turning our WGIS-SDI system into an internet hub of geo-information about the Brazilian Amazon.     

An extended investigation of Helios 1 and 2 observations: The interplanetary magnetic field between 0.3 and 1 AU

Helios-1 and 2 spacecraft allowed a detailed investigation of the radial dependence of the interplanetary magnetic field components between 0.3 and 1 AU. The behaviour of the radial component B _ris in a very good agreement with Parker's model (B _r r ^-2) and the azimuthal component B also shows a radial dependence which is close to theoretical predictions (B r ^-1). Experimental results for the normal component B and for the field magnitude B are consistent with those from previous investigations. The relative amplitude of the directional fluctuations with periods less than 12 hr is essentially independent of heliocentric distance, while their power decreases approximately as r ^–3 without any appreciable difference between higher and lower velocity regimes.Also at Laboratorio Plasma nello Spazio, CNR, Frascati.     

Environmental limitations on recruitment from seed in invasive Spartina densiflora on a southern European salt marsh

The South American cordgrass, Spartina densiflora, has invaded a range of different habitats that can support different native species assemblages on salt marshes in the Gulf of Cadiz, Spain. Little is known about the mechanisms of invasion. We examined the potential for seed germination and recruitment in a field transplant experiment, representing a wide range of environments, on elevational gradients across marshes with muddy and sandy sediments. The biotic resistance of native, perennial vegetation (where present) to recruitment of the alien was also investigated. Spartina densiflora seeds were able to germinate over a greater than 2-m range of elevation in the tidal frame. Germination success on unvegetated muddy sediments was related to sediment redox potential, with poor germination at strongly negative redox potentials on the lower sites. On sandy, well-drained sediments, germination was apparently constrained by water availability at the highest elevations. Comparison of vegetated and cleared plots on the upper marsh showed that there was a negative relationship between the presence of Atriplex portulacoides and germination on the muddy sediments. Recruitment (survival of seedlings for 12 weeks) was seen only on unvegetated muddy sediments at the highest elevation. Hence the invasive success and wide elevational tolerance of S. densiflora on the marshes of the Gulf of Cadiz are not reflected in its short-term ability to become established from its prolific seed production. Colonization of sub-optimal habitats may be largely by vegetative propagules and clonal growth.     

Die Ablenkung des Lichtes an der Sonne und die Änderung Seiner Geschwindigkeit und Wellenlänge

Zusammenfassung Die Ergebnisse der Radar-Echo-Messungen von I. I. Shapiro, welche auf eine Verringerung der Lichtgeschwindigkeit beim Vorübergang des Lichtes an der Sonne hinweisen, werden zusammen mit der Ablenkung des Lichtes und der Verschiebung seiner Spektrallinien wellentheoretisch erklärt. Es genügt hierzu die Annahme eines materiellen lichtwellentragenden Mediums mit einer Dichte unterhalb des empirischen Vakuums; das Medium muss dann radial zur Sonne eine geringe Inhomogenität besitzen, die in entsprechenden kleinen Zusatzgliedern in den Maxwellschen Gleichungen ihren Ausdruck findet.Auf protophysikalischer Grundlage aufbauend wird die Phasengleichung (22) der an der Sonne vorbeigehenden Lichtwellen unter einfachsten Annahmen abgeleitet und integriert; als Resultat ergeben sich die drei genannten Effekte in Übereinstimmung mit der Erfahrung (Gleichung (39), (44), (47)).

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Shapiro (1968) published the first results of radar-echo-observations on Venus and Mercury in the neighbourhood of upper conjunctions with the Sun; the observations indicate a decrease of the velocity of light passing the Sun. The theory of Soldner is disproved; and the general relativity is in accord with the observed facts. But not this theory alone. In this publication the deflection of light, decrease of the velocity of light, and displacement of spectral-lines are explained with the aid of a wavetheory. Hereby the assumption of a material medium carrying light-waves is sufficient, the density of which is below that of the empirical vacuum; hence, the medium must have a small inhomogeneityh radial to the Sun, and the Maxwell equations contain small additional terms (Equation (3)). They lead to the field equations (4) and (5). The protophysical fundamentals of the wave-theory (6), (8), (9), (10a) lead to the Equations (12) of wave-phase. If we assume that the behaviour of the light passing the Sun is independent (in first approximation) from the wave-form (F), the Equation (22) of wave-phase, is deduced for simple-periodic waves of light. Figure 1 outlines the slope and deflection of the ray of light by the Sun. Section 5 contains the solution of (22); and Section 6 the results. The constant of inhomogeneity =1/210^–5 (of the radius of the Sun) produces a deflection (39) of light passing the Sun. The length of waves of the light approaching the Sun is decreased to a minimum and is increasing with increasing distance from the Sun until the former value ((43) and (44)). The velocity of light approaching the Sun is decreased to a minimum and increases with increasing distance from the Sun to its former value ((46) and (47)).