Warm-Season Annual to Decadal Temperature Variability for Hokkaido, Japan, Inferred from Maximum Latewood Density and Ring Width Data

We present a warm season (April–September) temperature reconstructionfor Asahikawa, north central Hokkaido, Japan for AD 1557–1990. The reconstruction, which accounts for 34% of the temperature variancefrom 1925–1990, is based on maximum latewood density data from Saghalinspruce (Picea glehnii) growing at timberline (1340–1390 m) at MountAsahidake, Hokkaido. We only present a high frequency (prewhitened or white noise) version of the reconstruction because there is an unexplained offset in the mean between the actual and estimated temperature data for an earlier period of overlap from 1891–1924. The coldest summer in the reconstruction is 1718, forwhich the estimated value is 12.89 ° C, nearly four standard deviations (SD) below the mean. A colder-than-average year is reconstructed for 1641 (13.30° C, nearly 3 SD below mean), following the eruption of Komagatake, Hokkaido which began in July, 1640. The Asahikawa density chronology, shows decadal modes of variation with statistically significant spectral peaks prior to around 1850. A tree-ring width chronology for this same site (AD 1532–1990) is in phase with a tree-ring width record from centralKamchatka prior to around 1850, but out of phase since that time. This pattern suggests, as has been hypothesized for temperature-sensitive tree-ring records from the eastern Pacific sector (Alaska and Patagonia), that a decadal mode of climate variation was more dominant in the Pacific sector prior to about 1850, after which a higher frequency (ENSO-type) mode may have become more pronounced, at least until recent decades. Additional data from the northwestern Pacific is needed to compare to these findings.     

Variations in abundances and distributions of isoprenoid chromans and long-chain alkylbenzenes in sediments of the Mulhouse Basin: a molecular sedimentary record of palaeosalinity

The abundances and distribution patterns of mono-, di- and trimethylated 2-methyl-2-(4,8,12-trimethyltridecyl) chromans (MTTCs) and long-chain alkylbenzenes in extracts of marl (66 samples), anhydrite (15) and halite (1) strata of the Salt IV Formation of the Oligocene Mulhouse Basin are reported. The distributions of the methylated MTTCs indicate salinity changes of the upper part of a density stratified water column of the basin. These variations are explained by a tectonically or climatically induced change in the supply of water of relative lower salinity to form a layer overlying the deeper water brine. Hence, it is suggested that mesohaline (3.5–15%) conditions in the surface waters were established as a result of periodic incursions of marine water and subsequent evaporation. Conversely, during periods when the surface water was derived mainly from fresh water from the hinterland, lower average salinity in the surface layer resulted. The distributions of long-chain alkylbenzenes also appear to record these changes.     

Contrasting modes of supercontinent formation and the conundrum of Pangea

Repeated cycles of supercontinent amalgamation and dispersal have occurred since the Late Archean and have had a profound influence on the evolution of the Earth's crust, atmosphere, hydrosphere, and life. When a supercontinent breaks up, two geodynamically distinct tracts of oceanic lithosphere exist: relatively young interior ocean floor that develops between the dispersing continents, and relatively old exterior ocean floor, which surrounded the supercontinent before breakup. The geologic and Sm/Nd isotopic record suggests that supercontinents may form by two end-member mechanisms: introversion (e.g. Pangea), in which interior ocean floor is preferentially subducted, and extroversion (e.g. Pannotia), in which exterior ocean floor is preferentially subducted.The mechanisms responsible remain elusive. Top–down geodynamic models predict that supercontinents form by extroversion, explaining the formation of Pannotia in the latest Neoproterozoic, but not the formation of Pangea. Preliminary analysis indicates that the onset of subduction in the interior (Rheic) ocean in the early Paleozoic, which culminated in the amalgamation of Pangea, was coeval with a major change in the tectonic regime in the exterior (paleo-Pacific) ocean, suggesting a geodynamic linkage between these events. Sea level fall from the Late Ordovician to the Carboniferous suggests that the average elevation of the oceanic crust decreased in this time interval, implying that the average age of the oceanic lithosphere increased as the Rheic Ocean was contracting, and that subduction of relatively new Rheic Ocean lithosphere was favoured over the subduction of relatively old, paleo-Pacific lithosphere. A coeval increase in the rate of sea floor spreading is suggested by the relatively low initial ⁸⁷Sr/⁸⁶Sr in late Paleozoic ocean waters. We speculate that superplumes, perhaps driven by slab avalanche events, can occasionally overwhelm top–down geodynamics, imposing a geoid high over a pre-existing geoid low and causing the dispersing continents to reverse their directions to produce an introverted supercontinent.     

Semiautomatic and Automatic Cooperative Inversion of Seismic and Magnetotelluric Data

Natural source electromagnetic methods have the potential to recover rock property distributions from the surface to great depths. Unfortunately, results in complex 3D geo-electrical settings can be disappointing, especially where significant near-surface conductivity variations exist. In such settings, unconstrained inversion of magnetotelluric data is inexorably non-unique. We believe that: (1) correctly introduced information from seismic reflection can substantially improve MT inversion, (2) a cooperative inversion approach can be automated, and (3) massively parallel computing can make such a process viable. Nine inversion strategies including baseline unconstrained inversion and new automated/semiautomated cooperative inversion approaches are applied to industry-scale co-located 3D seismic and magnetotelluric data sets. These data sets were acquired in one of the Carlin gold deposit districts in north-central Nevada, USA. In our approach, seismic information feeds directly into the creation of sets of prior conductivity model and covariance coefficient distributions. We demonstrate how statistical analysis of the distribution of selected seismic attributes can be used to automatically extract subvolumes that form the framework for prior model 3D conductivity distribution. Our cooperative inversion strategies result in detailed subsurface conductivity distributions that are consistent with seismic, electrical logs and geochemical analysis of cores. Such 3D conductivity distributions would be expected to provide clues to 3D velocity structures that could feed back into full seismic inversion for an iterative practical and truly cooperative inversion process. We anticipate that, with the aid of parallel computing, cooperative inversion of seismic and magnetotelluric data can be fully automated, and we hold confidence that significant and practical advances in this direction have been accomplished.     

Compression and consolidation anisotropy of some soft soils

The compression and consolidation anisotropy of 11 soft soils were studied by conducting oedometer tests on sets of duplicate undisturbed specimens prepared in the vertical and horizontal directions from adjacent sections of carefully sampled borehole cores. The one-dimensional compression, yield and creep characteristics of the various silts, clays and amorphous peaty material tested were similar for the vertical and horizontal directions. The exception was the structured, coarse fibrous peaty material which was strongly cross-anisotropic. Drainage occurred more rapidly in the horizontal direction with horizontal-to-vertical permeability ratios r _k of 1.0–1.7. Higher r _k values were associated with more marked fabrics, namely for clays with fine sand partings, fibrous organic inclusions or fine root-holes and the laminated silts. The r _k value was for practical purposes independent of the stress level. Brendan C. O’Kelly: Formerly Scott Wilson Consulting Engineers, UK     

Assessing the spatial variability of the ~3 μm OH/H2O absorption feature in CM2 carbonaceous chondrites

H₂O and OH are readily detected in hydrated minerals in CM chondrites via reflectance spectroscopy due to their characteristic vibration absorptions at infrared wavelengths. Previous spectroscopic work on bulk powdered CM chondrites has shown that spectral parameters, like the wavelength position of the “3 μm absorption feature,” vary systematically with the extent to which the samples have been aqueously altered. However, it is yet unclear how these spectral features may vary across an intact meteorite chip when measured at spatial scales smaller than that of the individual components of the meteorite. Here, we explore the spatial variability of this spectral feature and others on intact CM2 chips which, unlike powders, retain their petrologic and textural characteristics. We also model the modal mineralogy of the bulk meteorite powders and correlate this with key spectral features, demonstrating that microscope Fourier transform infrared spectroscopic mapping provides a powerful, rapid, and non-destructive technique for assessing compositional diversity and variations in water–rock interactions in chondritic planetary materials. In all CM2 chondrites studied here, we find that variations in the position, shape, and strength of the 3 μm absorption feature reveal a single chondrite can exhibit as much spectral variation as the entire suite of CM2 chondrites. The observed variations in the position and shape of the 3 μm feature within individual CM2 chondrite chips suggest a range of alteration products (e.g., Mg-rich to Fe-rich phyllosilicates) are present and record sub-mm scale variations in the amount and/or chemistry of the altering fluids. The samples having experienced the most progressive aqueous alteration show the least amount of variability in features like the 3 μm absorption band minimum position, whereas the least altered samples exhibit the most variability. We also find that the bulk spectral signatures in the least altered samples appear to be biased toward the spectral signatures of clasts versus matrix. By extension, asteroid reflectance spectra exhibiting 3 μm absorption features consistent with those measured here may be interpreted in a similar framework in which the spectrum of what may appear to be the least altered asteroids represents an average that belies the true diversity of mineralogy and chemistry of the body.     

A depositional model for offshore deposits of the lower Blue Gate Member,Mancos Shale,Uinta Basin,Utah, USA

Depositional models that use heterogeneity in mud‐dominated successions to distinguish and diagnose environments within the offshore realm are still in their infancy, despite significant recent advances in understanding the complex and dynamic processes of mud deposition. Six cored intervals of the main body of the Mancos Shale, the lower Blue Gate Member, Uinta Basin, were examined sedimentologically, stratigraphically and geochemically in order to evaluate facies heterogeneity and depositional mechanisms. Unique sedimentological and geochemical features are used to identify three offshore environments of deposition: the prodelta, the mudbelt and the sediment‐starved shelf. Prodelta deposits consist of interlaminated siltstone and sandstone and exhibit variable and stressed trace fossil assemblages, and indicators of high sedimentation rates. The prodelta was dominated by river‐fed hyperpycnal flow. Mudbelt deposits consist of interlaminated siltstone and sandstone and are characterized by higher bioturbation indices and more diverse trace fossil assemblages. Ripples, scours, truncations and normally graded laminations are abundant in prodelta and mudbelt deposits indicating dynamic current conditions. Mudbelt sediment dispersal was achieved by both combined flow above storm wave base and current‐enhanced and wave‐enhanced sediment gravity flows below storm wave base. Sediment‐starved shelf deposits are dominantly siltstone to claystone with the highest calcite and organic content. Bioturbation is limited to absent. Sediment‐starved shelf deposits were the result of a combination of shelfal currents and hypopycnal settling of sediment. Despite representing the smallest volume, sediment‐starved shelf deposits are the most prospective for shale hydrocarbon resource development, due to elevated organic and carbonate content. Sediment‐starved shelf deposits are found in either retrogradational to aggradational parasequence sets or early distal aggradational to progradational parasequence sets, bounding the maximum flooding surface. An improved framework classification of offshore mudstone depositional processes based on diagnostic sedimentary criteria advances our predictive ability in complex and dynamic mud‐dominated environments and informs resource prospectivity.