Nutrient Inputs, Phytoplankton Response, and CO2 Variations in a Semi-Enclosed Subtropical Embayment, Kaneohe Bay, Hawaii

The marine shelf areas in subtropical and tropical regions represent only 35% of the total shelf areas globally, but receive a disproportionately large amount of water (65%) and sediment (58%) discharges that enter such environments. Small rivers and/or streams that drain the mountainous areas in these climatic zones deliver the majority of the sediment and nutrient inputs to these narrow shelf environments; such inputs often occur as discrete, episodic introductions associated with storm events. To gain insight into the linked biogeochemical behavior of subtropical/tropical mountainous watershed-coastal ocean ecosystems, this work describes the use of a buoy system to monitor autonomously water quality responses to land-derived nutrient inputs and physical forcing associated with local storm events in the coastal ocean of southern Kaneohe Bay, Oahu, Hawaii, USA. The data represent 2.5 years of near-real time observations at a fixed station, collected concurrently with spatially distributed synoptic sampling over larger sections of Kaneohe Bay. Storm events cause most of the fluvial nutrient, particulate, and dissolved organic carbon inputs to Kaneohe Bay. Nutrient loadings from direct rainfall and/or terrestrial runoff produce an immediate increase in the N:P ratio of bay waters up to values of 48 and drive phytoplankton biomass growth. Rapid uptake of such nutrient subsidies by phytoplankton causes rapid declines of N levels, return to N-limited conditions, and subsequent decline of phytoplankton biomass over timescales ranging from a few days to several weeks, depending on conditions and proximity to the sources of runoff. The enhanced productivity may promote the drawing down of pCO₂ and lowering of surface water column carbonate saturation states, and in some events, a temporary shift from N to P limitation. The productivity-driven CO₂ drawdown may temporarily lead to air-to-sea transfer of atmospheric CO₂ in a system that is on an annual basis a source of CO₂ to the atmosphere due to calcification and perhaps heterotrophy. Storms may also strongly affect proximal coastal zone pCO₂ and hence carbonate saturation state due to river runoff flushing out high pCO₂ soil and ground waters. Mixing of the CO₂-charged water with seawater causes a salting out effect that releases CO₂ to the atmosphere. Many subtropical and tropical systems throughout the Pacific region are similar to Kaneohe Bay, and our work provides an important indication of the variability and range of CO₂ dynamics that are likely to exist elsewhere. Such variability must be taken into account in any analysis of the direction and magnitude of the air?Csea CO₂ exchange for the integrated coastal ocean, proximal and distal. It cannot be overemphasized that this research illustrates several examples of how high frequency sampling by a moored autonomous system can provide details about ecosystem responses to stochastic atmospheric forcing that are commonly missed by traditional synoptic observational approaches. Finally, the work exemplifies the utility of combining synoptic sampling and real-time autonomous observations to elucidate the biogeochemical and physical responses of coastal subtropical/tropical coral reef ecosystems to climatic perturbations.     

It starts at home? Climate policies targeting household consumption and behavioral decisions are key to low-carbon futures

Through their consumption behavior, households are responsible for 72% of global greenhouse gas emissions. Thus, they are key actors in reaching the 1.5 °C goal under the Paris Agreement. However, the possible contribution and position of households in climate policies is neither well understood, nor do households receive sufficiently high priority in current climate policy strategies. This paper investigates how behavioral change can achieve a substantial reduction in greenhouse gas emissions in European high-income countries. It uses theoretical thinking and some core results from the HOPE research project, which investigated household preferences for reducing emissions in four European cities in France, Germany, Norway and Sweden. The paper makes five major points: First, car and plane mobility, meat and dairy consumption, as well as heating are the most dominant components of household footprints. Second, household living situations (demographics, size of home) greatly influence the household potential to reduce their footprint, even more than country or city location. Third, household decisions can be sequential and temporally dynamic, shifting through different phases such as childhood, adulthood, and illness. Fourth, short term voluntary efforts will not be sufficient by themselves to reach the drastic reductions needed to achieve the 1.5 °C goal; instead, households need a regulatory framework supporting their behavioral changes. Fifth, there is a mismatch between the roles and responsibilities conveyed by current climate policies and household perceptions of responsibility. We then conclude with further recommendations for research and policy.     

Polymorphism of As4S3 (tris-(μ2-sulfido)-tetra-arsenic): accurate structure refinement on natural α- and β-dimorphites and inferred room temperature thermodynamic properties

An accurate structure refinement, using single-crystal X-ray diffraction data, on natural α- and β-dimorphites collected at Solfatara di Pozzuoli, in the Phlegraean Fields, near Naples and at Vesuvius (Italy) is reported. Theoretical calculations at various levels of sophistication have been used to calculate molecular vibrational frequencies and gas-phase specific heats, to analyze the crystal packing, and to estimate lattice energies of both phases. All computational methods contribute to demonstrate that the β-phase is the thermodynamically stable one at room temperature.     

Contrasting regional discharge evolutions in the Amazon basin (1974–2004)

Former hydrological studies in the Amazon Basin generally describe annual discharge variability on the main stem. However, the downstream Amazon River only represents the mean state of the Amazonian hydrological system. This study therefore uses a new data set including daily discharge in 18 sub-basins to analyze the variability of regional extremes in the Amazon basin, after recalling the diversity of the hydrological annual cycles within the Amazon basin. Several statistical tests are applied in order to detect trends and breaks in the time series. We show that during the 1974–2004 period, the stability of the mean discharge on the main stem in Óbidos is explained by opposite regional features that principally involve Andean rivers: a decrease in the low stage runoff, particularly important in the southern regions, and an increase in the high stage runoff in the northwestern region. Both features are observed from the beginning of the nineties. These features are also observed in smaller meridian sub-basins in Peru and Bolivia. Moreover we show that the changes in discharge extremes are related to the regional pluriannual rainfall variability and the associated atmospheric circulation as well as to tropical large-scale climatic indicators.     

A novel methodological approach for land subsidence prediction through data assimilation techniques

Computational Geosciences - Anthropogenic land subsidence can be evaluated and predicted by numerical models, which are often built over deterministic analyses. However, uncertainties and...     

Geodynamic significance of ophiolites within the Calabrian Arc

Abstract Slices of oceanic lithosphere belonging to the neo‐Tethys realm crop out discontinuously in the northern Calabrian Arc, Southern Apennines. They consist of high‐pressure–low‐temperature metamorphic ophiolitic sequences formed from metaultramafics, metabasites and alternating metapelites, metarenites, marbles and calcschist. Ophiolites occupy an intermediate position in the northern Calabrian Arc nappe pile, situated between overlying Hercynian continental crust and the underlying Apenninic limestone units. In the literature, these ophiolitic sequences are subdivided into several tectonometamorphic units. Geochemical characteristics indicate that metabasites were derived from subalkaline basalts with tholeiitic affinity (transitional mid‐oceanic ridge basalt type), and a harzburgitic‐lherzolitic protolith is suggested for the serpentinites. The pressure–temperature‐deformation paths of the metabasites from different outcrops display similar features: (i) the prograde segment follows a typical Alpine geothermal gradient up to a metamorphic climax at 350°C and 0.9 GPa and crystallization of the high‐pressure mineral assemblage occurs along a pervasive foliation developed during a compressive tectonic event; and (ii) the retrogression path can be subdivided in two segments, the first is characterized by nearly isothermal decompression to approximately 400°C and 0.3 GPa and the second follows a cooling trajectory. During low‐pressure conditions, a second deformation event produces millimetric to decametric scale asymmetric folds that describe west‐verging major structures. The third deformation event is characterized by brittle extensional structures. The tectonometamorphic evolution of the ophiolitic sequences from the different outcrops is similar. Both thermobarometric modeling and tectonic history indicate that the studied rocks underwent Alpine subduction and exhumation processes as tectonic slices inside a west‐verging accretionary wedge. The subduction of oceanic lithosphere was towards the present east; therefore, the Hercynian continental crust, overthrusted on the ophiolitic accretionary wedge after the neo‐Tethys closure, was part of the African paleomargin or a continental microplate between Africa and Europe.     

Middle and late Pleistocene glaciations in the Campo Felice Basin (central Apennines, Italy)

The present paper refers to research conducted in the tectonic-karst depression of Campo Felice in the central Apennines (Italy), in which glacial, alluvial and lacustrine sediments have been preserved. Stratigraphic interpretations of sediments underlying the Campo Felice Plain are based on evidence obtained from nine continuous-core boreholes. The boreholes reach a depth of 120 m and provide evidence of five sedimentation cycles separated by erosion surfaces. Each cycle is interpreted as an initial response to a mainly warm stage, characterized by low-energy alluvial and colluvial deposition, pedogenesis, and limited episodes of marsh formation. In turn, a mainly cold stage follows during which a lake formed, and glaciers developed and expanded, leading to deposition of glacial and fluvioglacial deposits. The chronological framework is established by eleven accelerator mass spectrometer ¹⁴C ages and three ³⁹Ar-⁴⁰Ar ages on leucites from interbedded tephra layers. These age determinations indicate five glacial advances that respectively occurred during marine oxygen isotope stages 2, 3-4, 6, 10 and 14.     

Seasonal temperatures for the past ∼400 years reconstructed from diatom and chironomid assemblages in a high-altitude lake (Lej da la Tscheppa,Switzerland)

We analysed a 42 cm long sediment record from Lej da la Tscheppa, a high-altitude lake (2,616 m a.s.l.) in the Upper Engadine valley (Switzerland) for subfossil diatoms, chironomids and pollen. The chronology of the top 21 cm of the record was established using ²¹⁰Pb analysis using a constant-rate-of-supply model, and validated with ¹³⁷Cs measurements and the content of spheroidal carbonaceous particles. A tentative chronology for the lower part of the core was obtained through extrapolation of the sedimentation rates in the uppermost part of the record. Pollen assemblages in the record reflect regional changes in forestation and land-use patterns in the Upper Engadine valley and show no evidence of significant local human activity in the lake’s catchment. Diatom assemblages record a distinct increase in planktonic taxa since the early 19th century, suggesting a decrease in the duration of ice-cover. In contrast, chironomid assemblages remained stable during a large part of the record. We applied an established chironomid-based July air temperature transfer function and a newly developed diatom-based spring air temperature transfer function to reconstruct past seasonal air temperature changes at Lej da la Tscheppa. The reconstructions indicate a diatom-inferred warming trend in spring temperatures during the past ca. 400 years, whereas chironomid-inferred summer temperatures suggest a slight cooling trend. These biota-based reconstructions are in good agreement with the centennial-scale temperature trend in an independent reconstruction of regional temperatures in the Upper Engadine region based on instrumental records and documentary proxy evidence from the Alps. Our results suggest that, in high-altitude lakes, independent chironomid- and diatom-based seasonal temperature reconstruction is possible and can be successfully used to track seasonal temperature trends.     

A hydraulic invariance‐based methodology for the implementation of storm‐water release restrictions in urban land use master plans

A hydraulic invariance (HI)‐based methodology was developed as a tool to support implementation of storm flow control measures into land use master plans (LUMPs) for urban catchments. The methodology is based on the use of simple hydrologic analysis to compare predevelopment and postdevelopment catchment flow release scenarios. Differently from previous literature examples, for which the parcel scale is usually considered for the analysis, HI was pursued assuming the LUMP areas of transformation as the basic units for assigning storm water control measures in the form of flow release restrictions. The methodology was applied to a case study catchment in the southern part of the City of Catania (Italy), for which the LUMP re‐design has been recently proposed. Simulations were run based on the use of the EPA‐Storm Water Management Model and allowed deriving flow release restrictions in order to achieve HI at the subcatchment level for design events of different return period.     

Halocinèse précoce associée au rifting jurassique dans l'Atlas central de Tunisie (région de Majoura–El Hfay)

Seismic and sequence stratigraphy analyses, petroleum-well control and surface data studies of the Majoura–El Hfay region in the Central Atlas of Tunisia had led to identify and calibrate Jurassic seismic horizons. Seismic stratigraphic sections, seismic tectonics analyses, isochron and isopach mapping of Jurassic sequences show a differentiated structuring of platform and depocentre blocks limited by deep-seated NE–SW, north–south east–west and NW–SE faults intruded by Upper Triassic salt. The early salt migration seems to have started by the platform fracturing during the Lower Liassic rifting event. These movements are fossilized by thickness variations of Jurassic horizons, aggrading and retrograding onlap and toplap structures between subsiding rim-syncline gutters and high platform flanks intruded by salt pillows and domes. The salt migration is also attested by Middle and Upper Jurassic space depocentre migrations. Around the Majoura–El Hfay study blocks bounded by master faults, Triassic salt have pierced the Cretaceous and Tertiary sedimentary cover in a salt diapir extrusion and salt wall structures. To cite this article: D. Tanfous Amri et al., C. R. Geoscience 337 (2005).