The dissociation constants of carbonic acid in seawater at salinities 5 to 45 and temperatures 0 to 45°C

The pK₁^* and pK₂^* for the dissociation of carbonic acid in seawater have been determined from 0 to 45°C and S = 5 to 45. The values of pK₁^* have been determined from emf measurements for the cell:

Pt](1 − X)H2 + XCO2|NaHCO3, CO2 in synthetic seawater|AgC1; Ag

where X is the mole fraction of CO₂ in the gas. The values of pK₂^* have been determined from emf measurements on the cell:

Pt, H2(g, 1 atm)|Na2CO3, NaHCO3 in synthethic seawater|AgC1; Ag

The results have been fitted to the equations:

lnK^*₁ = 2.83655 − 2307.1266/T − 1.5529413 lnT + (−0.20760841 − 4.0484/T)S^0.5 + 0.08468345S − 0.00654208S¹

InK^*₂ = −9.226508 − 3351.6106/T− 0.2005743 lnT + (−0.106901773 − 23.9722/T)S^0.5 + 0.1130822S − 0.00846934S^1.5

where T is the temperature in K, S is the salinity, and the standard deviations of the fits are σ = 0.0048 in lnK₁^* and σ = 0.0070 in lnK₂^*.Our new results are in good agreement at S = 35 (±0.002 in pK₁^*and ±0.005 in pK₂^*) from 0 to 45°C with the earlier results of Goyet and Poisson (1989). Since our measurements are more precise than the earlier measurements due to the use of the Pt, H₂|AgCl, Ag electrode system, we feel that our equations should be used to calculate the components of the carbonate system in seawater.     

Greening international shipping through private governance: A case study of the Clean Shipping Project

This article aims to generate insights into both private governance and partnerships within the shipping industry, but also tries to improve understanding of the complex process of institutionalisation.This is achieved through a case study of the Clean Shipping Project, a public/private partnership that aims to promote sustainability in the shipping industry. A set of enabling and constraining factors are examined that shape the institutionalisation process and determine to what extent the Clean Shipping Project can establish and expand authority as an industry norm.Overall, the Clean Shipping Project cannot yet be considered a full-fledged private governance institution, because of an insufficient level of collaborative advantage mainly due to weak system robustness and unfavourable market characteristics and conditions. However, institutionalisation is an ongoing process and the future outlook for the Clean Shipping Project remains promising. The Clean Shipping Project is certainly a relevant supplement to existing regulations and there is a basic level of commitment and cohesion within the partnership, so it is not unlikely that in the future this initiative may help to uncouple growth in shipping activities from environmental harm.     

Computations of the almost highest short-crested waves in deep water

The highest short-crested waves have been studied analytically and numerically by several workers, but without a conclusive view. An efficient numerical scheme is proposed in this paper which retains the water-surface elevations in an implicit form in the governing equations, rather than using a series approximation, thus improving the accuracy of the numerical results. Convergence of the numerical scheme is verified. The almost highest short-crested waves in deep water are then evaluated, which are defined for the condition with the largest wave energies. It is found that the critical angle for wave frequency reversal also demarcates the wave characteristics near breaking, for either kinematic or dynamic prominence. The known results available for the limiting two-dimensional cases of standing and progressive waves are compared favourably.     

Concentrations of unsubstituted polynuclear aromatic hydrocarbons in bay mussels (Mytilus edulis) from Oregon, USA

Concentrations of fifteen unsubstituted polynuclear aromatic hydrocarbons (PNAH) were measured in Mytilus edulis from two sites in Yaquina Bay, Oregon, USA, during 1979–1980. There were significant differences in PNAH levels between the two populations. The average total concentration in mussels inhabiting the more industrialized bayfront was 986·2 μg/kg compared with 273·9 μg/kg in mussels from a more remote site across the bay. Substantial differences were found in the concentrations of different PNAH in M. edulis examined during this study. The smaller more water soluble, compounds were concentrated to one or two orders of magnitude above the larger, less soluble PNAH.     

Local buckling strength of ring stiffened cylindrical shells under external pressure

The paper presents a non-linear buckling analysis of ring stiffened cylindrical shells subject to external pressure. The collapse pressure is calculated by assuming failure to occur when the material reaches a plastic stress state defined by the Ilyushin criterion. It is shown in the paper that use of the non-linear theory can reduce the estimated first yield by up to 25% in comparison to the linear buckling analysis used up to now. Comparison of predicted failure loads are in good agreement with the lower bound of test results.     

The elemination of re-reflected waves by a porous medium of finite thickness

The elimination of re-reflected waves in a wave channel by installing a porous medium in front of the wavemaker is investigated. The thickness of the porous wall required to eliminate the re-reflected waves is shown to be related to th porosity, friction coefficient, and wave period, as well as to both the positions of the porous medium and the test structure. However, this study indicates that the goal of eliminating re-reflected waves can be achieved by simply varying the thickness of the porous medium according to the wave period, with all the other factors arbitrarily selected.Assuming that the oscillation amplitude of the wavemaker board is constant, the primitive wave amplitude, before reaching the porous medium, becomes smaller as the wave period is increased. In addition, the study found that the required thickness of the porous medium for eliminating the re-reflected wave becomes larger as the wave period is increased. This results in a trend which further reduces the wave amplitude after the wave passes through the porous medium. In consequence, the oscillation amplitude of a wavemaker board has to be adjusted in a larger scale if the wave period is to be increased.     

Sensitivity to stress of the estuarine bivalve Macoma balthica from areas between the Netherlands and its southern limits (Gironde)

Variation in the sensitivity to stress of Macoma balthica was measured in several French and Dutch estuaries. For adult and juvenile Macoma balthica exposed to copper under conditions of starvation, differences in mortality rate, condition, glycogen, burrowing rate and copper content were assessed. No significant differences were observed between adults and juveniles; the influence of treatment and origin was always evident. Animals from the most southern estuaries, Loire and Gironde, near to the species's southern limit of distribution, showed, in the field, the strongest deviations for the ecophysiological traits measured, and were in the experiments the most sensitive to stress.     

Late Quaternary Seismic Stratigraphy of the Eastern Bengal Shelf

An ultra-high-resolution seismic study of the eastern Bengal Shelf with the parametric narrow-beam echosounder Parasound allows the interpretation of late Quaternary depositional patterns in terms of seismic stratigraphy. Accommodation space was still present on the outer shelf during the last lowstand, where a prograding delta developed in the western survey area. Oolitic beach ridges were later formed on top of this lowstand delta. Farther east, large parts of the shelf were exposed to subaerial erosion and a river system extended seaward across the area. A subaqueous highstand delta prograded southwards following the maximum transgression about 7,000 years ago. Its foreset beds exhibit acoustic voids very likely generated by sediment liquefaction, possibly caused by episodic energetic events such as major cyclones and/or earthquakes. Bottomset sediments extend seaward close to the shelf break in the west, whereas no Holocene sediments cover the outer shelf in the east.     

Tectonic setting of the Azores Plateau deduced from a OBS survey

The studies of Azores seismicity generally show shocks with either normal faulting or right-lateral strike-slip along the ESE direction, compatible with a eastward relative motion of the Eurasian (EU) relative to the African (AF) plate. However, the 1 January 1980 earthquake was interpreted as a clear left-lateral strike-slip shock along the N150E direction. This pattern is difficult to explain in terms of the relative motion between the EU, AF and North American (NA) plates: all available models for the present day movement of this triple junction fail to explain the regional variability in the stress conditions of the area. Here we present data from a 34-day long Ocean Bottom Seismograph array deployment. We show that the seismicity is distributed along a band aligned with the island chain itself, and is concentrated along several faults with an approximate N150E strike, cutting the Azores plateau in all the area covered by the OBS network. The combination of these new results with other geophysical data permits us to conclude that the tectonic setting of the Azores plateau is characterised by the existence of two sets of faults, in the N120E and N150E directions, defining several crustal blocks, whose relative motion accommodates the interaction of the three megaplates. The deformation of these tectonic blocks is probably driven by the shear between the EU and AF plates. This model explains well the spatial variability of the stress conditions in the Azores domain, the combination of dextral and sinistral strike slip mechanisms and the observed seismotectonics of the Azores islands.