Export Production in the Subarctic North Pacific over the Last 800 kyrs: No Evidence for Iron Fertilization?

The subarctic North Pacific is a high nitrate-low chlorophyll (HNLC) region, where phytoplankton growth rates, especially those of diatoms, are enhanced when micronutrient Fe is added. Accordingly, it has been suggested that glacial Fe-laden dust might have increased primary production in this region. This paper reviews published palaeoceanographic records of export production over the last 800 kyrs from the open North Pacific (north of ∼35°N). We find different patterns of export production change over time in the various domains of the North Pacific (NW and NE subarctic gyres, the marginal seas and the transition zone). However, there is no compelling evidence for an overall increase in productivity during glacials in the subarctic region, challenging the paradigm that dust-born Fe fertilization of this region has contributed to the glacial draw down of atmospheric CO₂. Potential reasons for the lack of increased glacial export production include the possibility that Fe-fertilization rapidly drives the ecosystem towards limitation by another nutrient. This effect would have been exacerbated by an even more stable mixed layer compared to today. This revised version was published online in July 2006 with corrections to the Cover Date.     

Thematic land-cover map assimilation and synthesis: the case of locating potential bioenergy feedstock in eastern Ontario,Canada

Insufficient spatial coverage of existing land-cover data is a common limitation to timely and effective spatial analysis. Achieving spatial completeness of land-cover data is the most challenging for large study areas which straddle ecological or administrative boundaries, and where individuals and agencies lack access to, and the means to process, raw data from which to derive spatially complete land-cover maps. In many cases, various sources of secondary data are available, so that land-cover map assimilation and synthesis can resolve this research problem. The following paper develops a reliable and repeatable framework for assimilating and synthesizing pre-classified data sets. Assimilation is achieved through data reformatting and map legend reconciliation in the context of a specific application. Individual maps are assessed for accuracy at various geographic scales and levels of thematic precision, with an emphasis on the ‘area of overlap’, in order to extract information that guides the synthesis process. The quality of the synthesized land-cover data set is evaluated using advanced accuracy assessment methods, including a measure describing the ‘magnitude of disagreement’. This method is applied to derive a seamless thematic map of the land cover of eastern Ontario from two disparate map series. The importance of assessing data quality throughout the process using multiple reference data sets is highlighted, and limitations of the method are discussed.     

Tomographic Imaging of Lg and Sn Propagation in the Middle East

?—?Observations based on relatively limited data recorded by sparsely distributed stations have indicated that regional seismic phase propagation (Lg and Sn) is very complex in the Middle East. Accurate characterization of regional seismic wave propagation in this region necessitates the use of a large number of seismic stations. We have compiled a large data set of regional and local seismograms recorded in the Middle East. This data set comprises approximately four years of data from national short-period networks in Turkey and Syria, data from temporary broadband arrays in Saudi Arabia and the Caspian Sea region, and data from GSN, MEDNET, and GEOFON stations in the Middle East. We have used this data set to decipher the character and pattern of regional seismic wave propagation. We have mapped zones of blockage as well as inefficient and efficient propagation for Lg, Pg, and Sn throughout the Middle East. Two tomographic techniques have been developed in order to objectively determine regions of lithospheric attenuation in the Middle East.¶We observe evidence of major increase in Lg attenuation, relative to Pg, across the Bitlis suture and the Zagros fold and thrust belt, corresponding to the boundary between the Arabian and Eurasian plates. We also observe a zone of inefficient Sn propagation along the Dead Sea fault system which coincides with low Pn velocities along most of the Dead Sea fault system and with previous observations of poor Sn propagation in western Jordan. Our observations indicate that in the northern portion of the Arabian plate (south of the Bitlis suture) there is also a zone of inefficient Sn propagation that would not have been predicted from prior measurements of relatively low Pn velocities. Mapped high attenuation of Sn correlates well with regions of Cenozoic and Holocene basaltic volcanism. These regions of uppermost mantle shear-wave attenuation most probably have anomously hot and possibly thin lithosphere.     

The contrasting geochemical behaviours of iodine and bromine in recent sediments from the Namibian shelf

The vertical distribution of iodine, bromine and organic carbon has been examined in sediment cores from a range of environments on the Namibian shelf. The relationship between Br and C org. is linear, and that between I and C org. is variable, for all surface sediments; I/C org. ratios show a decrease of about one order of magnitude between the outer shelf oxidising sediments ($\text{250 × 10}{}^{\mathrm{?4}}$) and the organic-rich inner shelf sediments ($\text{20 × 10}{}^{\mathrm{?4}}$). The contrasting behaviour of the halogens in surface sediments is explained by differences in the amount of halogen absorbed by living organisms within the euphotic zone and on seston on the seabed. It is suggested that sorption by seston occurs only in oxidising sediment where free O₂ is available. Hence, iodine is sorbed by seston in the outer shelf environment, but is not sorbed by the reducing sediments of the inner shelf. Here the iodine in the sediment represents only that taken up by plankton. On the outer shelf, 50–80% of the total iodine in the organic matter is sorbed by seston. The principal site of Br uptake is not known.The distribution of C org. in subsurface sediments broadly reflects that found at the surface, although there is a slight decrease with depth in the outer shelf cores due to dilution by terrigenous materials. In the inner shelf cores, there is no change in the relationship of iodine and bromine to organic carbon at depth. Those from the mid shelf, and especially the outer shelf, on the other hand, show decreases in both I/C org. and Br/C org. ratios, reaching values at about 70 cm depth that are similar to those in surface reduced sediments from the inner shelf. Over this depth interval I/C org. ratios decrease by a factor of five while Br/C org. ratios show a two fold decrease. These changes in the ratios at depth imply that diagenesis within the reducing cores is negligible compared with that of oxidised sediments. The implications of diagenesis with regard to halogen recycling in sediments are briefly discussed.     

Composition of manganese nodules and manganese carbonates from Loch Fyne,Scotland

Manganese nodules and manganese carbonate concretions occur in the upper 10–15 cm of the Recent sediments of Loch Fyne, Argyllshire in water depths of 180–200 m. The nodules are spherical, a few mm to 3 cm in diameter, and consist of a black, Mn-rich core and a thin, red, Fe-rich rim. The carbonate occurs as irregular concretions, 0.5–8 cm in size, and as a cement in irregular nodule and shell fragment aggregates. It partially replaces some nodule material and clastic silicate inclusions, but does not affect aragonitic and calcitic shell fragments.The nodules are approximately 75% pure oxides and contain 30% Mn and 4% Fe. In the cores, the principal mineral phase is todorokite, with a Mn/Fe ratio of 17. The rim consists of X-ray amorphous Fe and Mn oxides with a Mn/Fe ratio of 0.66. The cores are enriched, relative to Al, in K, Ba, Co, Mo, Ni and Sr while the rims contain more P, Ti, As, Pb, Y and Zn.The manganese carbonate has the composition (Mn_47.7 Ca_45.1 Mg_7.2) CO₃. Apart from Cu, all minor elements are excluded from significant substitution in the carbonate lattice.Manganese nodules and carbonates form diagenetically within the Recent sediments of Loch Fyne. This accounts for the high Mn/Fe ratios in the oxide phases and the abundance of manganese carbonate concretions. Mn concentrations in the interstitial waters of sediment cores are high (ca. 10 ppm) as also, by inference, are the dissolved carbonate concentrations.     

Rare earth element zonation in Pacific ferromanganese nodules

The lower surfaces of ferromanganese nodules from the north equatorial Pacific Ocean, which are enriched in Mn, Cu and Ni, and the upper surfaces, which are enriched in Fe, P and Co, have been analyzed for La, Ce, Nd, Sm, Eu, Gd, Dy, Er and Yb. The REE contents are lower and the Ce anomaly is smaller in the lower surfaces than in the upper surfaces. The magnitude of the Ce anomaly increases with decreasing $\text{Mn}\text{Fe}$ ratio, indicative of a seawater origin. The zonal distribution of the other REE supports the conclusion derived previously from inter-nodule and nodule/sediment relationships that diagenetic fixation of rare earths in sediments affects their enrichment by nodular iron oxyhydroxides.     

Concentrations and solubility of heavy metals in muck sediments from the St. Lucie Estuary,U.S.A.

To evaluate muck sediments as a potential soil amendment, total and Mehlich III-extractable concentrations of Cd, Cu, Cr, Ni, Pb, Zn, and Co in 59 muck sediment samples from the St. Lucie Estuary were analyzed. A seven-step chemical fractionation procedure was used to assess the potential mobility of heavy metals. Except for Cd, the average total concentrations of the metals are lower than the reported average concentrations of these elements in municipal composts in the U.S.A. The concentrations were also below critical levels for the safe use of wastes and byproducts in agriculture, as established by the United States Environmental Protection Agency. The Cd, Cu, Cr, Ni, Pb, Zn and Co in the sediments were predominantly associated with silicate minerals in the residual form. Most metals in the muck sediments occur predominantly in weakly mobile or nonbioavailable forms. Use of mucks in neutral pH upland soils should not pose any significant hazards or risk to the environment. However, Cd, Cu, Cr, Ni, Pb, Zn, and Co, especially Zn, Cu, and Pb, could be more readily released from the muck sediments under acidic soil conditions.     

Geology and thermochronometry of the east edge of the Median Batholith (Median Tectonic Zone): a new perspective on Permian to Cretaceous crustal growth of New Zealand

Abstract We report new field, petrological and isotopic data and interpretations from one of New Zealand’s major basement geological boundaries, the contact between the east side of the Median Batholith (formerly Median Tectonic Zone) and the allochthonous Mesozoic terranes of the Eastern Province. In the Nelson and Hollyford–Eglinton areas this contact is a Cenozoic fault, the Median Tectonic Line of earlier workers. However, in the Longwood Range, unfaulted pre-Cenozoic geological relations are preserved intact. Our new Ar–Ar, U–Pb and isotopic data show that the Median Batholith in the Longwood Range consists of two suites. (i) Eastern, isotopically primitive (⁸⁷Sr/⁸⁶Sr_i = 0.702 to 0.703; ?_NdT = + 7 to + 8) trondhjemite and gabbroic rocks of Permian age that we believe are part of the intraoceanic Brook Street arc of the Eastern Province. (ii) Western, isotopically more evolved (⁸⁷Sr/⁸⁶Sr_i = 0.703 to 0.704; ?_NdT = + 3 to + 5) quartz diorites, quartz monzodiorites and rare granites of Middle Triassic to Early Jurassic age that we correlate with a pulse of magmatism elsewhere in the Median Batholith. Field observations in the Longwood Range indicate intrusive, not faulted, contacts between these units and constrain accretion of the Brook Street Terrane to Gondwana to have occurred 230–245 Ma. Intra-batholith shear zones (T ~ 600°C and P ~ 0.2–0.3 GPa) were active at approximately 220 Ma. Modelling of K-feldspar Ar incremental heating ages indicate that most of the Longwood Range had cooled below 175°C by the Middle Jurassic and experienced no subsequent reheating. Significant additional post-accretionary Early Cretaceous and Cenozoic thermotectonic activity in Median Batholith in the Hollyford-Eglinton area is indicated by a new 140 ± 2 Ma U-Pb zircon date on a Largs ignimbrite, as well as by Cenozoic K-feldspar Ar–Ar ages in the Middle Triassic Mistake Diorite.     

Millennial-scale variations in hydrography and biogeochemistry in the Eastern Equatorial Pacific over the last 100 kyr

In this study, we use records of nitrogen isotope ratios (δ¹⁵N), UK’37 temperature estimates, organic carbon and opal percentages from high-resolution sediment cores located in the eastern equatorial Pacific (EEP) to explore the mechanisms linking millennial-scale changes in low-latitude sea surface temperature, water column denitrification and surface productivity to the timing of northern or southern polar climate during the last 100,000 yr. Our results support a hypothesis that the Southern Hemisphere, and its connection to the low latitudes via shallow subsurface ocean circulation, has a primary influence on the biogeochemistry of the EEP. In addition, our results suggest that, during the last glacial stage, denitrification rates fluctuated on millennial timescales in response to water-column ventilation rather than upstream oxidant demand in intermediate-depth waters.However, due to the poor age constraints available for Marine Isotopic Stage (MIS) 3, the EEP sedimentary data presented here could support two conflicting mechanisms, one driven by enhanced intermediate overturning circulation in the Southern Ocean during Heinrich Events/Antarctic Warm Events, implying that subsurface flow rates control thermocline ventilation, and a second one consistent with more sluggish intermediate circulation during Antarctic Warm Events and giving a central role to the temperature control on oxygen solubility in Southern Ocean surface waters.