Preliminary observations of oxygen and carbon dioxide of the wintertime Bering Sea marginal ice zone

Wintertime oxygen and pH profiles across the marginal ice zone of the central and southeastern Bering Sea shelf are analyzed and compared with summer data. During the winter, at water depths shallower than 75 m, the water column is homogeneous and near freezing. Between the 75- and 200-m isobaths the structure is essentially two-layered, a cool and fresh upper layer overlying a warmer, more saline bottom layer. The oxygen concentration in the surface mixed layer is higher than the summer values, but the degree of saturation is lower because of the lower temperature in winter. The oxygen degree of saturation in the bottom mixed layer on the shelf in winter are higher than in the surface water in winter and the bottom water in summer.In summer the oxygen and carbon dioxide data show extreme variability governed primarily by biological processes. Winter oxygen and pH data, however, do not scatter as much as the summer data and indicate conservative mixing of several sub-surface water masses. The surface water is undersaturated in both oxygen and carbon dioxide and seems to absorb oxygen, but little carbon dioxide, from the atmosphere.Two stations were occupied in the Aleutian Basin. The homogeneous surface layer has the same oxygen and pH values as in the minimum temperature layer observed in the summer by other investigators at the same location. The result substantiates the hypothesis of early investigators that the summer minimum temperature layer is the remnant local winter water. All winter surface waters sampled are undersaturated with respect to oxygen, suggesting that the input of oxygen through the air-sea exchange does not keep up with the rate of upwelling and cooling, which reduces the degree of oxygen saturation. Surface carbon dioxide is also undersaturated because of cooling. The maximum temperature layer at these two Aleutian Basin stations is warmer, fresher, and contains more oxygen, but less carbon dioxide, than in the summer, suggesting advective input of some nonlocal seawater.     

Upwelling and river runoff as sources of dissolved nitrous oxide to the Alsea estuary,Oregon

Surface waters of Alsea Bay, an unpolluted estuary on the Oregon coast, were analysed for nitrous oxide, nitrate and nitrite on a weekly or biweekly basis during the summer of 1979. The estuary was found to be a variable source of N₂O to the atmosphere. Large and rapid increases in the concentrations of N₂O, NO₃^?, and NO₂^? occurred at the beginning of the sampling period and are attributed to the influx of nutrient-rich upwelling water into the estuary with the tide. The subsequent decline in concentrations of nitrate, nitrite and nitrous oxide over the remainder of the summer is attributed to a decrease in upwelling intensity, a decline in nitrification rates and to assimilatory nitrate reduction. Measurements of nitrous oxide at six stations along the Alsea River were also made in September and October before and after the onset of the rainy season. Samples taken after flood conditions were established were systematically 50% higher than pre-flood samples. The data suggest that soil runoff results in elevated concentrations of N₂O in rivers.     

Kinetic studies of lead(II) uptake by the seagrass Zostera muelleri in water by radiotracing,atomic absorption spectrometry and electrochemical techniques

Evidence was found that uptake of lead from seawater in both model and natural systems by the leaves of the seagrass Zostera muelleri does occur for live, dead and scraped leaves at all the lead concentrations tested. Positive uptake of lead was measured using the three analytical techniques of radio-tracer, differential pulse anodic stripping voltammetry and atomic absorption spectrometry; similar uptake profiles were obtained for each technique. Profiles always showed an initial rapid uptake phase followed by a gradual transition to a plateau phase at which an approximate equilibrium between lead attached to seagrass and free ionic lead in seawater was reached. The presence of active lead uptake processes was indicated in experiments which attempted to remove lead from leaves by a chelating agent.     

Chronology and evolution of the northern Iceland Plateau

New aeromagnetic data, K-Ar age determinations of dredged marine igneous rocks, as well as other geophysical evidence have shed light on the chronology, nature and evolution of the northern Iceland Plateau. Correspondence between seismic refraction profiles taken on the Jan Mayen Ridge and westward through Jan Mayen Island, suppressed aeromagnetic anomalies, earthquake surface wave studies, and ages of dredged igneous rocks suggest these strata may form an extended region of thickened crust, possibly of Caledonian age, extending westward toward the Kolbeinsey Ridge and northwest to the south wall of the Jan Mayen Fracture Zone.     

Relationships between Campi Flegrei and Mt. Somma volcanism: evidence from melt inclusions in clinopyroxene phenocrysts from volcanic breccia xenoliths

Summary We present compositions of reheated melt inclusions in clinopyroxene phenocrysts from three mafic xenoliths in Breccia Museo, Campi Flegrei, Italy. Melt inclusion compositions are remarkably different from the compositions of known contemporary Campi Flegrei lavas, being significantly enriched in K₂O and depleted in Na₂O. Some differences are also evident in FeO^* (total Fe as FeO) and TiO₂ contents. The clinopyroxene phenocrysts could not have crystallised from Campi Flegrei magmas. We suggest that they originated from a volcanic system genetically very similar to, and possibly linked with, the >14 ka volcanic system of Mt. Somma, another Campanian volcano ∼ 30 km east from Campi Flegrei, from which Vesuvius subsequently developed. This result indicates a close relationship (or link) between the two volcanic systems which have until now been considered separate. We speculate that the link was established prior to eruption of the Neapolitan Yellow Tuff (NYT) (∼ 12 ka). The xenoliths were derived from a volcanic system older than the host breccias themselves. We suggest that this older volcanism had close similarities with the volcanism of the older products of Mt. Somma (∼25 ka). Received March 20, 2000; accepted November 2, 2000     

About Darcy's law in non-Galilean frame

This paper is aimed towards investigating the filtration law of an incompressible viscous Newtonian fluid through a rigid non-inertial porous medium (e.g. a porous medium placed in a centrifuge basket). The filtration law is obtained by upscaling the flow equations at the pore scale. The upscaling technique is the homogenization method of multiple scale expansions which rigorously gives the macroscopic behaviour and the effective properties without any prerequisite on the form of the macroscopic equations. The derived filtration law is similar to Darcy's law, but the tensor of permeability presents the following remarkable properties: it depends upon the angular velocity of the porous matrix, it verifies Hall–Onsager's relationship and it is a non-symmetric tensor. We thus deduce that, under rotation, an isotropic porous medium leads to a non-isotropic effective permeability. In this paper, we present the results of numerical simulations of the flow through rotating porous media. This allows us to highlight the deviations of the flow due to Coriolis effects at both the microscopic scale (i.e. the pore scale), and the macroscopic scale (i.e. the sample scale). The above results confirm that for an isotropic medium, phenomenological laws already proposed in the literature fails at reproducing three-dimensional Coriolis effects in all types of pores geometry. We show that Coriolis effects may lead to significant variations of the permeability measured during centrifuge tests when the inverse Ekman number Ek⁻¹ is 𝒪(1). These variations are estimated to be less than 5% if Ek⁻¹<0.2, which is the case of classical geotechnical centrifuge tests. We finally conclude by showing that available experimental data from tests carried out in centrifuges are not sufficient to determining the effective tensor of permeability of rotating porous media. Copyright © 2004 John Wiley & Sons, Ltd.