Tuning a physically-based model of the air–sea gas transfer velocity

Air–sea gas transfer velocities are estimated for one year using a 1-D upper-ocean model (GOTM) and a modified version of the NOAA–COARE transfer velocity parameterization. Tuning parameters are evaluated with the aim of bringing the physically based NOAA–COARE parameterization in line with current estimates, based on simple wind-speed dependent models derived from bomb-radiocarbon inventories and deliberate tracer release experiments. We suggest that A = 1.3 and B = 1.0, for the sub-layer scaling parameter and the bubble mediated exchange, respectively, are consistent with the global average CO₂ transfer velocity k. Using these parameters and a simple 2nd order polynomial approximation, with respect to wind speed, we estimate a global annual average k for CO₂ of 16.4 ± 5.6 cm h^?1 when using global mean winds of 6.89 m s^?1 from the NCEP/NCAR Reanalysis 1 1954–2000. The tuned model can be used to predict the transfer velocity of any gas, with appropriate treatment of the dependence on molecular properties including the strong solubility dependence of bubble-mediated transfer. For example, an initial estimate of the global average transfer velocity of DMS (a relatively soluble gas) is only 11.9 cm h^?1 whilst for less soluble methane the estimate is 18.0 cm h^?1.     

Spatial variation in river runoff into a coastal area — An ecological approach

Carbon and nitrogen stable isotopes were used to investigate spatial variation in terrestrial particulate organic matter (POM) input to a coastal area off the Tagus river estuary. Isotopic variation in higher trophic level organisms was also examined, along the coast. This study was carried out in late summer, after a period of 3 months of low river flow. The overall aim was to determine if under such conditions the coastal area is enriched by the river plume and, particularly, if lower secondary productivity should be expected in some areas. Spatial variation was detected as a gradient of decreasing terrestrial input with increasing distance from the river. It was concluded that terrestrial carbon input was also incorporated into higher trophic levels and that organisms with lower mobility are more sensitive to the gradient in terrestrial input. Even in low flow conditions the whole fishing area remained under the influence of the river plume, which still accounted for 24% of the total POM 30 km from the river mouth. Additionally, δ¹⁵N values indicated pollution input from the river Tagus.     

Depositional architecture and sequence stratigraphy of the Karoo basin floor to shelf edge succession, Laingsburg depocentre, South Africa

The Laingsburg depocentre of the SW Karoo Basin, South Africa preserves a well-exposed 1200 m thick succession of upper Permian strata that record the early filling of a basin during an icehouse climate. Uniformly fine-grained sandstones were derived from far-field granitic sources, possibly in Patagonia, although the coeval staging and delivery systems are not preserved. Early condensed shallow marine deposits are overlain by distal basin plain siltstone-prone turbidites and volcanic ashes. An order of magnitude increase in siliciclastic input to the basin plain is represented by up to 270 m of siltstone with thin sandstone turbidites (Vischkuil Formation). The upper Vischkuil Formation comprises three depositional sequences, each bounded by a regionally developed zone of soft sediment deformation and associated 20-45 m thick debrite that represent the initiation of a major sand delivery system. The overlying 300 m thick sandy basin-floor fan system (Unit A) is divisible into three composite sequences arranged in a progradational-aggradational-retrogradational stacking pattern, followed by up to 40 m of basin-wide hemipelagic claystone. This claystone contains Interfan A/B, a distributive lobe system that lies 10 m beneath Unit B, a sandstone-dominated succession that averages 150 m thickness and is interpreted to represent a toe of slope channelized lobe system. Unit B and the A/B interfan together comprise 4 depositional sequences in a composite sequence with an overall basinward-stepping stacking pattern, overlain by 30 m of hemipelagic claystone. The overlying 400 m thick submarine slope succession (Fort Brown Formation) is characterized by 10-120 m thick sand-prone to heterolithic packages separated by 30-70 m thick claystone units. On the largest scale the slope stratigraphy is defined by two major cycles interpreted as composite sequence sets. The lower cycle comprises lithostratigraphic Units B/C, C and D while the upper cycle includes lithostratigraphic Units D/E, E and F. In each case a sandy basal composite sequence is represented by an intraslope lobe (Units B/C and D/E respectively). The second composite sequence in each cycle (Units C and E respectively) is characterized by slope channel-levee systems with distributive lobes 20-30 km down dip. The uppermost composite sequence in each cycle (Units D and F respectively) are characterised by deeply entrenched slope valley systems. Most composite sequences comprise three sequences separated by thin (<5 m thick) claystones. Architectural style is similar at individual sequence scale for comparable positions within each composite sequence set and each composite sequence. The main control on stratigraphic development is interpreted as late icehouse glacio-eustasy but along-strike changes associated with changing shelf edge delivery systems and variable bathymetry due to differential substrate compaction complicate the resultant stratigraphy.     

Relative dispersion in the Liguro-Provençal basin: From sub-mesoscale to mesoscale

Relative dispersion in the Liguro-Provençal basin (a subregion of the Mediterranean Sea) is investigated using clusters of surface drifters deployed during two Marine Rapid Environment Assessment (MREA) experiments covering different months in 2007 and 2008, respectively. The clusters have initial radii of less than 1 km, or an order of magnitude below a typical deformation radius (approximately 10-20 km). The data set consists of 45 original pairs and more than 50 total pairs (including chance ones) in the spatial range between 1 and 200 km. Relative dispersion is estimated using the mean square separation of particle pairs and the Finite Scale Lyapunov Exponents (FSLEs). The two metrics show broadly consistent results, indicating in particular a clear exponential behaviour with an e-folding time scale between 0.5 and 1 days, or Lyapunov exponent ?? in the range of 0.7-1 days⁻¹. The exponential phase extends for 4-7 days in time and between 1 and 10-20 km in separation space. To our knowledge, this is only the third time that an exponential regime is observed in the world ocean from drifter data. This result suggests that relative dispersion in the Liguro-Provençal basin is nonlocal, namely controlled mainly by mesoscale dynamics, and that the effects of the sub-mesoscale motions are negligible in comparison. NCOM model results are used to complement the data and to quantify errors arising from the sparse sampling in the observations.     

Inter-basin movements of Mediterranean sperm whales provide insight into their population structure and conservation

The sperm whale is one of the very few deep diving mammal species in the Mediterranean Sea. Following a rare mass stranding of male sperm whales in the Adriatic Sea in December 2009, photo-identification methods were used in order to investigate previous sightings of the stranded whales in the region. Fluke photos of the stranded whales were compared with those of 153 and 128 free-ranging individuals photographed in the western and eastern Mediterranean basins, respectively. Three out of the seven stranded whales had been previously photo-identified and some of them more than once. To reach the stranding place, two of these re-identified whales performed long-range inter-basin movements of about 1600-2100 km (in a straight line) either through the Strait of Sicily or the Strait of Messina. In addition, comparisons among all whales photographed in the two Mediterranean basins revealed that one more individual first photographed in the western basin (1991) was re-identified 13 years later in the eastern basin (2004). These three cases provide the first conclusive evidence of inter-basin movement of sperm whales in the Mediterranean Sea. Inter-basin gene flow is important for the survival of the small and endangered Mediterranean sperm whale population. Mitigating the disturbance created by human activities in the straits area is crucial for its conservation.     

Patterns and controls of surface sediment distribution: west-central Florida inner shelf

The west-central Florida inner shelf represents a transition between the quartz-dominated barrier-island system and the carbonate-dominated mid-outer shelf. Surface sediments exhibit a complex distribution pattern that can be attributed to multiple sediment sources and the ineffectiveness of physical processes for large-scale sediment redistribution. The west Florida shelf is the submerged extension of the Florida carbonate platform, consisting of a limestone karst surface veneered with a thin unconsolidated sediment cover. A total of 498 surface sediment samples were collected on the inner shelf and analyzed for texture and composition. Results show that sediment consists of a combination of fine quartz sand and coarse, biogenic carbonate sand and gravel, with variable but subordinate amounts of black, phosphorite-rich sand. The carbonate component consists primarily of molluskan fragments. The distribution is patchy and discontinuous with no discernible pattern, and the transition between sediment types is generally abrupt. Quartz-rich sediment dominates the inner 15 km north of the entrance into Tampa Bay, but south of the Bay is common only along the inner 3 km. Elsewhere, carbonate-rich sediment is the predominate sediment type, except where there is little sediment cover, in which cases black, phosphorite-rich sand dominates. Sediment sources are likely within, or around the periphery of the basin. Fine quartz sand is likely reworked from coastal units deposited during Pleistocene sea-level high stands. Carbonate sand and gravel is produced by marine organisms within the depositional basin. The black, phosphorite-rich sand likely originates from the bioerosion and reworking of the underlying strata that irregularly crop out within the study area. The distribution pattern contains elements of both storm- and tide-dominated siliciclastic shelves, but it is dictated primarily by the sediment source, similar to some carbonate systems. Other systems with similar sediment attributes include cool-water carbonate, sediment-starved, and mixed carbonate/siliciclastic systems. This study suggests a possible genetic link among the three systems.     

A densely sampled core and climate variable aliasing

Undersampled records are susceptible to aliasing, in which a high frequency appears incorrectly as a lower one. We study the sampling requirements in a core taken from Rockall Trough using bulk density, P-wave velocity, and magnetic susceptibility as measured on an automated system. At 2-cm spacing (approximately 33 years in this core), all variables show a characteristic red-noise behavior, but with a spectral slope that is sufficiently weak so that significant aliasing appears to be present. P-wave velocity shows the largest potential corruption, probably owing to the weaker spatial averaging present in the sensor. Approximately 50% of the apparent low-frequency energy is aliased in all variables at some frequencies in both quiet and active regions of the record. In this core, a sampling interval of 0.2 cm appears to be "safe" in both active and quiet portions of the core, aliasing little or no energy, except in the P-wave record. For cores of different duration, sampling interval, and measurement type, the considerations will be identical, the importance of the problem depending directly upon the shape of the overall spectrum describing the entire frequency (wavenumber) range of physical variability.     

How U.S. ocean policy and market power can reform the coral reef wildlife trade

As the world’s largest importer of marine ornamental species for the aquaria, curio, home décor, and jewelry industries, the United States has an opportunity to leverage its considerable market power to promote more sustainable trade and reduce the effects of ornamental trade stress on coral reefs worldwide. Evidence indicates that collection of some coral reef animals for these trades has caused virtual elimination of local populations, major changes in age structure, and promotion of collection practices that destroy reef habitats. Management and enforcement of collection activities in major source countries such as Indonesia and the Philippines remain weak. Strengthening US trade laws and enforcement capabilities combined with increasing consumer and industry demand for responsible conservation can create strong incentives for improving management in source countries. This is particularly important in light of the March 2010 failure of the parties to the Convention on International Trade in Endangered Species (CITES) to take action on key groups of corals.     

Detection of deep water benthic macroalgae using image-based classification techniques on multibeam backscatter at Cashes Ledge,Gulf of Maine,USA

Benthic macroalgae form an important part of temperate marine ecosystems, exhibiting a complex three-dimensional character which represents a vital foraging and spawning ground for many juvenile fish species. In this research, image-based techniques for classification of multibeam backscatter are explored for the detection of benthic macroalgae at Cashes Ledge in the Gulf of Maine, USA. Two classifications were performed using QTC-Multiview, differentiated by application of a threshold filter, and macroalgal signatures were independently extracted from the raw sonar datagrams in Matlab. All classifications were validated by comparison with video ground-truth data. The unfiltered classification shows a high degree of complexity in the shallowest areas within the study site; the filtered demonstrates markedly less variation by depth. The unfiltered classification shows a positive agreement with the video ground-truth data; 82.6% of observations recording Laminaria sp., 39.1% of Agarum cribrosum and 100.0% (n = 3) of mixed macroalgae occur within the same acoustically distinct group of classes. These are discrete from the 8.1% recorded agreement with absences and nulls (>40 m) of macrophytes (n = 32) from a total of 86 ground-truth locations. The results of the water column data extraction (WCDE) show similar success, accurately predicting 78.3% of Laminaria sp. and 30.4% of A. cribrosum observations.