Evidences for multiple remagnetization of Proterozoic dykes from Iguerda inlier (Anti-Atlas Belt,Southern Morocco)

No paleomagnetic data exist for Paleo-Mesoproterozoic times of the West African Craton (WAC). Therefore, paleogeographic reconstructions for such old geological times are difficult to constrain. Gaps on the sedimentary record and intense remagnetizations are the major problems that paleomagnetic studies come across. Recent geochronological results for dyke swarms that intrude several Proterozoic inliers of WAC in the Anti-Atlas Belt (southern Morocco) revealed ages between Paleoproterozoic and early Neoproterozoic, opening for the first time a window of opportunity to conduct paleomagnetic studies and tentatively infer about the paleoposition of WAC during Proterozoic. On this scope we conducted a paleomagnetic study on seven Proterozoic dykes of the Iguerda inlier. The meaning of the obtained paleomagnetic directions was evaluated by rock magnetic and mineral analyses, complemented by petrographic observations. Our samples record the presence of a complex history of remagnetization, mostly assigned to several Phanerozoic thermal/chemical events, in particular to the late stages of Pan African orogeny (s.l.), to the Late Carboniferous Variscan orogeny, and even to more recent events. The recognized remagnetization processes are related to widespread metamorphic events under greenschist facies followed by low-temperature oxidation, both responsible for the formation of new magnetic phases, like magnetite and hematite. These events obliterated the primary (magmatic) thermo-remanent magnetization and promoted multiple remagnetizations of the dykes, thermally and chemically. For only one dyke the presence of primary magnetization is possible to infer, though not to confirm, and would place WAC at an equatorial position around 1750 Ma.     

The influence of cloud cover index on the accuracy of solar irradiance model estimates

Summary Cloud cover index (CCI) obtained from satellite images contains information on cloud amount and their optical thickness. It is the chief climate data for the assessment of solar energy resources in most radiative transfer models, particularly for the model BRASIL-SR that is currently operational at CPTEC. The wide range of climate environments in Brazil turns CCI determination into a challenging activity and great effort has been directed to develop new methods and procedures to improve the accuracy of these estimations from satellite images (Martins 2001; Martins et al. 2003a; Ceballos et al. 2004). This work demonstrates the influence of CCI determination methods on estimates of surface solar irradiances obtained by the model BRASIL-SR comparing deviations among ground data and model results. Three techniques using visible and/or thermal infrared images of GOES-8 were employed to generate the CCI for input into the model BRASIL-SR. The ground-truth data was provided by the solar radiation station located at Caicó/PE, in Brazilian Northeast region, which is part of the UNEP/GEF project SWERA (Solar and Wind Energy Resources Assessment). Results have shown that the application of the bi-spectral techniques have reduced mean bias error up to 66% and root mean square error up to 50% when compared to the usual technique for CCI determination based on the straightforward determination of month-by-month extremes for maximum and minimum cloud states. Correspondence: Fernando R. Martins, Brazilian Institute for Space Research (INPE), P.O. Box 515, S?o José dos Campos, 12245-970 S?o Paulo, Brazil     

Paradoxes of modernity: imperial Rio de Janeiro, 1808–1821

This paper examines the spatial dynamics of urbanism in Rio de Janeiro during the early nineteenth century. Conventional narratives of modernisation fail to capture the complexities of this moment, between 1808 and 1821, when the city replaced Lisbon as the capital of the Portuguese empire. The position of colony and metropolis were inverted, Portuguese absolutism was bolstered by British liberalism, and a market-economy arose alongside the expansion of slavery. As the newly-created imperial capital, Rio felt the effects of these various transformations: the physical boundaries of the city rapidly expanded, its economy diversified and the cultural life of the city was re-shaped. Our aim in this paper is to understand this particular moment of urban transformation as a product of the intersection of global networks of trade, slavery and industrial capitalism. Rather than depicting the historical geography of the city as a passive space for European conquest and expansion, we consider the extent to which its urban dynamics were shaped by a distinct local geography of globalisation. In particular, we examine the interrelated spatialities that are part and parcel of the modernising process.     

Selective chemical extraction of Cu from selected mineral and soil samples: enhancement of Cu geochemical anomalies in Southern Portugal

The study described herein concerns the application of selective chemical extractions on metal-bearing minerals and soils to geochemical exploration. Specifically, the study aims at the detection of anomalous soils in the vicinity of two mineralized zones in Southern Portugal.A kinetic study of the selectivity of partial chemical extractions applied to Cu minerals has been carried out in order to establish a systematic procedure (reagents, extraction plateau, etc.) which could be recommended for soils of the two study zones. It is shown that: (1) NH₄ acetate dissolves malachite, azurite and cuprite completely and chrysocolla, conicalcite and atacamite only partially; (2) hydroxylamine hydrochloride dissolves chrysocolla and conicalcite only partially; (3) H₂O₂ dissolves chalcopyrite only partially; (4) NH₄ oxalate (U.V.) dissolves conicalcite and atacamite only partially; (5) mixed-acid attack dissolves residual chalcopyrite, chrysocolla, atacamite and conicalcite.A total of 740 soil samples were collected from the Salgadinho and Tinoca areas. The Cu mineralization in the Salgadinho area is situated in an Upper-Devonian Volcanic-Siliceous Complex. The weathering products of the mineralization are mainly amorphous iron oxides, goethite and hematite. The Cu mineralization in Tinoca area is located in the Arronches-Campo Maior belt, where stratiform Cu mineralization is found. The weathering products of the mineralization are mainly malachite, amorphous iron oxides, goethite and hematite.In order to identify the Cu-bearing phases and the extraction plateau, the −80 mesh fraction of two soil samples was submitted to an extraction procedure using the following reagents in sequence: NH₄ acetate, hydroxylamine hydrochloride, NH₄ oxalate (dark), NH₄ oxalate (U.V.) and finally strong acids.In soils from the Salgadinho and Tinoca areas, the use of NH₄ oxalate (U.V.) in single dissolution which would incorporate those phases dissolved by NH₄ acetate and NH₄ oxalate (dark), gives the broadest anomalous surface and higher contrast for Cu than acid digestion. The analysis of NH₄ oxalate (U.V.) extractions, instead of acid digestion, can thus be recommended for both areas.     

The Azambuja fault: An active structure located in an intraplate basin with significant seismicity (Lower Tagus Valley, Portugal)

The Azambuja fault is a NNE trending structure located 50 km NE of Lisbon, in an area of important historical seismicity. It is sited in the Lower Tagus Basin, a compressive foredeep basin related to tectonic inversion of the Mesozoic Lusitanian Basin in the Miocene. The fault is evident in commercial seismic reflection data, where it shows steep thrust geometry downthrowing the Cenozoic sediments to the east. It has also a clear morphological signature, presenting a NNE-SSW trending, east facing, 15 km long scarp, reaching a maximum height of 80 m. The fault scarp is the geomorphic appearance of a flexure expressed as a zone of distributed deformation, where Miocene and Pliocene sediments are tilted eastwards and are cut by steeply dipping meso-scale faults presenting reverse and normal offsets, with a net downthrow to the east. This pattern at the surface is compatible with a steep fault in the basement that tilts and branches through the overlying Cenozoic sedimentary cover. In order to constrain the neotectonic activity of this structure, detailed geological studies were conducted. Morphotectonics was studied through aerial photo interpretation, analysis of topographic maps and digital mapping. Those studies indicate Quaternary slip on the fault in the ranges of 0.05–0.06 mm per year. Seismogenic behaviour was assumed for the Azambuja fault based on the evidence of Quaternary tectonic activity and its location in an area of significant historical seismicity. M _w 6.4–6.7 maximum earthquakes, with recurrence intervals of 10000–25000 years, were estimated based upon the displaced morphological references, cumulative offsets and fault length.     

Ergodicity in Natural Fault Systems

— Attempts to understand the physics of earthquakes over the past decade generally have focused on applying methods and theories developed based upon phase transitions, materials science, and percolation theory to a variety of numerical simulations of extended fault networks. This recent work suggests that fault systems can be interpreted as mean-field threshold systems in metastable equilibrium (Rundle et al., 1995; Klein et al., 1997; Ferguson et al., 1999), and that these results strongly support the view that seismic activity is highly correlated across many space and time scales within large volumes of the earth’s crust (Rundle et al., 2000; Tiampo et al., 2002). In these systems, the time averaged elastic energy of the system fluctuates around a constant value for some period of time and is punctuated by major events that reorder the system before it settles into another metastable energy well. One way to measure the stability of such a system is to check a quantity called the Thirumalai-Mountain (TM) energy metric (Thirumalai and Mountain, 1993; Klein et al., 1996). In particular, using this metric, we show that the actual California fault system is ergodic in space and time for the period in question, punctuated by the occurrence of large earthquakes, and that, for individual events in the system, there are correlated regions that are a subset of the larger fault network.     

Horizontal patterns of water temperature and salinity in an estuarine tidal channel: Ria de Aveiro

This work presents results from two complementary and interconnected approaches to study water temperature and salinity patterns in an estuarine tidal channel. This channel is one of the four main branches of the Ria de Aveiro, a shallow lagoon located in the Northwest coast of the Iberian Peninsula. Longitudinal and cross-sectional fields of water temperature and salinity were determined by spatial interpolation of field measurements. A numerical model (Mohid) was used in a 2D depth-integrated mode in order to compute water temperature and salinity patterns. The main purpose of this work was to determine the horizontal patterns of water temperature and salinity in the study area, evaluating the effects of the main forcing factors. The field results were depth-integrated and compared to numerical model results. These results obtained using extreme tidal and river runoff forcing, are also presented. The field results reveal that, when the river flow is weak, the tidal intrusion is the main forcing mechanism, generating saline and thermal fronts which migrate with the neap/spring tidal cycle. When the river flow increases, the influence of the freshwater extends almost as far as the mouth of the lagoon and vertical stratification is established. Results of numerical modelling reveal that the implemented model reproduces quite well the observed horizontal patterns. The model was also used to study the hydrology of the study area under extreme forcing conditions. When the model is forced with a low river flow (1 m³ s⁻¹) the results confirm that the hydrology is tidally dominated. When the model is forced with a high river flow (1,000 m³ s⁻¹) the hydrology is dominated by freshwater, as would be expected in such an area.     

Electron microprobe dating of monazite from high-T shear zones in the São José de Campestre Massif, NE Brazil

The easternmost domain of the Borborema Province, northeastern Brazil, presents widespread, extensional-related high-temperature metamorphism during the Brasiliano (=Pan-African) orogeny. This event reached the upper amphibolite to granulite facies and provoked generalized migmatization of Proterozoic metapelitic rocks of the Seridó Group and tonalitic to granodioritic orthogneisses of the Archean to Paleoproterozoic basement. We report new geochronological data based on electron microprobe dating of monazite from metapelitic migmatite and leuconorite within the high-T shear zones that make up the eastern continuation of the huge E–W Patos shear belt. These data were also constrained by using the Sm–Nd isotopic systematic on garnet from a syntectonic alkaline granite and two garnet-bearing leucosomes. The results suggest an age of about 578 to 574 Ma for the peak of the widespread high-T metamorphism. This event is best recorded by Sm–Nd garnet-whole rock ages. The U–Th–Pb isotopes on monazite of the metapelitic migmatite show a younger thermal event at 553 ± 10 Ma. When compared to the Sm–Nd garnet-whole rock ages, the U–Th–Pb electron probe monazite ages seem to record an event of slightly lower temperatures after the peak of the high-T metamorphism. This may reflect the difference in the isotopic behavior of the geochronological methods employed. Otherwise, the U–Th–Pb ages on monazites could indicate an event not yet very well defined. In anyway, this paper reveals the partial or even complete re-opening and resetting of the U–Th–Pb isotopic system produced by the action of low-T Ca-rich fluid.     

Solid speciation and availability of chromium in ultramafic soils from Niquelândia, Brazil

The sources and the potential availability of chromium were investigated in ultramafic soils from Niquelândia (Goïas State, Brazil), with chemical extractions associated to mineralogical studies, in order to evaluate its bioavailability and its potential impact on the soil biodiversity. Cr contents are particularly high in the studied soils and its partitioning among the solid phase varies with the position in the landscape and depth. Most of the Cr is associated to Fe-oxides but the amount of exchangeable Cr(VI) is high, particularly in one soil profile. Cr availability is higher than expected, and Cr-tolerant vegetation is probably growing on these soils.