Voltammetric estimation of iron(III) thermodynamic stability constants for catecholate siderophores isolated from marine bacteria and cyanobacteria

Thermodynamic stability constants have been estimated for the complexation of iron(III) with catecholate-type siderophores isolated from the marine bacterium Alteromonas luteoviolacea and from the marine cyanobacterium Synechococcus sp. PCC 7002. Stability constants were determined utilizing the “chelate scale” of Taylor et al. (1994). The scale is based upon a linear relationship between the reduction potentials and the pH-independent thermodynamic stability constants for known iron(III) complexes. Log K values for the alterobactin B ferric iron complex are 43.6 ± 1.5 at pH 8.2 and 37.6 ± 1.2 at pH 6, consistent with a shift from bis-catecholate to monosalicylate/monocatecholate iron coordination with decreasing pH. Synechococcus isolates PCC 7002 Nos. 1 and 3 formed iron(III) complexes with stability constants of approximately 38.1 ± 1.2 and 42.3 ± 1.5, respectively. The binding strengths of the iron(III) complexes examined in this study are quite high, suggesting that catecholate siderophores may play a role in the solubilization and biological uptake of iron in the marine environment.     

Vertical migration and mortality of benthos in dredged material: Part III—polychaeta

The survival of benthic invertebrates from dredging and disposal activities is a major environmental concern in such projects. The purpose of the research described in this paper was to determine the ability of benthos (polychaetes, Scoloplos fragilis and Nereis succinea) to migrate vertically in natural and exotic sediments and to determine the survival of benthos when exposed to particular amounts of simulated dredged material.Mortalities generally increased with increased sediment depth, exotic sediment and burial time. Temperature also affected vertical migration and mortalities. These experiments, together with other experiments conducted by us and other workers, indicate that polychaetes in particular, and benthos in general, can survive dredging and disposal projects. Under certain conditions several major taxa (polychaetes, molluscs, crustaceans) can be expected to successfully recolonise disposal sites by vertical migration.     

The parameterisation and prediction of wave height and wind speed persistence statistics for oil industry operational planning purposes

This study sets out to define the basic forms in which wind speed and wave height persistence statistics may be defined for offshore engineering applications, and describes the development of a mathematical persistence model.The model incorporates some of the principles laid down by other workers, but it is fundamentally based on a new concept for parameterising persistence statistics, linking wind speed and sea state percentage probability of exceedance with the persistence average duration.North Sea measured wind and wave data have been used to calibrate and test the model. During the course of these test runs it proved necessary to fine tune the basic Weibull equation of the model, but following these adjustments the model runs were found to correlate well with the measured data.It is concluded that the model may be used to predict wind speed and wave height persistence statistics with acceptable accuracy for preliminary stage oil industry planning purposes and that the calibrated model has particular application for those areas where little measured data are currently available.     

Differential model of the hydrophysical fields' vertical structure in a stratified tidal flow over a shelf

This paper studies the influence of shelf tidal flows on the structure of surface and near-bottom turbulent boundary layers.Translated by Vladimir A. Puchkin.     

Three-dimensional inversion of marine magnetic anomalies: Implications for crustal accretion along the Mid-Atlantic Ridge (28°–31°30′ N)

We present magnetic field data collected over the Mid-Atlantic Ridge in the vicinity of the Atlantis Fracture Zone and extending out to 10 Ma-old lithosphere. We calculated a magnetization distribution which accounts for the observed magnetic field by performing a three-dimensional inversion in the presence of bathymetry. Our results show the well-developed pattern of magnetic reversals over our study area. We observe a sharp decay in magnetization from the axis out to older lithosphere and we attribute this decay to progressive low temperature oxidation of basalt. In crust which is 10 Ma, we observe an abrupt increase in magnetic field intensity which could be due to an increase in the intensity of magnetization or thickness of the magnetic source layer. We demonstrate that because the reversal epoch was of unusually long duration, a two-layer model comprised of a shallow extrusive layer and a deeper intrusive layer with sloping polarity boundaries can account for the increase in the amplitude of anomaly 5. South of the Atlantis Fracture Zone, high magnetization is correlated with bathymethic troughts at segment end points and lower magnetization is associated with bathymetric highs at segment midpoints. This pattern can be explained by a relative thinning of the magnetic source layer toward the midpoint of the segment. Thickening of the source layer at segment endpoints due to alteration of lower oceanic crust could also cause this pattern. Because we do not observe this pattern north of the fracture zone, we suggest it is a result of the nature of crustal formation process where mantle upwelling is focused. South of the fracture zone, reversals along discontinuity traces only continue to crust 2 Ma old. In crust >2 Ma, we observe bands of high, positive magnetization along discontinuity traces. We suggest that within the discontinuity traces, a high, induced component of magnetization is produced by serpentinized lower crust/upper mantle and this masks the contribution of basalts to the magnetic anomaly signal.