The observation that a fraction of organic matter produced in marine systems evades the concerted efforts of microbial communities and is buried in sediments suggests that there are ‘speed bumps’ in carbon degradation pathways that impede microbially driven remineralization processes. The initial step in degradation of macromolecules, extracellular enzymatic hydrolysis, is often stated to be ‘the’ rate-limiting step in carbon remineralization. Experimental investigations described here, however, demonstrate that at least in certain cases, microbes produce extracellular enzymes on time scales of hours to tens of hours in response to substrate addition, and hydrolysis is extremely rapid. If enzymatic hydrolysis can be rapid, what factors slow or stop organic matter degradation? A lack of the correct inducer to initiate enzyme production, and/or a lack of the correct organism to produce the required enzyme, may result in a complete lack of hydrolysis in certain environments—a barricade, rather than a speed bump. Preliminary evidence supporting this hypothesis includes a comparison of polysaccharide hydrolysis in seawater and sediments, which demonstrates that the spectrum of enzymes active in seawater and sediments are fundamentally different. Furthermore, a survey of enzyme activities in surface waters from a range of locations suggests that pelagic microbial communities also differ widely in their abilities to express specific extracellular enzymes. Trans-membrane transport through porins is yet another potential location of structure-related selectivity.Our efforts to identify speed bumps and barricades are hampered by our inability to structurally characterize in sufficient detail the macromolecular structures present in marine systems. Furthermore, assessments of organic matter ‘quality’ from a chemical perspective do not necessarily accurately reflect the availability of organic carbon to microbial communities. For these communities, in fact, ‘quality’ may be a variable, which depends on the enzymatic and uptake capabilities of community members. To begin to assess substrate structure and quality from a microbial perspective, we will have to combine specific knowledge of macromolecular structures with detailed investigations of the enzymatic and transport capabilities of heterotrophic marine microbes. 相似文献
Extensive potassium and phosphorous-rich mineralization occurs on the outer continental shelf of the southern and west coasts of South Africa and Nambia. This article reviews the potential of exploiting these deposits in an environmentally sound manner for the manufacture of fertilizer. At present, reserves of potash and phosphate fertilizer are exploited from terresterial deposits, the majority being surface mined. The use of fertilizer in South Africa has shown no growth in the past 13 years, and, in some years, usage has even declined. On average, over the last decade, South Africa has consumed 2 million Mt of fertilizer (including nitrogen) per annum, the vast majority of phosphate fertilizer being produced by FOSKOR from the Phalaborwa Igneous Complex. Potash fertilizer is imported into South Africa. Although fertilizer consumption is expected to decrease in the short-term, there are good future prospects for the domestic and international fertilizer market. Considerable research into both glauconitic (containing K 2 O) and phosphatic deposits along the southern African continental shelf indicate that these sedimentary deposits have a complex genesis and mineralization. Of the total K 2 O reserves of 1300 million Mt on the southern African margin, 1000 million Mt is located off the southern African west coast, and the remainder situated on the Agulhas Bank. The largest glauconite concentration ( ±300 million Mt K 2 O) off southern Africa lies west of Saldanha Bay, South Africa. The distribution of P 2 O 5 off southern Africa is dominated by the vast deposit between Walvis Bay and Luderitz, Nambia. This reserve is estimated to contain 1000 million Mt of greater than 5% P 2 O 5 in a relatively small area of about 10000 km2. The phosphorite deposit south of Saldanha Bay constitutes a reserve of ±3500 million Mt of apatite and the deposit on the Agulhas Bank comprises 5500 million Mt. The phosphate deposit off Saldanha Bay occurs as an extensive, low to medium grade deposit. Although vast resources of potash and phosphatic minerals occur along the southern African outer continental shelf the expensive nature of marine exploitation may render most of these deposits, especially the phosphates, subeconomic. The low price of fertilizer andextensive natureontheonland deposits, although confined to asmallnumber of countries, mean that it will not be financially viable to extract these deposits. Assuming high grade glauconitic sand with the right composition can be located, the high market price indicates good future prospects for these potash deposits. 相似文献
The construction of reservoir models is frustrated by the fact that core and well cover only a fraction of the reservoir volume and it is therefore difficult to determine features like facies shape, -size, and -distribution, inter- and intra-facies boundaries and lateral trends from them. These features are, however, critical to fluid flow and they should necessarily be incorporated in the reservoir model and we therefore propose to systematically describe geometry and distribution of facies. To this end we make use of “standard facies models” that a priori contain all elements and boundaries of facies for a number of typical depositional environments. 相似文献
This paper discusses the use of Hermite polynomial in the derivation of statistical properties of waves, wave field kinematics and dynamics and wave forces under various conditions. Specifically, covariance functions and approximate spectra are obtained for (1) wave force on vertical cylinder according to Morison's formula, (2) horizontal fluid particle velocity considering the effects of free surface fluctuations, and (3) elevation of breaking waves. 相似文献
The most widely used mathematical model to represent flow-induced in-line forces on structures is based on the Morison1 equation. The present paper investigates the validity of using an extension of Morison's equation for non-stationary structures, by comparing predictions with results from a simple laboratory experiment. An elastically-mounted circular cylinder is placed in the sinusoidal flow of a U-tube, and responds in-line with the flow. Cylinder forces and responses are recorded over a range of Keulegan Carpenter numbers up to 35. An equation of motion is solved simply by using relative coordinates and by employing equivalent linearisation. The linear results are compared over a wide variation of parameters with solutions using the full nonlinear equation. Thereafter experimental results are compared with linear predictions. 相似文献
The paper presents a comparison between experimental data and numerical results of the hydrodynamic coefficients and also of the wave induced motions and loads on a fast monohull model. The model with 4.52 m length was constructed in Fibre Reinforced Plastic (FRP), and made up of 4 segments connected by a backbone in order to measure sectional loads. The objective of the investigation was to assess the capability of a nonlinear time domain strip method to represent the nonlinear and also the forward speed effects on a displacement high speed vessel advancing in large amplitude waves. With this objective in mind the experimental program included forced oscillation tests in heaving and pitching, for a range of periods, three different amplitudes and several speeds of advance. In head regular waves comprehensive ranges of wave periods, wave steepness and speeds, were tested in order to measure heave, pitch and loads in three cross sections.
The numerical method assumes that the radiation and diffraction hydrodynamic forces are linear and the nonlinear contributions arise from the hydrostatics and Froude–Krilov forces and the effects of green water on deck. The assumption of linearity of the radiation forces is validated by comparing calculated hydrodynamic coefficients with experimental data for three different amplitudes of the forced oscillations. Both global coefficients and sectional coefficients are compared. The motions and loads in waves are compared in terms of first and higher harmonic amplitudes and also in terms of sagging and hogging peaks. 相似文献
In this paper we discuss the results of a swath bathymetric investigation of the Canary archipelago offshore area. These new
data indicate that volcanism is pervasive throughout the seafloor in the region, much more that would be suggested by the
islands. We have mapped tens of volcanic edifices between Fuerteventura and Gran Canaria and offshore Tenerife, La Gomera,
El Hierro and La Palma. Volcanic flows are present between Tenerife and La Gomera and salic necks dominate the eastern insular
slope of La Gomera. This bathymetry also supports land geologic studies that indicate that the oceanic archipelago has acquired
its present morphology in part by mass wasting, a consequence of the collapse of the volcanic edifices. In the younger islands,
Tenerife, La Palma and El Hierro, the Quaternary (1.2 to 0.15 Ma) debris avalanches are readily recognizable and can be traced
offshore for distances measured in tens of km. Off the older islands, Lanzarote, Fuerteventura, Gran Canaria and La Gomera
(<20 to 3.5 Ma), the avalanches have been obscured by subsequent turbidity current deposition and erosion as well as hemipelagic
processes. The failure offshore western Lanzarote is in the form of a ramp at the base of the insular slope bound on the seaward
side by a scarp. Its size and the lack of evidence of rotation along its landwards side precludes the possibility that it
is a slump. It probably represents a slide whose outer scarp is caused by break-up of the slide. Mounds on the ramp’s surface
may represent post-displacement volcanic structures or exotic blocks transported to their present locations by the slide.
The failures offshore Fuerteventura are so large that, although they occurred in the Miocene-Pliocene, exotic blocks displaced
from upslope are still recognizable in the insular margin morphology. The Canary Island insular margin appears to be a creation
of Miocene-Pliocene mass wasting and more recent turbidity current deposition and erosion, and hemilepagic deposition. Failures
offshore La Gomera are due to debris flows and/or turbidity currents. These events have obscured earlier mass wasting events.
An erratum to this article is available at . 相似文献
Geomorphic, stratigraphic, and faunal observations of submarine slide scars that occur along the flanks of Monterey Canyon in 2.0–2.5 km water depths were made to identify the processes that continue to alter the surface of a submarine landslide scar after the initial slope failure. Deep-sea chemosynthetic biological communities and small caves are common on the sediment-free surfaces of the slide scars, especially along the headwall. The chemosynthetic organisms observed on slide scars in Monterey Canyon undergo a faunal succession based in part on their ability to maintain their access to the redox boundaries in the sediment on which they depend on as an energy source. By burrowing into the seafloor, these organisms are able to follow the retreating redox boundaries as geochemical re-equilibration occurs on the sole of the slide. As these organisms dig into the seafloor on the footwall, they often generate small caves and weaken the remaining seafloor. While chemosynthetic biological communities are typically used as indicators of fluid flow, these communities may be supported by methane and hydrogen sulfide that are diffusing out of the fresh seafloor exposed at the sole of the slide by the slope failure event. If so, these chemosynthetic biological communities may simply mark sites of recent seafloor exhumation, and are not reliable fluid seepage indicators. 相似文献