Geochronology of anthropogenic pollutants in riparian wetland sediments of the Lippe River (Germany)

Anthropogenic pollutants were determined in a dated sediment core, collected from a riparian wetland of the Lippe River (Ruhr district, Germany). The historical trend in heavy metals, polycyclic aromatic hydrocarbons, organochlorines, polychlorinated biphenyls and linear alkylbenzenes as well as more recent contaminants such as industrial additives, organotins, synthetic musks, methyltriclosan and some other compounds were determined for the time period between 1930 and 1986. Emission sources, information on technical production and usage, as well as on the individual pollution pathways, with appropriate environmental stability, were considered in the interpretation of the sediment contamination over the past 50 years.Contaminants were analysed and interpreted according to two different criteria: (a) the origin of the main contaminants as related to mining and industrial activities as well as municipal sewage and agricultural effluents and (b) the pollution history. Due to a significant appearance of formerly missing contaminants in sediments deposited since 1970, we suggest classifying contaminants as either common (predating 1970) or modern (postdating 1970).In summary, the study provided a comprehensive reconstruction of the pollution history of the Lippe River system.     

Rockfall Hazard Analysis From Discrete Fracture Network Modelling with Finite Persistence Discontinuities

Developing an accurate representation of the rock mass fabric is a key element in rock fall hazard analysis. The orientation, persistence and density of fractures control the volume and shape of unstable blocks or compartments. In this study, the discrete fracture modelling technique and digital photogrammetry were used to accurately depict the fabric. A volume distribution of unstable blocks was derived combining polyhedral modelling and kinematic analyses. For each block size, probabilities of failure and probabilities of propagation were calculated. A complete energy distribution was obtained by considering, for each block size, its occurrence in the rock mass, its probability of falling, its probability to reach a given location, and the resulting distribution of energies at each location. This distribution was then used with an energy–frequency diagram to assess the hazard.     

Resolving mechanisms of toxicity while pursuing ecotoxicological relevance?

In this age of modern biology, aquatic toxicological research has pursued mechanisms of action of toxicants. This has provided potential tools for ecotoxicologic investigations. However, problems of biocomplexity and issues at higher levels of biological organization remain a challenge. In the 1980s and 1990s and continuing to a lesser extent today, organisms residing in highly contaminated field sites or exposed in the laboratory to calibrated concentrations of individual compounds were carefully analyzed for their responses to priority pollutants. Correlation of biochemical and structural analyses in cultured cells and tissues, as well as the in vivo exposures led to the production and application of biomarkers of exposure and effect and to our awareness of genotoxicity and its chronic manifestations, such as neoplasms, in wild fishes. To gain acceptance of these findings in the greater environmental toxicology community, “validation of the model” versus other, better-established often rodent models, was necessary and became a major focus. Resultant biomarkers were applied to heavily contaminated and reference field sites as part of effects assessment and with investigations following large-scale disasters such as oil spills or industrial accidents.

Over the past 15 years, in the laboratory, small aquarium fish models such as medaka (Oryzias latipes), zebrafish (Danio rerio), platyfish (Xiphophorus species), fathead minnow (Pimephales promelas), and sheepshead minnow (Cyprinodon variegatus) were increasingly used establishing mechanisms of toxicants. Today, the same organisms provide reliable information at higher levels of biological organization relevant to ecotoxicology. We review studies resolving mechanisms of toxicity and discuss ways to address biocomplexity, mixtures of contaminants, and the need to relate individual level responses to populations and communities.     

Paleomagnetism of the Cambro-Ordovician McClure Mountain alkalic complex,Colorado

The Middle to Late Cambrian loop in the North American apparent polar wander path (APWP) has been variously attributed to tectonic rotations, remagnetizations and primary magnetizations. Although no primary thermal remanent magnetizations or primary detrital remanent magnetizations have as yet been demonstrated, the temporally self-consistent nature of the loop has been used as an argument for primary magnetizations. We have studied535 ± 5Ma nepheline syenites and syenites of the McClure Mountain alkalic complex, as well as495 ± 10Ma red trachyte dikes which intruded the complex, in an effort to find a primary TRM. Because Zijderveld analysis yielded consistent results for only one trachyte dike, remagnetization great-circle analysis was employed, giving a pole for the trachyte dikes at the tip of the loop (43°N, 114°E), while the syenites and nepheline synenites gave a pole at the base of the loop (18°N, 142°E). The magnetic carrier in the trachytes is hematite which apparently formed during a pervasive hydrothermal alteration. KAr whole rock dating of the trachytes suggests a Pennsylvanian age for the alteration, and thus a late Paleozoic remagnetization of the trachytes. Thus, the low-latitude Cambrian pole is confirmed, but we find no evidence in this study to support the primary nature of the Cambrian APWP.     

Slump debris flows in the Akovolwo Mountains area of Benue State,Nigeria

In September 1979, rain-induced complex landslides occurred in two separate localities along the slopes of the Akovolwo Mountains near Jato-Aka in the Kwande Local Government area of Benue State, Nigeria.The two movements developed on bedrock slopes covered by a veneer of colluvium and (or) residuum no more than 1.5 to 2m deep. Each started as a slump and graduated into a debris flow. The slump, extending downhill a short distance away from the head scarp, had been reconstituted into a debris flow as the initial movement (sliding movement) of the soil mass caused remoulding of the saturated moving mass into viscous debris-laden mud. The resulting mass moved partly along a pre-existing mountain stream channel and partly along a fresh channel it cleared in the savanna forest. At the break of slope, the mass of boulders was dumped and a trail of smaller fragments littered the channels towards the Katsina-Ala River.     

Applying essentially non‐oscillatory interpolation to controlled‐source electromagnetic modelling*

Modelling and inversion of controlled‐source electromagnetic (CSEM) fields requires accurate interpolation of modelled results near strong resistivity contrasts. There, simple linear interpolation may produce large errors, whereas higher‐order interpolation may lead to oscillatory behaviour in the interpolated result. We propose to use the essentially non‐oscillatory, piecewise polynomial interpolation scheme designed for piecewise smooth functions that contains discontinuities in the function itself or in its first or higher derivatives. The scheme uses a non‐linear adaptive algorithm to select a set of interpolation points that represent the smoothest part of the function among the sets of neighbouring points. We present numerical examples to demonstrate the usefulness of the scheme. The first example shows that the essentially non‐oscillatory interpolation (ENO) scheme better captures an isolated discontinuity. In the second example, we consider the case of sampling the electric field computed by a finite‐volume CSEM code at a receiver location. In this example, the ENO interpolation performs quite well. However, the overall error is dominated by the discretization error. The other examples consider the comparison between sampling with essentially non‐oscillatory interpolation and existing interpolation schemes. In these examples, essentially non‐oscillatory interpolation provides more accurate results than standard interpolation, especially near discontinuities.     

The biogeochemical sulfur cycle in the marine boundary layer over the Northeast Pacific Ocean

The major components of the marine boundary layer biogeochemical sulfur cycle were measured simultaneously onshore and off the coast of Washington State, U.S.A. during May 1987. Seawater dimethylsulfide (DMS) concentrations on the continental shelf were strongly influenced by coastal upwelling. Concentration further offshore were typical of summer values (2.2 nmol/L) at this latitude. Although seawater DMS concentrations were high on the biologically productive continental shelf (2–12 nmol/L), this region had no measurable effect on atmospheric DMS concentrations. Atmospheric DMS concentrations (0.1–12 nmol/m³), however, were extremely dependent upon wind speed and boundary layer height. Although there appeared to be an appreciable input of non-sea-salt sulfate to the marine boundary layer from the free troposphere, the local flux of DMS from the ocean to the atmosphere was sufficient to balance the remainder of the sulfur budget.