全文获取类型
收费全文 | 70843篇 |
免费 | 1311篇 |
国内免费 | 863篇 |
专业分类
测绘学 | 1748篇 |
大气科学 | 5376篇 |
地球物理 | 14056篇 |
地质学 | 24314篇 |
海洋学 | 6554篇 |
天文学 | 16201篇 |
综合类 | 186篇 |
自然地理 | 4582篇 |
出版年
2021年 | 554篇 |
2020年 | 630篇 |
2019年 | 671篇 |
2018年 | 1446篇 |
2017年 | 1307篇 |
2016年 | 1799篇 |
2015年 | 1123篇 |
2014年 | 1691篇 |
2013年 | 3607篇 |
2012年 | 1952篇 |
2011年 | 2774篇 |
2010年 | 2410篇 |
2009年 | 3338篇 |
2008年 | 2869篇 |
2007年 | 2865篇 |
2006年 | 2654篇 |
2005年 | 2317篇 |
2004年 | 2215篇 |
2003年 | 2126篇 |
2002年 | 2056篇 |
2001年 | 1817篇 |
2000年 | 1732篇 |
1999年 | 1545篇 |
1998年 | 1463篇 |
1997年 | 1474篇 |
1996年 | 1274篇 |
1995年 | 1155篇 |
1994年 | 1063篇 |
1993年 | 980篇 |
1992年 | 938篇 |
1991年 | 900篇 |
1990年 | 898篇 |
1989年 | 841篇 |
1988年 | 813篇 |
1987年 | 911篇 |
1986年 | 849篇 |
1985年 | 1032篇 |
1984年 | 1157篇 |
1983年 | 1063篇 |
1982年 | 982篇 |
1981年 | 954篇 |
1980年 | 816篇 |
1979年 | 799篇 |
1978年 | 775篇 |
1977年 | 729篇 |
1976年 | 648篇 |
1975年 | 668篇 |
1974年 | 650篇 |
1973年 | 668篇 |
1972年 | 395篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
621.
The paper is devoted to the conditions under which opacite rims developed around hornblende grains in andesite of the catastrophic eruption (March 30, 1956) of Bezymyannyi volcano, Kamchatka. The opacite rims were produced by a bimetasomatic reaction between hornblende and melt with the development of the following zoning: hornblende → Px + Pl + Ti-Mag → Px + Pl → Px → melt. Biometasomatic reaction was accompanied by the active removal of CaO from the rim, addition of SiO2, and more complicated behavior of other components. The hornblende also shows reactions of its volumetric decomposition under near-isochemical conditions. The opacite rims developed under isobaric conditions, at a pressure of approximately 6 kbar. The main reason for the instability of the hornblende was the heating of the magma chamber from 890 to 1005°C due to new hot magma portion injection. The time interval between the injection and the start of eruption was estimated from the thickness of the opacite rims and did not exceed 37 days. Hence, the March 30, 1956, eruption was not related to the volcanic activity in November of 1955 but to the injection of a fresh magma portion in February–March of 1956. 相似文献
622.
623.
624.
625.
Jos M. Marques Paula M. Carreira Maria Rosrio Carvalho Maria J. Matias Fraser E. Goff Maria J. Basto Rui C. Graa Luís Aires-Barros Luís Rocha 《Applied Geochemistry》2008,23(12):3278-3289
This paper reviews the geochemical, isotopic (2H, 18O, 13C, 3H and 14C) and numerical modelling approaches to evaluate possible geological sources of the high pH (11.5)/Na–Cl/Ca–OH mineral waters from the Cabeço de Vide region (Central-Portugal). Water–rock interaction studies have greatly contributed to a conceptual hydrogeological circulation model of the Cabeço de Vide mineral waters, which was corroborated by numerical modelling approaches. The local shallow groundwaters belong to the Mg–HCO3 type, and are derived by interaction with the local serpentinized rocks. At depth, these type waters evolve into the high pH/Na–Cl/Ca–OH mineral waters of Cabeço de Vide spas, issuing from the intrusive contact between mafic/ultramafic rocks and an older carbonate sequence. The Cabeço de Vide mineral waters are supersaturated with respect to serpentine indicating that they may cause serpentinization. Magnesium silicate phases (brucite and serpentine) seem to control Mg concentrations in Cabeço de Vide mineral waters. Similar δ2H and δ18O suggest a common meteoric origin and that the Mg–HCO3 type waters have evolved towards Cabeço de Vide mineral waters. The reaction path simulations show that the progressive evolution of the Ca–HCO3 to Mg–HCO3 waters can be attributed to the interaction of meteoric waters with serpentinites. The sequential dissolution at CO2 (g) closed system conditions leads to the precipitation of calcite, magnesite, amorphous silica, chrysotile and brucite, indicating that the waters would be responsible for the serpentinization of fresh ultramafic rocks (dunites) present at depth. The apparent age of Cabeço de Vide mineral waters was determined as 2790 ± 40 a BP, on the basis of 14C and 13C values, which is in agreement with the 3H concentrations being below the detection limit. 相似文献
626.
Elevated As concentrations in groundwater in the eastern United States have been recognized predominantly in the accretionary geologic terranes of northern New England. A retrospective examination of more than 18,000 existing groundwater samples from the Pennsylvania Department of Environmental Protection (PA DEP) Drinking Water and Sampling Information System database indicates that elevated groundwater As concentrations occur throughout the northern half of the Piedmont Province of Pennsylvania. Chemical analyses of 53 samples collected in 2005 from drinking water wells in this area all had detectable As, and 23% of these samples contained elevated (>133 nmol/L or >10 μg/L) concentrations of As. Elevated concentrations of As in the groundwater samples were most common in the Mesozoic sedimentary strata composed of sandstone and red mudstone with interbedded gray shale, and gray to black siltstone and shale. Arsenic was typically not elevated in groundwater of diabase intrusions of the Newark Basin or in crystalline and calcareous aquifers to the north of the Newark Basin. Geochemical parameters such as pH and oxidation–reduction potential can indicate mobility mechanisms of As in some regions. In this area, measured groundwater conditions were predominantly oxidizing (Eh > +50 mV), and more than 85% of samples contained arsenate as the dominant As species. Variations in pH were strongly correlated to the As concentration, with highest As concentrations observed at pH values greater than 6.4. The original source of As is most likely the black and gray shales that contain some arsenian pyrite with groundwater concentrations likely to be controlled by adsorption/desorption reactions with Fe oxides in the red mudstone aquifer materials. 相似文献
627.
628.
High levels of Cd and Zn in Jamaican soils observed in geochemical surveys are related to the presence of phosphorites of possible Late-Miocene or Pliocene age. The trace element and REE geochemistry of the phosphorites, together with SEM studies, indicate a guano origin for the phosphorites. No specific host minerals for Cd could be identified in the fossiliferous phosphorite which is characterized by uniquely high levels of Cd, Zn, Ag, Be, U and Y. However, in the soil Cd is present in lithiophorite and a complex history of pedological development is preserved in the aluminous–goethite present in the soil. The unique guano signature is preserved in the soil despite the fact that guanos themselves have either not been observed or have been destroyed by continuing karst and soil development. The phosphorite geochemical signature can be traced in the data of a 1988 island-wide soil geochemical survey, identifying areas where the Palaeo-environment that supported bird ‘rookeries’ existed in the Late-Miocene or Pliocene. 相似文献
629.
F. Parello A. Aiuppa H. Calderon F. Calvi D. Cellura V. Martinez M. Militello K. Vammen D. Vinti 《Applied Geochemistry》2008
This paper reports new geochemical data on dissolved major and minor constituents in surface waters and ground waters collected in the Managua region (Nicaragua), and provides a preliminary characterization of the hydrogeochemical processes governing the natural water evolution in this area. The peculiar geological features of the study site, an active tectonic region (Nicaragua Depression) characterized by active volcanism and thermalism, combined with significant anthropogenic pressure, contribute to a complex evolution of water chemistry, which results from the simultaneous action of several geochemical processes such as evaporation, rock leaching, mixing with saline brines of natural or anthropogenic origin. The effect of active thermalism on both surface waters (e.g., saline volcanic lakes) and groundwaters, as a result of mixing with variable proportions of hyper-saline geothermal Na–Cl brines (e.g., Momotombo geothermal plant), accounts for the high salinities and high concentrations of many environmentally-relevant trace elements (As, B, Fe and Mn) in the waters. At the same time the active extensional tectonics of the Managua area favour the interaction with acidic, reduced thermal fluids, followed by extensive leaching of the host rock and the groundwater release of toxic metals (e.g., Ni, Cu). The significant pollution in the area, deriving principally from urban and industrial waste-water, probably also contributes to the aquatic cycling of many trace elements, which attain concentrations above the WHO recommended limits for the elements Ni (∼40 μg/l) and Cu (∼10 μg/l) limiting the potential utilisation of Lake Xolotlan for nearby Managua. 相似文献
630.