Instrument development to search for biomarkers on mars: Terrestrial acidophile, iron-powered chemolithoautotrophic communities as model systems

Recent findings by the MER rover opportunity confirming the presence of iron minerals that can only be formed in the presence of water emphasize the study of analogous environments to Mars on Earth. The study of chemolithoautotrophic communities living in acidic iron-rich habitats is highly relevant in order to identify Mars analog environment-specific biomarkers. Iron oxidizing bacteria like Leptospirillum ferrooxidans and Acidithiobacillus ferrooxidans have ways of life for which it is feasible to identify a past or present hypothetical niche on Mars. We have developed a strategy for biomarker identification based on: (i) search for biosignatures on acid and metal-rich environments; (ii) development of an immunosensor microarray; and (iii) integration into an instrument for autonomous and remote operation. The instrument that we have built, called Signs Of LIfe Detector (SOLID), is capable of processing a variety of samples for the detection of specific biomarkers. Antibodies against several bacterial strains have been developed and tested in a microarray biosensor on SOLID. Tests with field samples have been successfully performed, allowing the detection of L. ferrooxidans, A. ferrooxidans present in sediment samples.     

Geochemistry of metabauxites in the Bergsträsser Odenwald (Mid German Crystalline Rise) and palaeoenvironmental implications

Summary Pre- to early Variscan metamorphosed volcano-sedimentary series of the western (Bergstr?sser) Odenwald have been intruded by Variscan calc-alkaline magmatites with plate margin affinities. Within the NE-SW trending metabasic and metapelitic series, intercalations of anomalously aluminous- and iron-rich compositions representing former bauxites are distinguishable. Geochemical data indicate that the Al-, Fe-rich rocks are the metamorphic equivalents of a former bauxitic-ferralitic weathering profile, now comprising spinel fels (top) with relics of pisolitic structures, corundum-chlorite fels, corundum-cordierite-plagioclase gneiss, sillimanite-cordierite-plagioclase gneiss, cordierite-plagioclase gneiss and kinzigite (base) displaying a decrease of weathering in the order as listed. The evolution of such terrestrial sediments is related to specific climatic, environmental, and physico-chemical conditions similar to those of the present-day tropical to subtropical humid regions with high seasonal rains and intensive drainage. Comparison with palaeomagnetic and palaeoclimatic data indicate that the Odenwald metabauxites originally formed during the Lower to Mid-Devonian. Our results imply that, during this geological time span, parts of the precursors of the Mid-German Crystalline Rise not only transversed low latitudes but also were exposed to terrestrial weathering.

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Zusammenfassung Die Geochemie der Metabauxite im Bergstr?sser Odenwald (Mitteldeutsche Kristallinschwelle) und ihre Bedeutung für das Pal?omilieu Im westlichen (Bergstr?sser) Odenwald intrudierten variszische Plattenrand-Kalkalkali-Magmatite in pr?- bis früh-variszische, ehemalige vulkano-sediment?re Serien. Innerhalb der heute NE-SW streichenden Metabasit- und Metapelitzüge treten lokal Al-Fe-reiche Einschaltungen auf, die strukturell und geochemisch als metamorphe ?quivalente eines ehemaligen bauxitisch-ferralitischen Verwitterungsprofils klassifiziert werden k?nnen. Sie umfassen Spinellfelse mit erhaltenen, ehemaligen zonierten Pisolithen, Korund-Chloritfelse, Korund-Cordierit-Plagioklasgneise, Sillimanit-Cordierit-Plagioklasgneise, Cordierit-Plagioklasgneise und Kinzigite. Bauxite k?nnen als terrestrische Bildungen nur unter speziellen klimatischen und physiko-chemischen Bedingungen entstehen. Pal?omagnetische und pal?oklimatische Daten legen die Bildung der ehemaligen Bauxite im unteren bis mittleren Devon nahe. Daraus folgt, da? w?hrend dieser geologischen Zeitspanne die Vorl?ufer der mitteldeutschen Kristallinschwelle bei der Norddrift nicht nur ?quatorn?he passierten, sondern auch partiell ungest?rte, terrestrische, tropisch-subtropische Verwitterungsprozesse abliefen.

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Received June 10, 1999; revised version accepted October 30, 2000     

Prospects for astrometry with the Hubble Space Telescope

The Hubble Space Telescope (HST), a large optical telescope having an aperture of 2.4 meters and a length of 8.8 meters, is being developed by the National Aeronautics and Space Administration. This telescope will be placed into earth orbit by the space shuttle. Astrometric observations with the HST are made using a Fine Guidance Sensor which is capable of measuring the position of one object relative to another with an accuracy of ±0.002 arcseconds. The astrometric user of HST will be provided with an Astrometric Data Reduction Software package (ADRS). The variety of astrometric problems to be investigated with HST is discussed.     

Modes to replace transitional asymptotic ray fields in a vertically inhomogeneous earth model

Summary. Asymptotic ray theory (ART) fails in transition regions near critically reflected, bottom glancing or caustic-forming rays in a vertically inhomogeneous layered earth. These deficiencies are repaired here by replacing the transitional ray fields with guided modes plus truncation remainders. Exact ray-mode equivalences and their high-frequency asymptotic approximations are formulated, and their validity and efficiency are verified by numerical comparisons for SH motion in a two-layer earth model comprised of an inhomogeneous sediment above an homogeneous semi-infinite bedrock.     

The dust coma of periodic comet Churyumov-Gerasimenko (1982 VIII)

The dust coma of Comet P/Churyumov-Gerasimenko was monitored in the infrared (1–20 μm) from September 1982 to March 1983. Maximum dust production rate of ～2 × 10⁵ g/sec occured in December, 1 month postperihelion. The ratio of dust/gas production was higher than that in other short-period comets. No silicate feature was visible in the 8- to 13-μm spectrum on 23 October. The mean geometric albedo of the grains was ～0.04 at 1.25 μm and ～0.05 at 2.2 μm.     

The geochemistry of lead in rivers,estuaries and the continental shelf of the Southeastern United States

Transport by southeastern rivers has insignificant influence on the lead concentration of southeastern shelf waters. If the rate of mobilization and transport of lead by these rivers is representative of uncontaminated fluvial transport during the Pleistocene, only about 5% of the prehistoric output of lead to the North Atlantic can be accounted for by river input.Lead concentrations in southeastern shelf waters are similar to those of North Atlantic Water from the upper 1000 m, which is probably similar to the intrusion source water for the shelf. Atmospheric inputs to the shelf of the same magnitude as observed for the Western North Atlantic are difficult to reconcile given the residence time of shelf waters and their lead concentration unless the rate of loss of lead to shelf sediments is about the same as the atmospheric flux.     

Pressure-induced incipient amorphization of α-quartz and transition to coesite in an eclogite from Antarctica: a first record and some consequences

Monocrystalline quartz inclusions in garnet and omphacite from various eclogite samples from the Lanterman Range (Northern Victoria Land, Antarctica) have been investigated by cathodoluminescence (CL), Raman spectroscopy and imaging, and in situ X‐ray (XR) microdiffraction using the synchrotron. A few inclusions, with a clear‐to‐opalescent lustre, show ‘anomalous’ Raman spectra characterized by weak α‐quartz modes, the broadening of the main α‐quartz peak at 465 cm^?1, and additional vibrations at 480–485, 520–523 and 608 cm^?1. CL and Raman imaging indicate that this ‘anomalous’α‐quartz occurs as relicts within ordinary α‐quartz, and that it was preserved in the internal parts of small quartz inclusions. XR diffraction circular patterns display irregular and broad α‐quartz spots, some of which show an anomalous d‐spacing tightening of ～2%. They also show some very weak, hazy clouds that have d‐spacing compatible with coesite but not with α‐quartz. Raman spectrometry and XR microdiffraction characterize the anomalies with respect to α‐quartz as (i) a pressure‐induced disordering and incipient amorphization, mainly revealed by the 480–485 and 608‐cm^?1 Raman bands, together with (ii) a lattice densification, evidenced by d‐spacing tightening; (iii) the cryptic development of coesite, 520–523 cm^?1 being the main Raman peak of coesite and (iv) Brazil micro‐twinning. This ‘anomalous’α‐quartz represents the first example of pressure‐induced incipient amorphization of a metastable phase in a crustal rock. This issue is really surprising because pressure‐induced amorphization of metastable α‐quartz, observed in impactites and known to occur between 15 and 32 GPa during ultrahigh‐pressure (UHP) experiments at room temperature, is in principle irrelevant under normal geological P–T conditions. A shock (due to a seism?) or a local overpressure at the inclusion scale (due to expansion mismatch between quartz and its host mineral) seem the only geological mechanisms that can produce such incipient amorphization in crustal rocks. This discovery throws new light on the modality of the quartz‐coesite transition and on the pressure regimes (non‐lithostatic v. lithostatic) during high‐pressure/UHP metamorphism. In particular, incipient amorphization of quartz could favour the quartz‐coesite transition, or allow the growth of metastable coesite, as already experimentally observed.