Effect of heat treatment on dynamic properties of selected rock types taken from the Salt Range in Pakistan

Temperature is one of the variables that influence the elasto-plastic behavior and integrity of rock outcrops. Fluctuations in temperature can trigger alteration of some of the mineral properties and impact the brittle-plastic transition. Initiation and propagation of thermally induced tension cracks tend to weaken most rock types. The principal goal of this study was to anticipate impacts of thermal stress-strain cycles on the dynamic response of representative rock units exposed in the Khewra Gorge of the Salt Range Punjab of Pakistan. Ten types of sedimentary rock units were sampled, including marl, dolomite, three types of limestone, and five different sandstones exhibiting varying characteristics in outcrop. Boulder specimens were collected from the field and transported to the laboratory to prepare 50 drill cores that could be subjected to thermal cycling between 50 and 200 °C in increments of 50 °C. Room temperature core samples were tested using an Erudite resonance frequency meter to measure their Q-factors and the resonance frequency (F_r) at an applied loading frequency of 7 KHz with 0.01 V output voltage. Results suggest that thermal cycling tends to reduce the dynamic Young’s modulus (E_d) and Q-factor. Other parameters, such as damping ratio (ξ), specific damping capacity (Ψ), and loss factor (?) appeared to increase with increasing temperature cycles, likely as a result of developing thermally induced tensile fractures. The resultant values of the null hypothesis (t-critical and t-stats) suggests that the null hypothesis can be discarded because there was no observable difference between the measured and expected values for the cores tested. The observations and data emanating from this study might be useful in designing low-level radioactive waste landfills, nuclear waste repositories, and deep underground excavations where the increased temperature could alter the mechanical behavior of the parent rock mass.     

Assessment of the reliability of supervised classifications of Landsat-7, ASTER,and SPOT-5 multispectral data in rock unit discriminations of Jabal Daf-Wadi Fatima area,Saudi Arabia

Multispectral, multiresolution remotely sensed data were processed to emphasize geological interpretation of Jabal Daf-Wadi Fatima area. The investigated area is situated in the central western part of Saudi Arabia and geologically consists of igneous and metamorphosed rocks overlain by sedimentary sequence belonging to the Arabian-Nubian Shield. Three sets of digital satellite data, Landsat-7 ETM+, ASTER, and SPOT-5, were used in this study. The application of image processing techniques enables to identify and delineate the lithologic units and the structural features of the study area. The results of this study indicate that the confusion matrix of the three maximum likelihood supervised classifications of the three datasets shows that the Landsat ETM+ bands scored the best degree of average and overall accuracy (77 and 78%, respectively). This classification distinguishes most of the rock units for mapping in the investigated area. The supervised classification of ASTER and SPOT bands has lower degrees of accuracy than the classified Landsat data. The supervised classification of SPOT bands has a degree of average and overall accuracy of 66 and 67%, respectively, but it is the best for distinguishing the spectral signatures of the different members of Fatima Formation (lower, middle, and upper members). The statistical analyses of the confusion matrices of classifications and the interpretation of the produced classified thematic maps revealed that the classification accuracy does not necessary depend on the spatial resolution of satellite data. The data of the highest spatial resolution such as SPOT data are also very useful in emphasizing and classifying the rock units of a small outcrop area. The detailed geological map of Jabal Daf-Wadi Fatima area is interpreted in this work from supervised classified images of different resolutions as well as the structure map of this area. This study shows that it is preferable to use the supervised classifications of multiresolution data for rock unit discrimination in detailed field mapping.     

Structural properties of Urfa stone doped with erbium oxide

In this study, we investigated the structural properties of Urfa stone (US) doped with erbium oxide (Er₂O₃). Solid US was powdered by using an agate mortar, and its elemental composition was determined using inductive coupling plasma (ICP) methods. Varying amounts of Er₂O₃ (5, 10, 20, 30, and 40%) were added as a dopant to the US powder using mechanical alloying methods. The resultant samples were sintered at 1000 °C for 1 h. The structural properties of the Er₂O₃-doped US samples were subsequently investigated using X-ray diffraction (XRD), Fourier-transform infrared spectrometry (FTIR), and photoluminescence methods. Results from the XRD analysis of the Er₂O₃-doped US powder indicated two crystalline phases: (1) calcium oxide (CaO) or lime and (2) Er₂O₃. After the samples were sintered at 1000 °C, CaO, Er₂O₃, calcium carbonate (CaCO₃), and mixed crystalline phases were observed. Results from the FTIR analysis of the Er₂O₃-doped US samples indicated absorption bands at 711.91, 872.08, and 1396.87 cm^?1 in the spectra. Finally, photoluminescence analysis results indicated a shift in the emission and excitation bands to longer and shorter wavelengths, respectively, in the solid state (non-aqueous media) US-Er complex.     

A practical approach for the interpretation of flowing well tests

Flowing well test is one of the tools employed to identify transmissivity and storage coefficient of a confined aquifer where the potentiometric surface is located above the ground surface, so that the groundwater flows naturally from the well without pumping. During a flowing well test, constant hydraulic head is preserved at the well while the discharge from the well decreases with time and the temporal variation of discharge provides significant information about aquifer characteristics. In this study, a simple and straightforward approach is presented as an alternative to a number of graphical or error minimization-based techniques available in the literature for analyzing data from flowing well tests. The proposed method employs a polynomial regression equation to establish a link between observed discharge and the theoretical dimensionless discharge that is introduced in the analytical solution, so as to retrieve the aquifer parameters. The method is tested with a vast number of synthetically generated data sets as well as a real data set reported in the literature. Besides its simplicity, the present method is seen to produce highly accurate and reliable estimations.     

Geospatial assessment of soil erosion intensity and sediment yield: a case study of Potohar Region,Pakistan

Estimation of spatial extent of soil erosion, one of the most serious forms of land degradation, is critical because soil erosion has serious implications on soil fertility, water ecosystem, crop productivity and landscape beauty. The primary objective of the current study was to assess and map the soil erosion intensity and sedimentation yield of Potohar region of Pakistan. Potohar is the rainfed region with truncated and complex topography lying at the top of the Indus Basin, the world’s largest irrigation networks of canals and barrages. Spatially explicit Revised Universal Soil Loss Equation (RUSLE) Model integrated with Remote Sensing-GIS techniques was used for detecting/mapping of erosion prone areas and quantification of soil losses. The results show that the Potohar region is highly susceptible to soil erosion with an average annual soil loss of 19 tons ha^?1 year^?1 of which the maximum erosion (70–208 tons ha^?1 year^?1) was near the river channels and hilly areas. The sediment yield due to the erosion is as high as 148 tons ha^?1 year^?1 with an average of 4.3 tons ha^?1 year^?1. It was found that 2.06% of the total area falls under severe soil erosion, 13.34% under high erosion, 15.35% under moderate soil erosion while 69.25% of the area lies in the low (tolerable) soil erosion. Chakwal and Jhelum districts of the region are seriously affected by erosion owing to their topography and soil properties. The information generated in this study is a step forward towards proper planning and implementation of strategies to control the erosion and for protection of natural resources. It is, hence, necessary that suitable water harvesting structures be made to control water to prevent soil erosion and provision of water in the lean season in this region. Tree plantation and other erosion control practices such as strip cropping can also minimize soil erosion in this region.     

Extreme deformation characteristics and countermeasures for a tunnel in difficult grounds in southern Shaanxi,China

The Qingling–Bashan (QB) mountain region in southern Shaanxi mainly consists of strongly compressive zones from east to west, with tight folds and compressive fractures. There is a wide distribution of soft rocks of various types, such as phyllite and slate, accompanied by complex geological structures. Ironically, tunnel construction in these difficult grounds with complicated geological conditions embraces a high risk of extreme deformation due to various unpredictable reasons, which can frequently cause collapse and result in budget overruns during the construction period. Therefore, it is crucial to conduct effective countermeasures to eliminate or avoid such adverse impacts. This paper provides a case study on the “Yingfeng tunnel” (a tunnel constructed in soft rock consisting of a slate ground) based on a geological survey, indoor experiments and in situ monitoring. A successive rock mass deformation resulted in the tunnel lining seriously intruding into construction clearance and some other sections, even collapsing during the construction. The maximum displacement amount was 62.5 cm, while the maximum deformation speed reached as high as 34.18 mm/day. Additionally, to evaluate the construction impacts of tunnelling-induced geo-hazards, an investigation on extreme deformation was conducted. Considering the time-dependent features of the rock mass deformation, the constraint-convergence method was used to put forward applicable countermeasures in this paper. Finally, from the feedbacks of monitoring results, extreme deformation of the Yingfeng tunnel was effectively controlled.     

Efficacy of laser cleaning in the removal of biological patina on the volcanic scoria of the rock-hewn churches of Lalibela,Ethiopia

The Lalibela rock-hewn churches are one of the most important religious pilgrimage sites in Ethiopia. These churches are carved from the scoriaceous basalt rock substrate, which has been exposed to attack by biological agents with significant loss of surface material. Particularly, the widespread growth of lichens and other microorganisms on the carved surfaces of the churches has proven to represent a substantial threat for the preservation of the site. In this study, laboratory tests have been conducted to assess the feasibility of using laser technology as an efficient cleaning method of biological patina from polymineralic stone substrates. Multi-analytical techniques were applied for the characterization of the stone samples collected from two of the Lalibela churches: Bete Giyorgis and Bete Amanuel. Stone samples artificially inoculated with bacteria, yeast, fungi isolates, and lichen-encrusted samples were laser cleaned using UV and IR laser wavelengths. The high content of Fe and Ti oxides and the high porosity have made the stone surfaces easily susceptible to low-energy laser treatment. Results indicate that laser cleaning can be applied to polymineralic lithotypes and UV irradiation can successfully remove lichen colonies. Further studies need to be conducted to optimize the laser procedure in polymineralic, high porosity stones.     

Semi-analytical solutions for vertically and laterally loaded piles in multilayered soil deposits

In geotechnical practice, it is of considerable importance to assess the behavior of vertical–lateral coupled loading piles in multilayered soil deposits. This study deals with a semi-analytical formulation for the performance of a pile suffering from combined vertical and lateral loads. The emphasis is on quantifying the mobilization of the subgrade reaction provided by the layered soil stratums. In the proposed method, subgrade reactions, correlated with both the accumulative axial load transfer and side resistances depending upon the pile–soil interaction, are abstracted as a series of nonlinear springs in both vertical and lateral directions. On account of this, an alternative transfer matrix method is applied to characterize the pile reaction along the depth under the identified boundary conditions atop the pile; meanwhile, the condition of static equilibrium, between two specific pile segments located at the border of soil layers, is also essential. On this basis, validation of the solution is conducted by comparing with observations from experiments and predictions obtained from other existing methods. In addition, the influence of properties in shallow soil layer and the vertical load on the lateral response of the pile is also discussed. The results indicate a reduction in the lateral displacement and the maximum bending moment within the pile with the increase in the shallow soil stiffness, but a growth with the increase in vertical load due to the “P-Δ effect.”     

Biogeochemical characterization of a Mediterranean shallow lake using stable isotopes: Laguna del Cristo (NW Iberian Peninsula)

The present multi-isotopic study (δ¹⁸O–δD_water, δ³⁴S–δ¹⁸O_{dissolved-sulphate}, δ¹³C_{dissolved-inorganic-carbon}, δ¹³C–δ¹⁸O_{shells-modern-gastropods}, δ¹³C_plants, and δ¹³C_{sedimentary-organic-matter}) is aimed at assessing the hydrogeochemical changes and biogeochemical dynamics in a Mediterranean shallow lake fed by a Quaternary–Tertiary aquifer, the “Laguna del Cristo” (NW Iberian Peninsula), a system sensitive to climate fluctuations, between 2010 and 2011. Lake water is of the bicarbonate type, and there are no major pollutants. δ¹⁸O-δD_water values plot on a local evaporation line (δD=5.29δ¹⁸O–12.29) indicating that evaporative enrichment had a significant impact on lake water isotopic features. Periods of high water levels are characterized by lower δ³⁴S–δ¹⁸O_{dissolved-sulphate} and δ¹³C_{dissolved-inorganic-carbon} values and suggest sulphate derived from weathering of sulphides in the catchment area, delivered to the lake by surface run-off or via groundwater, and in situ decay of organic matter. During lower water levels, sulphate reduction and enhanced primary productivity lead to higher δ³⁴S_{dissolved-sulphate} and δ¹³C_{dissolved-inorganic-carbon} values. Evaporation induced enrichment in ¹⁸O_sulphate, ¹³C_{dissolved-inorganic-carbon} and ¹³C–¹⁸O_{shells-Galba-Gyraulus}. δ¹³C_plant confirms the C3 photosynthetic pathway. Enrichment in ¹³C submerged aquatic plants indicates that HCO₃^? is the main carbon source, except for ¹³C-depleted Potamogeton. The TOC, δ¹³C_org values, and TC/TN ratios in sediments all confirm the autochthonous character of organic matter contribution. This study provides a baseline for isotopic research into shallow, flow-through lakes fed by siliciclastic aquifers, and stresses the importance of evaporation and refilling (direct precipitation and groundwater discharge) in controlling the solute chemistry and stable isotopic composition in temperate regions with contrasting seasonal climates. The results also provide a snapshot of modern lake isotope variability that can be applied to paleoenvironmental reconstructions.     

Application of sugar foam to red soils in a semiarid Mediterranean environment

The study described here involved evaluating the effects that the application of one by-product (sugar foam waste) has upon red soils in the region of La Mancha (Central Spain). In view of the fact that this is a location where this type of soil abounds, this technique has been a common practice for many years. The principal goal was to investigate the impact of this approach on some of the soil properties and, secondly, on its level of fertility. As a result, this represents an investigation into the effects that this type of waste has on some soil quality parameters. The results showed that, after the addition of by-products over 25 years, sugar foam waste is of agricultural interest mainly due to the increase in organic matter concentration (about 2%) and, to a lesser extent, by increases in calcium carbonate (more than 30%) and P (four times more). The soil pH was also found to increase slightly (1.4), while the electrical conductivity almost did not change. The properties associated with these pedological qualities therefore had a positive effect by improving nutrient availability. As a result, foams arising from sugar industries have a positive effect on soil quality and the application of such foams to soils is beneficial since the need to dispose this residue is also removed.