An overview of toxicant identification in sediments and dredged materials

The identification of toxicants affecting aquatic benthic systems is critical to sound assessment and management of our nation's waterways. Identification of toxicants can be useful in designing effective sediment remediation plans and reasonable options for sediment disposal. Knowledge of which contaminants affect benthic systems allows managers to link pollution to specific dischargers and prevent further release of toxicant(s). In addition, identification of major causes of toxicity in sediments may guide programs such as those developing environmental sediment guidelines and registering pesticides, while knowledge of the causes of toxicity which drive ecological changes such as shifts in benthic community structure would be useful in performing ecological risk assessments. To this end, the US Environmental Protection Agency has developed tools (toxicity identification and evaluation (TIE) methods) that allow investigators to characterize and identify chemicals causing acute toxicity in sediments and dredged materials. To date, most sediment TIEs have been performed on interstitial waters. Preliminary evidence from the use of interstitial water TIEs reveals certain patterns in causes of sediment toxicity. First, among all sediments tested, there is no one predominant cause of toxicity; metals, organics, and ammonia play approximately equal roles in causing toxicity. Second, within a single sediment there are multiple causes of toxicity detected; not just one chemical class is active. Third, the role of ammonia is very prominent in these interstitial waters. Finally, if sediments are divided into marine or freshwater, TIEs perforMed on interstitial waters from freshwater sediments indicate a variety of toxicants in fairly equal proportions, while TIEs performed on interstitial waters from marine sediments have identified only ammonia and organics as toxicants, with metals playing a minor role. Preliminary evidence from whole sediment TIEs indicates that organic compounds play a major role in the toxicity of marine sediments, with almost no evidence for either metal or ammonia toxicity. However, interpretation of these results may be skewed because only a small number of interstitial water (n = 13) and whole sediment (n = 5) TIEs have been completed. These trends may change as more data are collected.     

Recent Results from Studies of Electric Discharges in the Mesosphere

The paper reviews recent advances in studies of electric discharges in the stratosphere and mesosphere above thunderstorms, and their effects on the atmosphere. The primary focus is on the sprite discharge occurring in the mesosphere, which is the most commonly observed high altitude discharge by imaging cameras from the ground, but effects on the upper atmosphere by electromagnetic radiation from lightning are also considered. During the past few years, co-ordinated observations over Southern Europe have been made of a wide range of parameters related to sprites and their causative thunderstorms. Observations have been complemented by the modelling of processes ranging from the electric discharge to perturbations of trace gas concentrations in the upper atmosphere. Observations point to significant energy deposition by sprites in the neutral atmosphere as observed by infrasound waves detected at up to 1000 km distance, whereas elves and lightning have been shown significantly to affect ionization and heating of the lower ionosphere/mesosphere. Studies of the thunderstorm systems powering high altitude discharges show the important role of intracloud (IC) lightning in sprite generation as seen by the first simultaneous observations of IC activity, sprite activity and broadband, electromagnetic radiation in the VLF range. Simulations of sprite ignition suggest that, under certain conditions, energetic electrons in the runaway regime are generated in streamer discharges. Such electrons may be the source of X- and Gamma-rays observed in lightning, thunderstorms and the so-called Terrestrial Gamma-ray Flashes (TGFs) observed from space over thunderstorm regions. Model estimates of sprite perturbations to the global atmospheric electric circuit, trace gas concentrations and atmospheric dynamics suggest significant local perturbations, and possibly significant meso-scale effects, but negligible global effects.     

Critical soil conditions for oxygen stress to plant roots: Substituting the Feddes-function by a process-based model

Effects of insufficient soil aeration on the functioning of plants form an important field of research. A well-known and frequently used utility to express oxygen stress experienced by plants is the Feddes-function. This function reduces root water uptake linearly between two constant pressure heads, representing threshold values for minimum and maximum oxygen deficiency. However, the correctness of this expression has never been evaluated and constant critical values for oxygen stress are likely to be inappropriate. On theoretical grounds it is expected that oxygen stress depends on various abiotic and biotic factors. In this paper, we propose a fundamentally different approach to assess oxygen stress: we built a plant physiological and soil physical process-based model to calculate the minimum gas filled porosity of the soil (_{gas_min}) at which oxygen stress occurs.First, we calculated the minimum oxygen concentration in the gas phase of the soil needed to sustain the roots through (micro-scale) diffusion with just enough oxygen to respire. Subsequently, _{gas_min} that corresponds to this minimum oxygen concentration was calculated from diffusion from the atmosphere through the soil (macro-scale).We analyzed the validity of constant critical values to represent oxygen stress in terms of _{gas_min}, based on model simulations in which we distinguished different soil types and in which we varied temperature, organic matter content, soil depth and plant characteristics. Furthermore, in order to compare our model results with the Feddes-function, we linked root oxygen stress to root water uptake (through the sink term variable F, which is the ratio of actual and potential uptake).The simulations showed that _{gas_min} is especially sensitive to soil temperature, plant characteristics (root dry weight and maintenance respiration coefficient) and soil depth but hardly to soil organic matter content. Moreover, _{gas_min} varied considerably between soil types and was larger in sandy soils than in clayey soils. We demonstrated that F of the Feddes-function indeed decreases approximately linearly, but that actual oxygen stress already starts at drier conditions than according to the Feddes-function. How much drier is depended on the factors indicated above. Thus, the Feddes-function might cause large errors in the prediction of transpiration reduction and growth reduction through oxygen stress.We made our method easily accessible to others by implementing it in SWAP, a user-friendly soil water model that is coupled to plant growth. Since constant values for _{gas_min} in plant and hydrological modeling appeared to be inappropriate, an integrated approach, including both physiological and physical processes, should be used instead. Therefore, we advocate using our method in all situations where oxygen stress could occur.     

Large wavenumber convection in the rotating annulus

Abstract

The annulus model considers convection between concentric cylinders with sloping endwalls. It is used as a simplified model of convection in a rapidly rotating sphere. Large azimuthal wavenumbers are preferred in this problem, and this has been exploited to develop an asymptotic approach to nonlinear convection in the annulus. The problem is further reduced because the Taylor-Proudman constraint simplifies the dependence in the direction of the rotation vector, so that a nonlinear system dependent only on the radial variable and time results. As Rayleigh number is increased a sequence of bifurcations is found, from steady solutions to periodic solutions and 2-tori, typically ending in chaotic behaviour. Both the magnetic (MHD convection) and non-magnetic problem has been considered, and in the non-magnetic case our bifurcation sequence can be compared with those found by previous two-dimensional numerical simulations.     

Seismic design and response evaluation of unbonded post‐tensioned hybrid coupled wall structures

This paper presents an analytical investigation on the seismic design and response of coupled wall structures that use unbonded post‐tensioned steel coupling beams. Both monolithic cast‐in‐place reinforced concrete wall piers and precast concrete wall piers are considered. Steel top and seat angles are used at the coupling beam ends for energy dissipation. The seismic design of prototype structures to achieve target displacement‐based performance objectives is evaluated based on nonlinear static and dynamic time history analyses. Additional recommendations are provided on shear design. Comparisons with ‘conventional’ structures that use embedded steel coupling beams as well as isolated walls with no coupling are provided. The results indicate that while the peak lateral displacements of unbonded post‐tensioned coupled wall structures are larger than the peak displacements of structures with embedded beams, the residual displacements are significantly reduced as a result of the restoring effect of the post‐tensioning steel. Copyright © 2008 John Wiley & Sons, Ltd.     

Influence of Zostera marina canopies on unidirectional flow,hydraulic roughness and sediment movement

Seagrasses develop extensive or patchy underwater meadows in coastal areas around the world, forming complex, highly productive ecosystems. Seagrass canopies exert strong effects on water flow inside and around them, thereby affecting flow structure, sediment transport and benthic ecology. The influence of Zostera marina canopies on flow velocity, turbulence, hydraulic roughness and sediment movement was evaluated through laboratory experiments in 2 flumes and using live Z. marina and a mobile sand bed. Profiles of instantaneous velocities were measured and sediment movement was identified upstream, within and downstream of patches of different sizes and shoot density and at different free-stream velocities. Flow structure was characterised by time-averaged velocity, turbulence intensity and Turbulent Kinetic Energy (TKE). When velocity data were available above the canopy, they were fitted to the Law of the Wall and shear velocities and roughness lengths were calculated. When a seagrass canopy was present, three layers were distinguishable in the water column: (1) within canopy represented by low velocities and high turbulence; (2) transition zone around the height of the canopy, where velocities increased, turbulence decreased and TKE was high; and (3) above canopy where velocities were equal or higher than free-stream velocities and turbulence and TKE were lower than below. Shoot density and patch-width influenced this partitioning of the flow when the canopy was long enough (based on flume experiments, at least more than 1 m-long). The enhanced TKE observed at the canopy/water interface suggests that large-scale turbulence is generated at the canopy surface. These oscillations, likely to be related to the canopy undulations, are then broken down within the canopy and high-frequency turbulence takes place near the bed. This turbulence ‘cascade’ through the canopy may have an important impact on biogeochemical processes. The velocity above the canopy generally followed a logarithmic profile. Roughness lengths were higher above the canopy than over bare sand and increased with increasing distance from the leading edge of the canopy; however, they were still small (<1 cm) compared to other studies in the literature. Within and downstream of the canopy, sediment movement was observed at velocities below the threshold of motion. It was likely caused by the increased turbulence at those positions. This has large implications for sediment transport in coastal zones where seagrass beds develop.     

Comparison of vegetation and stream sediment geochemical patterns in northeastern New South Wales

This study compares the geochemical response of stream sediments and adjacent vegetation samples, with variations in drainage catchment lithology and the occurrence of mineralisation, within a 14,000-km² block of the northeastern region of New South Wales, Australia. The area contains a range of lithologies within a Devonian–Permian accretionary complex and Mesozoic sedimentary basin, as well as a wide range of mineral deposits. Sampling was designed to confine each sub-catchment to a single lithological group (mafic and ultramafic rocks, acid intrusives, volcanics, metasedimentary and sedimentary rocks or alluvium). Leaves of over 20 genera, dominated by (Allo-)Casuarina, Eucalyptus, Acacia, Callistemon and Melaleuca, and the <250-μm fraction of the stream sediments were analysed by INAA. The uptake of most trace elements varied between genera, with Callistemon displaying the highest median As and La contents and Eucalyptus the highest Co contents. The stream sediment and vegetation geochemistry reflect both hydromorphic and mechanical dispersion within sub-catchments, with regional patterns dominant over local influences. The vegetation appears to be influenced to a greater extent by hydromorphic dispersion, as indicated by differences in the ratio of leaf to sediment Cr concentrations in sub-catchments draining serpentinites and basalts. Although most known mineral deposits in the region produced anomalies in at least one medium, there was little correlation between the trace element concentrations of the vegetation and stream sediments on a site-by-site basis. A number of Au targets were only detected on the basis of the biogeochemistry and others were only reflected in the stream sediment geochemistry. In general, vegetation displayed more extensive dispersion trains away from mineralisation than did the stream sediments. Differences in the response of the two sampling media suggest their joint use in exploration or environmental surveys to maximise the probability of detecting mineralisation.     

Rôles respectifs de l''advection et de la décantation sur la ride médio-atlantique (40° à 50°N)

Coring at 45 sites in the North Atlantic permitted to determine flux velocity and chemical composition of pelagic sediments. Piston cores were used to carry out a comparative study between the post-glacial period (10,000 yr. B.P. until present) and last glacial period (75,000–10,000 yr. B.P.). Special attention has been paid to the Mid-Atlantic Ridges-Azores-Iceland area, where an enrichment of chemical elements was observed with regards to “regional ocean ground noise”, perceived on an isolated seamount of the abyssal plain.This “ground noise” characterized by the presence of Pb, Rb, U, Th, illite and chlorite, is associated to a settling vertical flux since the surface brought by surface currents and wind transport since the North American shield: sediments, here, are continental soil erosion products.The ridge is clearly enriched by Ba, Br, Fe, Ti, Mn, Cu, Ni, Co and As. Ba and Br are mostly associated with planktonic carbonates. Part of Ba may be linked to the ridge's activity. Basalt weathering on the ridge supplies a part of Fe in excess. Hydrothermal activity may account for Mn, Cu, Co, Ni and As enrichment. Most of the excess observed may be explained by intrusion of advective inputs from erosion Icelandic products (Fe, Ti, Cu, Ta, Sc and smectites), probably transported by Norwegian bottom currents.Advective flux (Icelandic-Faeroan basaltic materials) and flux linked to submarine ridge activity represent 30% of inorganic sedimentation. Vertical flux (North American continental-derived terrigenous materials) represent 70% of inorganic sedimentation. These percentages are very similar to those which were calculated for the Pacific.

Résumé

Les vitesses d'accumulation (flux) et les compositions chimiques ont été déterminées pour des sédiments pélagiques, dans 45 sites de l'océan Atlantique Nord. Les échantillons, prélevés par carottage Kullenberg, ont permis de réaliser une étude comparative de la période post-glaciaire (10.000 ans B.P. à nos jours) et du dernier glaciaire (75.000–10.000 ans B.P.). Notre attention s'est portée particulièrement sur la dorsale médioatlantique Açores-Islande où l'on observe des enrichissements en éléments chimiques par rapport au “bruit de fond océanique régional” appréhendé sur un dôme isolé dans la plaine abyssale.À ce bruit de fond, caractérisé par Pb, Rb, U, Th, illite et chlorite, est associé un flux vertical mis en place par décantation depuis la surface, apporté par le vent et les courants de surface depuis le craton nord-américain; il s'agit des produits d'érosion des sols continentaux.L'enrichissement de la dorsale est net pour Ba, Br, Fe, Ti, Mn, Cu, Ni, Co et As.Ba et Br précipite en grande partie avec les carbonates planctoniques. Une partie de Ba peut être associée à l'activité de la ride. L'altération des basaltes de la ride fournit une partie du Fe en excès. L'activité hydrothermale peut expliquer les enrichissements en Mn, Cu, Co, Ni et As.L'essentiel de l'excès observé est expliqué par un apport advectif de produits d'érosion de l'Islande (Fe, Ti, Cu, Ta, Sc et smectites). Leur vecteur serait le courant de fond de la mer de Norvège.Le flux advectif (matériaux basaltiques islando-faeroan) et le flux liéà l'activité sousmarine de la dorsale représenterait 29% de la sédimentation inorganique.Le flux vertical (matériaux continentaux terrigènes nord-américain) représenterait 71% de la sédimentation inorganique. Ces chiffres sont très proches de ceux qui ont été évalués dans le Pacifique.     

Evidence for the thrust emplacement of the ‘Lesser Himalaya’ Chur granite,Himachal Pradesh

Numerous peraluminous and porphyritic granitic bodies and augen gneisses of granitic compositions occur in the nappe sequences of the Lower Himalaya. They are Proterozoic-to-lower Paleozoic in age and have been grouped into the ‘Lesser Himalaya granite belt’. The mode of emplacement and tectonic significance of these granites are as yet uncertain but they are generally considered to be sheet-like intrusions into the surrounding rocks. The small and isolated granite body (the Chur granite) that crops out around the Chur peak in the Himachal Himalaya is one of the more famous of these granites. Several lines of evidence have been adduced to show that the Chur granite has a thrust (the Chur thrust) contact with the underlying metasedimentary sequence (locally called the Jutogh Group). The Chur granite with restricted occurrence at the highest topographic and structural levels represents an erosional remnant of a much larger sub-horizontal thrust sheet. The contact relations between the country rocks and many of the other granite and granitic augen gneisses in the Lesser Himalaya belt are apparently similar to that of the Chur granite suggesting that at least some of them may also represent thrust sheets.