Coulometric total carbon dioxide analysis for marine studies: maximizing the performance of an automated gas extraction system and coulometric detector

A global survey of the distribution of dissolved CO₂ taking advantage of sampling opportunities provided by the World Ocean Circulation Experiment: World Hydrographic Program (WOCE-WHP) is being carried out through 1995. Goals include the measurement of oceanic inorganic carbon transport and the development of a data base from which future fossil-fuel CO₂ build-up can be monitored. The analytical method selected for total carbon dioxide (C_T) is gas extraction of acidified seawater with coulometric titration of the acid formed by the resultant carbon dioxide and monoethanolamine. To combine high accuracy and precision (± 1.5 μmol/kg for C_T ≥ 2000 μmol/kg) with a high rate of analysis, we have modified an automated single-parameter system. Following prototype development between 1987 and 1990, an instrument emerged with the acronym Somma standing for single-operator multiparameter metabolic analyzer. Improved functional and operating procedures have integrated electronic calibration, CO₂ gas calibration, and sample analysis with automated pressure, temperature, and conductivity (salinity) sensing into a single convenient transportable package.     

Carbon Isotope Geochemistry of the Orinoco Basin

Stable carbon isotope ratios have been used to study the sources of particulate organic carbon (POC) and total dissolved inorganic carbon in the Orinoco Basin. The isotopic composition of total dissolved inorganic carbon shows a range of from -8·1 to -23·0 ppt, an indication of dominance of biological processes. The isotopic composition of POC exhibits a range of from -24·1 to -34·6 ppt with little seasonal variation. The isotopic evidence indicates that the POC is predominantly of terrestrial origin rather than a result of in situ planktonic production. The similarity of isotopic composition of POC and coastal sediments suggests that riverine organic detritus has been transported 30-50 km offshore in a direction parallel to the Orinoco river channel.     

The Amphipod Community as a Bioindicator in Algeciras Bay (Southern Iberian Peninsula) Based on a Spatio-Temporal Distribution

Abstract. The amphipod population associated with Bugula neritina (L.), a verycommon bryozoan species in Algeciras Bay (Strait of Gibraltar), was studied on a spatio-temporal scale, in order to define its role as a bioindicator. Samples were collected in December, March, June and September along a transect running from the external to the internal sampling stations.
Fifty-three species belonging to 22 families were identified; the most abundant species were Jassa marmorata H olmes , Ischyrocerus inexpectatus (R uffo ) and Phtisica marina S labber .
The spatial evolution of the amphipod community reflected the physico-chemical conditions of Algeciras Bay, yielding a clear gradient from the outer to the inner stations. The stations located at the mouth of the bay, characterised by high hydrodynamism and low sedimentation, had a higher diversity and species richness than the inner stations with low water movement and higher sedimentation. Eight species preferred for the outer stations, while another nine species were typical of the inner harbours.
The most notable aspect of the seasonal evolution was the increased dominance of the tube-builder and deposit-suspension feeder Jassa marmorota .
Structural and ordination analyses corroborate the outer-inner gradient in the bay and illustrate the importance of hydrodynamic forces and sedimentation in the amphipod community.     

Coupled dynamics of tethered buoy systems

The three-dimensional coupled behavior during the interaction of buoys with their mooring systems is numerically analyzed. A time-domain model was developed to predict the response of a tethered buoy subject to hydrodynamic loadings. External loadings include hydrodynamic forces, tethers tensions, wind loadings and weight. System nonlinearities include large rotational and translational motions, and non-conservative fluid loadings. The mooring problem is formulated as a combined nonlinear initial-value and two-point-boundary-value problem which is directly integrated both in time and space. Buoy equations of motion are derived using small Eulerian angles. Coupling between rotational and translational degrees of freedom is included and coupling between the buoy and cable is effected by adopting the buoy equations of motion as boundary conditions at one end for the mooring problem. Numerical examples are provided to validate the formulation and solution technique; predicted responses of three types of buoy (sphere, spar, and disc) are compared with experimental results.     

A unified, polynomial approach for the approximate solution of thermoelastic problems in rectangular plates

The present paper, of a tutorial nature, solves two different thermoelastic problems using a unified approach: (a) thermoelastic stresses and deflections in thin, rectangular plates with edges elastically restrained against rotation when small-deflection theory is used and stress resultants in the middle plane of the plates are neglected; and (b) thermoelastic plane stress situations in rectangular plates with stress-free edges subjected to a two-dimensional temperature distribution.The first problem is attacked using polynomial coordinate functions which identically satisfy the governing boundary conditions, and the Ritz method is used to determine the plate response. When the flexibility coefficients approach zero (clamped edge conditions) the calculated results practically coincide with the exact solution for the test case treated in this paper. On the other hand this degenerate solution turns out to be a very convenient approximation for obtaining a solution to Airy's problem described in the second place and which is also solved in a straightforward manner using a variational approach.     

Beginning integrated coastal management efforts in Madagascar

Integrated coastal management (ICM) is an emerging approach in East Africa for the solution of various coastal issues. This paper is intended to provide an update on the current practical aspects concerning the ICM process and related policies and strategies in Madagascar. Efforts are being made in Madagascar for the mutual integration of numerous coastal projects and activities within the Environment Program of the National Environmental Action Plan. The foundations for an ICM program, built during an ICM workshop, which took place at the end of 1996 upon existing activities, are being expanded presently. These developments concern, above all, the institutional aspects related to the formulation of an ICM program. Therefore, the actual situation sees an overgrowing collaboration of the national and international agencies involved in the implementation of coastal projects, in an expandingly integrating way, within an institutional framework that grows progressively stronger. The case of Madagascar suggests reflections on how ICM can mitigate potential sectoral conflicts as well as on, how the sometimes complex nature of the social and cultural issues may influence the development of an ICM program. The need for monitoring ICM is stressed and the role of outside partners clarified.     

The morphodynamic modelling of tidal sand waves on the shoreface

An artificial sand wave on the Dutch shoreface of the North Sea has been studied in conditions with relatively strong tidal currents in the range of 0.5 to 1 m/s and sediments in the medium sand size range of 0.2 to 0.5 mm. The sand wave is perpendicular to the tidal current and has a maximum height and length of the order of 5 m and 1 km, respectively. The sand wave is dynamically active and shows migration rates of the order of a few metres per year. A numerical morphodynamic model (DELFT3D model) has been used to simulate the morphological behaviour of the sand wave in the North Sea. This model approach is based on the numerical solution of the three-dimensional shallow water equations in combination with a surface wave propagation model (wind waves) and the advection–diffusion equation for the sediment particles with online bed updating after each time step. The model results show that the sand wave grows in the case of dominant bed-load transport (weak tidal currents; relatively coarse sediment; small roughness height; low waves) and that the sand wave decays in the case of dominant suspended transport (strong currents, relatively fine sediment, large roughness height; storm waves).     

Data assimilation for a coastal area morphodynamic model: Morecambe Bay

This paper investigates the use of data assimilation in coastal area morphodynamic modelling using Morecambe Bay as a study site. A simple model of the bay has been enhanced with a data assimilation scheme to better predict large-scale changes in bathymetry observed in the bay over a 3-year period. The 2DH decoupled morphodynamic model developed for the work is described, as is the optimal interpolation scheme used to assimilate waterline observations into the model run. Each waterline was acquired from a SAR satellite image and is essentially a contour of the bathymetry at some level within the inter-tidal zone of the bay. For model parameters calibrated against validation observations, model performance is good, even without data assimilation. However the use of data assimilation successfully compensates for a particular failing of the model, and helps to keep the model bathymetry on track. It also improves the ability of the model to predict future bathymetry. Although the benefits of data assimilation are demonstrated using waterline observations, any observations of morphology could potentially be used. These results suggest that data assimilation should be considered for use in future coastal area morphodynamic models.     

Computational study of sail performance in upwind condition

Airflow around yacht sails with imposed final geometry is simulated using a CFD code, reproducing experimental tests carried in a wind tunnel. Two configurations are considered: one, mast–main sail and the other, mast–jib–main sail. Both configurations were studied in the same flow conditions of air velocity and incidence angle. The grid is structured-like next to the sails and unstructured in the rest of the domain. The turbulence model used is Shear Stress Transport. The results are compared against experimental and numerical results.     

Numerical modeling of nonlinear water waves over heterogeneous porous beds

The transformation of nonlinear water waves over porous beds is studied by applying a numerical model based on Chen's [2006. Fully nonlinear Boussinesq-type equations for waves and currents over porous beds. Journal of Engineering Mechanics, 132:2, 220–230] Boussinesq-type equations for highly nonlinear waves on permeable beds. The numerical model uses a high-order time-marching solution and fourth-order finite-difference schemes for discretization of first-order spatial derivatives to obtain a computational accuracy consistent with the model equations. By forcing the wave celerity and spatial porous-damping rate of the linearized model to match the exact linear theory for horizontal porous bed over a prescribed range of relative depths, the values of the model parameters are optimally determined. Numerical simulations of the damped wave propagation over finite-thickness porous layer demonstrate the accuracy of both the numerical model and governing equations, which have been shown by prior theoretical analyses to be accurate for both nominal and thick porous layers. These simulations also elucidate on the significance of the higher-order porous-damping terms and the influence of the hydraulic parameters. Application of the model to the simulation of the wave field around a laboratory-scale submerged porous mound provides a measure of its capability, as well as useful insight into the scaling of the porous-resistance coefficients. For application to heterogeneous porous beds, the assumption of weak spatial variation of the porous resistance is examined using truncated forms of the governing equations. The results indicate that the complete set of Boussinesq-type equations is applicable to porous beds of nonhomogeneous makeup.