Seismic microzonation for Muscat region,Sultanate of Oman

Natural Hazards - Site characterization was carried out for Muscat region using the ambient noise measurements applying the horizontal-to-vertical spectral ratio (HVSR) technique and using active...     

Factors affecting the Nd3+ (REE3+) luminescence of minerals

In this paper, possibilities and limits of the application of REE³⁺ luminescence (especially the Nd^{3+ 4}F_3/2 → ⁴I_9/2 emission) as structural probe are evaluated. Important factors controlling the Nd³⁺ luminescence signal are discussed, including effects of the crystal-field, crystal orientation, structural state, and temperature. Particular attention was paid to the study of the accessory minerals zircon (ZrSiO₄), xenotime–(Y) (YPO₄), monazite–(Ce) (CePO₄) and their synthetic analogues. Based on these examples we review in short that (1) REE³⁺ luminescence can be used as non-destructive phase identification method, (2) the intensities of certain luminescence bands are strongly influenced by crystal orientation effects, and (3) increased widths of REE³⁺-related emission bands are a strong indicator for structural disorder. We discuss the potential of luminescence spectroscopy, complementary to Raman spectroscopy, for the quantitative estimation of chemical (and potentially also radiation-induced) disorder. For the latter, emissions of Nd³⁺-related centres are found to be promising candidates.     

The building blocks of continental crust: Evidence for a major change in the tectonic setting of continental growth at the end of the Archean

Oceanic arcs are commonly cited as primary building blocks of continents, yet modern oceanic arcs are mostly subducted. Also, lithosphere buoyancy considerations show that oceanic arcs (even those with a felsic component) should readily subduct. With the exception of the Arabian–Nubian orogen, terranes in post-Archean accretionary orogens comprise < 10% of accreted oceanic arcs, whereas continental arcs compose 40–80% of these orogens. Nd and Hf isotopic data suggest that accretionary orogens include 40–65% juvenile crustal components, with most of these (> 50%) produced in continental arcs.Felsic igneous rocks in oceanic arcs are depleted in incompatible elements compared to average continental crust and to felsic igneous rocks from continental arcs. They have lower Th/Yb, Nb/Yb, Sr/Y and La/Yb ratios, reflecting shallow mantle sources in which garnet did not exist in the restite during melting. The bottom line of these geochemical differences is that post-Archean continental crust does not begin life in oceanic arcs. On the other hand, the remarkable similarity of incompatible element distributions in granitoids and felsic volcanics from continental arcs is consistent with continental crust being produced in continental arcs.During the Archean, however, oceanic arcs may have been thicker due to higher degrees of melting in the mantle, and oceanic lithosphere would be more buoyant. These arcs may have accreted to each other and to oceanic plateaus, a process that eventually led to the production of Archean continental crust. After the Archean, oceanic crust was thinner due to cooling of the mantle and less melt production at ocean ridges, hence, oceanic lithosphere is more subductable. Widespread propagation of plate tectonics in the late Archean may have led not only to rapid production of continental crust, but to a change in the primary site of production of continental crust, from accreted oceanic arcs and oceanic plateaus in the Archean to primarily continental arcs thereafter.     

A new Ordovician eurypterid (Arthropoda: Chelicerata) from southeast Turkey: Evidence for a cryptic Ordovician record of Eurypterida

A new species of eurypterid, Paraeurypterus anatoliensis gen. et sp. nov., is described from the Upper Ordovician (Katian) ?ort Tepe Formation of southeast Turkey. The single specimen, preserving the carapace, mesosoma and fragments of appendages, appears morphologically intermediate between the eurypteroid families Dolichopteridae and Eurypteridae. P. anatoliensis retains the plesiomorphic conditions of crescentic eyes with enlarged palpebral lobes and a quadrate carapace with ornamentation consisting of small pustules but also displaying the derived characteristics of genal facets and a row of large acicular scales across the posterior of each tergite. Phylogenetic analysis incorporating each of the major eurypterine clades and all Eurypterina having a three-segmented genital operculum (the triploperculate condition) resolves eurypteroids to be an unnatural group, with Dolichopteridae and Eurypteridae forming part of a grade leading to diploperculate Eurypterina. P. anatoliensis is intermediate between the two eurypteroid families, as is ‘Eurypterus’ minor from the Pentland Hills of Scotland, which is shown to be a distinct genus and assigned to Pentlandopterus gen. nov. Using the phylogenetic topology to infer ghost ranges for each of the major eurypterid clades reveals that the majority of eurypterid superfamilies must have originated by the Katian, indicating a largely unsampled record of Ordovician eurypterids. The occurrence of poor dispersers such as Paraeurypterus in the Ordovician of Gondwana is puzzling, and it has been suggested that they dispersed to the continent during periods of sea level lowstand in the Sandbian and Hirnantian, however this does not explain the lack of Ordovician species in North America and Europe, given the well-sampled nature of these continents, and an alternative is proposed whereby eurypterids originated in Gondwana and radiated out to Laurentia and Baltica in the late Ordovician and early Silurian, thus explaining their sudden appearance in the European and North American rock record.     

Lahnsteinite, Zn4(SO4)(OH)6 · 3H2O, a new mineral from the Friedrichssegen Mine, Germany

A new mineral, lahnsteinite, has been found in the dump of the Friedrichssegen Mine, Bad Ems district, Rhineland-Palatinate (Rheinland-Pfalz), Germany. Lahnsteinite, occurring as colorless tabular crystals in the cavities of goethite, is associated with pyromorphite, hydrozincite, quartz, and native copper. The Mohs’ hardness is 1.5; the cleavage is perfect parallel to (001). D _calc = 2.995 g/cm³, D _meas = 2.98(2) g/cm³. The IR spectrum is given. The new mineral is optically biaxial, negative, α = 1.568(2), β = 1.612(2), γ = 1.613(2), 2V _meas = 18(3)°, 2V _calc = 17°. The chemical composition (wt %, electron microprobe data; H₂O was determined by gas chromatography of ignition products) is as follows: 3.87 FeO, 1.68 CuO, 57.85 ZnO, 15.83 SO₃, 22.3 H₂O, total is 101.53. The empirical formula is (Zn_3.3Fe_0.27Cu_0.11)_Σ3.91(S_0.98O₄)(OH)₅ · 3H_2.10O. The crystal structure has been studied on a single crystal. Lahnsteinite is triclinic, space group P1, a = 8.3125(6), b = 14.545(1), c = 18.504(2) Å, α = 89.71(1), β = 90.05(1), γ = 90.13(1)°, V = 2237.2(3) ų, Z = 8. The strong reflections in the X-ray powder diffraction pattern [d, Å (I, %)] are: 9.30 (100), 4.175 (18), 3.476 (19), 3.290 (19), 2.723 (57), 2.624 (36), 2.503 (35), 1.574 (23). The mineral has been named after its type locality near the town of Lahnstein. The type specimen of lahnsteinite is deposited in the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, registration number 4252/1.     

Using streamflow characteristics to explore permafrost thawing in northern Swedish catchments

The recent and rapid warming of the Arctic leads to thawing of permafrost, which influences and changes subsurface water-flow systems in such landscapes. This study explores the utility of catchments as “sentinels of change” by considering long-term discharge data from 17 stations on unregulated rivers in northern Sweden and analyzing trends in annual minimum discharge and recession flow characteristics. For the catchments considered, the annual minimum discharge has increased significantly (based on the Mann Kendall test at a 95 % confidence level) in nine of the catchments and decreased significantly in one catchment. Considering changes in recession-flow characteristics, seven catchments showed significant trends consistent with permafrost thawing while two catchments showed significant trends in the opposite direction. These results are mechanistically consistent with generic physically based modeling studies and the geological setting, as the catchments considered span the spatial limit of permafrost extent. This study illuminates the potential for using hydrologic observations to monitor changes in catchment-scale permafrost. Further, this opens the door for research to isolate the mechanisms behind the different trends observed and to gauge their ability to reflect actual permafrost conditions at the catchment scale.     

Kinematics of the Central Taurides during Neotethys closure and collision, the nappes in the Sultan Mountains, Turkey

In the Central Taurides, the Sultan Mountains comprise in ascending order the Çimendere unit and the Ak?ehir, Do?anhisar, Çay nappes composed of metasedimentary sequences deposited from Cambrian to Tertiary. The overthrust of the Çay nappe on the Lutetian Celepta? formation representing the uppermost stratigraphic position in the Çimendere unit indicates that the latest nappe emplacement occurred during the Middle Eocene. The Oligocene and Miocene rocks are in post-tectonic facies in the west Central Taurides. The kinematic data from these nappes related to closure of the Neotethys reveal a top-NE shear sense in the northwest part and a top-SE shear sense in the southeast part of the Sultan Mountains. The Sultan Mountains are located in the north part of the Isparta Angle which was tectonically assembled by the Lycian, Hoyran–Bey?ehir–Hadim and Antalya allochthons on the Bey Da?lar? and Anamas–Akseki autochthons from the Latest Cretaceous to the Late Pliocene. The previous paleomagnetic data showed that the west and east subsections of the Isparta Angle were subjected to post-Eocene 30°–40° anticlockwise and clockwise rotations, respectively. In consideration of these paleomagnetic data, the kinematic data measured in the Sultan Mountains might be restored into approximately E–W-trending linear fabric associated with a top-E shear sense. These new kinematic data from the nappes in the Sultan Mountains disagree with the existing tectonic models that suggest N–S nappe translation over the Central Taurides during the latest Cretaceous–Middle Eocene. The alternative tectonic model for the Antalya nappes in the core of the Isparta Angle related to east–west compression suggests westward and eastward nappe emplacements on the surrounding autochthons. However, the new kinematic data presented here point consistently to a top-E shear sense in all tectonostratigraphic units in the Sultan Mountains currently located in the north part of the Anamas–Akseki autochthon.     

Evaluation of trace element availability from secondary metallurgical slag generated in steelmaking by sequential chemical extraction

During carbon steel manufacture, slag residues are generated to remove material impurities from liquid metal and thus control the quality of carbon steel. As the utilization of secondary metallurgical slags is not as efficient as those of primary slags, a comprehensive characterization of steel ladle slag was performed. Pseudo-total concentrations of a wide range of elements were determined during a 6-week sampling period with relevant physical and chemical properties, sequential extraction of trace elements, and parallel mineralogical characterization of extraction residues from a representative combined sample. According to the results, only Cr and V occurred in elevated concentrations with respective 6-week mean values of 198 and 310 mg kg^?1 (d.w.). The residual standard deviation of the weekly pseudo-total concentration values of the aforementioned elements (24 and 31 %, respectively) indicated that significant variation in the concentration of trace elements can occur due to fluctuation in process conditions and/or slag characteristics. The sequential extraction procedure suggested potential phytoavailability of V (123 mg kg^?1, d.w., amounting to 41 % of the respective pseudo-total concentration) through, e.g., changes in prevailing redox conditions. Although the analytical approach was validated by the analysis of a certified reference material and the calculation of extraction recoveries, the mineralogical characterization of parallel extraction residues indicated non-selectivity of the procedure coupled with potential redistribution phenomena during extraction with hydrogen peroxide and ammonium acetate.     

Landfill site selection and landfill liner design for Ankara, Turkey

Considering the high population growth rate of Ankara, it is inevitable that landfill(s) will be required in the area in the near future to sustain the sanitary waste disposal needs of the city. The main scope of this study is to select alternative landfill sites for Ankara based on the growing trends of Ankara toward the northwest, particularly toward the Sincan municipality, and to eventually select the best alternative through utilizing multi-criteria decision making. Landfill site selection was carried out utilizing Geographic Information System (GIS) and Multi-Criteria Decision Analysis. A number of criteria, namely, settlement, slope, proximity to roads, geology, availability and proximity of landfill containment material (i.e., clay for composite lining system), suitability for agriculture, erosion, vegetation cover and lineament system were gathered in a GIS environment. Each criterion was assigned a weight value by applying the Pairwise Comparison Method and the Analytical Hierarchy Method. In order to choose the best alternative, the Technique for Order Preference by Similarity to the Ideal Solution, which is regarded as an ideal point method, was applied and a landfill site was selected. The geotechnical properties of the so-called “Ankara clay” that shows widespread distribution in Ankara were reviewed and assessed for its suitability as a compacted clay liner.