Facies controls on the distribution of diagenesis and compaction in fluvial-deltaic deposits

The Upper Triassic – Lower Jurassic Åre Formation comprising the deeper reservoir in the Heidrun Field offshore mid-Norway consists of fluvial channel sandstones (FCH), floodplain fines (FF), and sandy and muddy bay-fill sediments (SBF, MBF) deposited in an overall transgressive fluvial to lower delta plain regime. The formation has been investigated to examine possible sedimentary facies controls on the distribution of cementation and compaction based on petrography and SEM/micro probe analyses of core samples related to facies associations and key stratigraphic surfaces. The most significant authigenic minerals are kaolinite, calcite and siderite. Kaolinite and secondary porosity from dissolution of feldspar and biotite are in particular abundant in the fluvial sandstones. The carbonate minerals show complex compositional and micro-structural variation of pure siderite (Sid I), Mg-siderite (Sid II), Fe-dolomite, ankerite and calcite, displaying decreasing Fe from early to late diagenetic carbonate cements. An early diagenetic origin for siderite and kaolinite is inferred from micro-structural relations, whereas pore filling calcite and ankerite formed during later diagenesis. The Fe-dolomite probably related to mixing-zone dolomitization from increasing marine influences, and a regional correlatable calcite cemented layer has been related to a flooding event. Porosity values in non-cemented sandstone samples are generally high in both FCH and SBF facies associations averaging 27%. Differential compaction between sandstone and mudstone has a ratio of up to 1:2 and with lower values for MBF. We emphasize the role of eogenetic siderite cementation in reducing compactability in the fine-grained, coal-bearing sediments most prominent in MBF facies. This has implications for modeling of differential compaction between sandstone and mudstones deposited in fluvial-deltaic environments.     

Narrow associated quasi-stellar object absorbers: clustering, outflows and the line-of-sight proximity effect

Using data from the Sloan Digital Sky Survey data release 3 (SDSS DR3), we investigate how narrow (<700 km s⁻¹) C  iv and Mg  ii quasar absorption-line systems are distributed around quasars. The C  iv absorbers lie in the redshift range 1.6 < z < 4 and the Mg  ii absorbers in the range 0.4 < z < 2.2. By correlating absorbers with quasars on different but neighbouring lines of sight, we measure the clustering of absorbers around quasars on comoving scales between 4 and 30 Mpc. The observed comoving correlation lengths are   r _o∼ 5 h ⁻¹Mpc  , similar to those observed for bright galaxies at these redshifts. Comparing correlations between absorbers and the quasars, in whose spectra they are identified, then implies: (i) that quasars destroy absorbers to comoving distances of ∼300 kpc (C  iv ) and ∼800 kpc (Mg  ii ) along their lines of sight; (ii) that ≳40 per cent of C  iv absorbers within 3000 km s⁻¹ of the quasi-stellar object are not a result of large-scale clustering but rather are directly associated with the quasar itself; (iii) that this intrinsic absorber population extends to outflow velocities of the order of 12 000 km s⁻¹; (iv) that this outflow component is present in both radio-loud and radio-quiet quasars and (v) that a small high-velocity outflow component is also observed in the Mg  ii population. We also find an indication that absorption systems within 3000 km s⁻¹ are more abundant for radio-loud quasars than for radio-quiet quasars. This suggests either that radio-loud objects live in more massive haloes, or that their radio activity generates an additional low-velocity outflow, or both.     

Pore size distribution in an uncompacted equilibrated ordinary chondrite

The extraordinarily uncompacted nature of the ordinary L chondrite fall Baszkówka gives a unique opportunity to investigate the potentially pre-compaction pore size distribution in an equilibrated ordinary chondrite. Using X-ray microtomography and helium pycnometry on two samples of Baszkówka, we have found that on average, two-thirds of the 19.0% porosity resides in inter- and intra-granular voids with volumes between 3×10⁻⁵ and 3 mm³. We show the cumulative number density of pore volumes observable by X-ray microtomography obeys a power law distribution function in this equilibrated ordinary chondrite. We foresee these data adding to our understanding of the impact processing of chondrites and their parent asteroids, where porosity and pore size play significant roles in the parameterization of impact events.     

Currents in a small channel on a sandy tidal flat

Channels affect drainage and bed stresses on tidal flats. Here, near-bottom currents observed on a sandy tidal flat are compared with those observed 35 m away inside a shallow (≈0.3 m deep) channel. For water depths between 0.5 and 2.5 m (when both current meters are submerged), current speeds 0.13 m above the bed on the flat are about 30% greater than those observed 0.13 m above the bed in the channel, and are approximately equal to those observed 0.58 m above the channel bed (0.26 m above the flat elevation). Flow directions on the flat are similar to those in the channel. For flows directed across the channel axis, the ratio of speeds increases from about 1.3 to about 2.2 with increasing water depth. The corresponding ratio of the vertical velocity variances (a proxy for turbulence) decreases from about 1.5 to about 0.2, suggesting that the turbulence near the bed of the channel is greater than that near the bed of the flat for water depths greater than about 1.0 m. Drag coefficients estimated with the vertical velocity variance are approximately 70% larger in the channel than over the visually smoother flat, consistent with prior studies suggesting that channels may increase tidal-flat roughness. For flows directed along the channel axis (in the cross-flat direction), the ratio of speeds (1.2) is similar to the ratio predicted by a cross-flat momentum (along-channel) balance.     

Macroscopic diffusivity in concrete determined by computational homogenization

Effective moisture and chloride ion diffusivity coefficients for concrete are determined by computational homogenization, where concrete is modeled on the mesoscale as a heterogenous three‐phase composite material. By imposing moisture and chloride ion gradients on a representative volume element, effective macroscale properties are obtained through finite element analysis. A parametric study of the effects of the ballast content was carried out. The numerical results correspond well with an estimate of the Hashin–Shtrikman type available in the literature. The computational homogenization strategy proposed here also includes the interfacial transition zone, and its influence on the effective diffusivity coefficients is assessed. Copyright © 2012 John Wiley & Sons, Ltd.     

Black ordinary chondrites: An analysis of abundance and fall frequency

Abstract— Black ordinary chondrite meteorites sample the spectral effects of shock on ordinary chondrite material in the space environment. Since shock is an important regolith process, these meteorites may provide insight into the spectral properties of the regoliths on ordinary chondrite parent bodies. To determine how common black chondrites are in the meteorite collection and, by analogy, the frequency of shock-alteration in ordinary chondrites, several of the world's major meteorite collections were examined to identify black chondrites. Over 80% of all catalogued ordinary chondrites were examined and, using an optical definition, 61 black chondrites were identified. Black chondrites account for approximately 13.7% of ordinary chondrite falls. If the optically altered gas-rich ordinary chondrites are included, the proportion of falls that exhibit some form of altered spectral properties increases to 16.7%. This suggests that optical alteration of asteroidal material in the space environment is a relatively common process.     

The Effect of Bottle Fill Rate and Pour Technique on the Recovery of Volatile Organics

This field study was conducted to examine whether the method or the flow rate (fill rate) used to fill a sample vial affects recovery of volatile organics (VOCs). To our knowledge, there have not been any systematic studies that have examined this issue. For this field study, three fill rates (50 mL/min, 250 mL/min, and ~1 L/min) and three filling methods (top‐pour, side‐pour, and bottom‐fill) were used to fill sample vials. We found that the bottom‐fill method, with the tubing submerged in the sample as it fills, yielded the greatest recovery (i.e., highest concentrations) of VOCs. Little improvement was observed by pouring down the side of a vial vs. simply pouring straight down from the top. We also found that filling the vials at the fastest fill rate (~1 L/min) yielded higher recovery than the slowest fill rate (50 mL/min) using all three filling methods. These results are counter to prevailing guidance and conventional wisdom that slower filling is preferable to faster filling and that pouring down the side of a sample vial is the best practice for VOC sampling. However, because we were unable to randomize the order the samples were collected with respect to fill rate, we recommend a follow‐on study be conducted that will allow us to confirm our findings and better determine which fill rates minimize losses of VOCs