Atmospheric effects in the remote sensing of phytoplankton pigments

We investigate the accuracy with which relevant atmospheric parameters must be estimated to derive phytoplankton pigment concentrations (chlorophyll a plus phaeophytin a ) of a given accuracy from measurements of the ocean's apparent spectral radiance at satellite altitudes. The analysis is limited to an instrument having the characteristics of the Coastal Zone Color Scanner scheduled to orbit the Earth on NIMBUS-G. A phytoplankton pigment algorithm is developed which relates the pigment concentration (C) to the three ratios of upwelling radiance just beneath the sea surface which can be formed from the wavelengths () 440, 520 and 550 nm. The pigment algorithm explains from 94 to 98% of the variance in log₁₀ C over three orders of magnitude in pigment concentration. This is combined with solutions to the radiative transfer equation to simulate the ocean's apparent spectral radiance at satellite altitudes as a function of C and the optical properties of the aerosol, the optical depth of which is assumed to be proportioned to ^-n . A specific atmospheric correction algorithm, based on the assumption that the ocean is totally absorbing at 670 nm, is then applied to the simulated spectral radiance, from which the pigment concentration is derived. Comparison between the true and derived values of C show that: (1) n is considerably more important than the actual aerosol optical thickness; (2) for C 0299-1 0.2 g l^-1 acceptable concentrations can be determined as long as n is not overestimated; (3) as C increases, the accuracy with which n must be estimated, for a given relative accuracy in C, also increases; and (4) for C greater than about 0.5 g 1^-1, the radiance at 440 nm becomes essentially useless in determining C. The computations also suggest that if separate pigment algorithms are used for C 1gl^-1 and C 1 gl^-1, accuracies considerably better than ±± in log C can be obtained for C 1 g l^-1 with only a coarse estimate of n, while for C 10 gl^-1, this accuracy can be achieved only with very good estimates of n.Contribution No. 387 from the NOAA/ERL Pacific Environmental Laboratory.On leave from Department of Physics, University of Miami, Coral Gables, Florida.     

Some methods for statistical analysis of multimodal distributions and their application to grain-size data

Some of the methods used in the resolution of mixed normal distributions are discussed under three headings: analytical, graphical, and numerical methods. Attention is given to their applicability in the analysis of grain-size data as derived from sieving. Comparisons are made by applying several methods to published data. It is concluded that the numerical methods offer most scope, especially the method of nonlinear least squares. Some analyses of beach sediments, using this method, are presented. The adoption of a convention for the number of individuals in the sample increases ease of interpretation.     

Geochronology and petrochemistry of Easter and Sala y Gomez Islands: implications for the origin of the Sala y Gomez Ridge

Easter and Sala y Gomez Islands lie along the Sala y Gomez Ridge, a broad zone of high topography and scattered seamounts extending east-southeast from the East Pacific Rise. K-Ar ages and major element abundances of volcanic rocks from these islands are used to test the fixed melting spot hypothesis for the origin of this feature. Poike volcano, the oldest center on Easter Island, was constructed in two episodes, occurring at 2.5 and 0.9 m.y. ago. Eruptive activity on Sala y Gomez was nearly contemporaneous with the earliest volcanism on Easter Island. No migration of volcanism with time is apparent along the Sala y Gomez Ridge. Basaltic rocks from Easter Island have tholeiitic affinities, while those dredged from the base of Sala y Gomez belong to an alkali olivine basalt series. Differences in basalt chemistry suggest that the volcanic rocks from the two islands formed from magmas that equilibrated at different pressures, and a model is presented which relates the character of the erupted liquids to magma segregation at the base of a progressively thickening lithosphere. The islands and seamounts comprising the Sala y Gomez Ridge do not fall on a small circle about the Nazca-mantle pole of absolute motion. Available evidence, therefore, does not support a fixed melting spot origin for Easter Island, Sala y Gomez, and the Sala y Gomez Ridge. Rather, it appears that the Sala y Gomez Ridge formed along a leaky fracture zone, and in response to a major re-orientation of spreading centers in this area.     

The spatial context of manpower policy: Implications of current Canadian policy on regional development and planning

Macro government policies are often considered outside the context of their spatial impact. Following recent discussions of the problem, this paper is concerned with a critical review of Canadian Manpower policy in the context of national efficiency, regional equity and their interaction. Thus Manpower policy is analysed with respect to its implications concerning regional development as well as implicit regional policy. It is contended that many of the problems of Manpower policy in the spatial context can be traced back to the implicit theoretical background of Manpower policy; Human Capital theory. A radical critique of Human Capital theory is presented and a brief discussion of the ‘functional’ relationship between regional inequality and national macro-planning is also noted. In general the paper concludes that Manpower and regional policies in Canada tend to be contradictory although more research is needed to analyse the spatial impact of macro-policy which may overwhelm spatial policy and significantly influence the future of the spatial economy.     

Major changes in ice stream dynamics during deglaciation of the north-western margin of the Laurentide Ice Sheet

Victoria Island lies at the north-western limit of the former North American (Laurentide) Ice Sheet in the Canadian Arctic Archipelago and displays numerous cross-cutting glacial lineations. Previous work suggests that several ice streams operated in this region during the last (Wisconsinan) glaciation and played a major role in ice sheet dynamics and the delivery of icebergs into the Arctic Ocean. This paper produces the first detailed synthesis of their behaviour from the Last Glacial Maximum through to deglaciation (～21–9.5 cal ka BP) based on new mapping and a previously published radiocarbon-constrained ice sheet margin chronology. Over 70 discrete ice flow events (flow-sets) are ‘fitted’ to the ice margin configuration to allow identification of several ice streams ranging in size from large and long-lived (thousands of years) to much smaller and short-lived (hundreds of years). The reconstruction depicts major ice streams in M'Clure Strait and Amundsen Gulf which underwent relatively rapid retreat from the continental shelf edge at some time between ～15.2 and 14.1 cal ka BP: a period which encompasses climatic warming and rapid sea level rise (meltwater pulse-1a). Following this, overall retreat was slower and the ice streams exhibited asynchronous behaviour. The Amundsen Gulf Ice Stream continued to operate during ice margin retreat, whereas the M'Clure Strait Ice Stream ceased operating and was replaced by an ice divide within ～1000 years. This ice divide was subsequently obliterated by another short-lived phase of ice streaming in M'Clintock Channel ～13 cal ka BP. The timing of this large ice discharge event coincides with the onset of the Younger Dryas. Subsequently, a minor ice divide developed once again in M'Clintock Channel, before final deglaciation of the island shortly after 9.5 cal ka BP. It is concluded that large ice streams at the NW margin of the Laurentide Ice Sheet, equivalent in size to the Hudson Strait Ice Stream, underwent major changes during deglaciation, resulting in punctuated delivery of icebergs into the Arctic Ocean. Published radiocarbon dates constrain this punctuated delivery, as far as is possible within the limits imposed by their precision, and we note their coincidence with pulses of meltwater delivery inferred from numerical modelling and ocean sediment cores.     

Reconstructing the last Irish Ice Sheet 2: a geomorphologically-driven model of ice sheet growth,retreat and dynamics

The ice sheet that once covered Ireland has a long history of investigation. Much prior work focussed on localised evidence-based reconstructions and ice-marginal dynamics and chronologies, with less attention paid to an ice sheet wide view of the first order properties of the ice sheet: centres of mass, ice divide structure, ice flow geometry and behaviour and changes thereof. In this paper we focus on the latter aspect and use our new, countrywide glacial geomorphological mapping of the Irish landscape (>39 000 landforms), and our analysis of the palaeo-glaciological significance of observed landform assemblages (article Part 1), to build an ice sheet reconstruction yielding these fundamental ice sheet properties. We present a seven stage model of ice sheet evolution, from initiation to demise, in the form of palaeo-geographic maps. An early incursion of ice from Scotland likely coalesced with local ice caps and spread in a south-westerly direction 200 km across Ireland. A semi-independent Irish Ice Sheet was then established during ice sheet growth, with a branching ice divide structure whose main axis migrated up to 140 km from the west coast towards the east. Ice stream systems converging on Donegal Bay in the west and funnelling through the North Channel and Irish Sea Basin in the east emerge as major flow components of the maximum stages of glaciation. Ice cover is reconstructed as extending to the continental shelf break. The Irish Ice Sheet became autonomous (i.e. separate from the British Ice Sheet) during deglaciation and fragmented into multiple ice masses, each decaying towards the west. Final sites of demise were likely over the mountains of Donegal, Leitrim and Connemara. Patterns of growth and decay of the ice sheet are shown to be radically different: asynchronous and asymmetric in both spatial and temporal domains. We implicate collapse of the ice stream system in the North Channel – Irish Sea Basin in driving such asymmetry, since rapid collapse would sever the ties between the British and Irish Ice Sheets and drive flow configuration changes in response. Enhanced calving and flow acceleration in response to rising relative sea level is speculated to have undermined the integrity of the ice stream system, precipitating its collapse and driving the reconstructed pattern of ice sheet evolution.     

Macrofauna along the Sudanese Red Sea coast: potential effect of mangrove clearance on community and trophic structure

Mangroves along the Sudanese Red Sea coast are under constant anthropogenic pressure. To better understand the influence of mangrove clearance on the intertidal benthic community, we investigated the composition, biodiversity and standing stock of the macrofauna communities at high‐, mid‐ and low‐water levels in three contrasting habitats: a bare sand flat, a cleared mangrove and an intact mangrove. In addition, a community‐wide metric approach based on taxon‐specific carbon and nitrogen isotope values was used to compare the trophic structure between the three habitats. The habitats differed significantly in terms of macrofaunal standing stock, community composition and trophic structure. The high‐ and mid‐water levels of the intact mangroves showed a distinct macrofaunal community characterized by elevated densities and biomass, largely governed by higher decapod and gastropod abundances. Diversity was similar for cleared and intact mangroves, but much lower for the bare sand flat. Community‐wide metrics indicated highest trophic diversity and community niche breadth in the intact mangroves. Differences between the cleared and intact mangroves can be partly attributed to differences in sediment characteristics resulting from mangrove clearance. These results suggest a significant impact of mangrove clearance on the macrofaunal community and trophic structure. This study calls for further investigations and management actions to protect and restore these habitats, and ensure the survival of this ecologically valuable coastal ecosystem.     

The Christiansen Effect in Saturn’s narrow dusty rings and the spectral identification of clumps in the F ring

Stellar occultations by Saturn’s rings observed with the Visual and Infrared Mapping Spectrometer (VIMS) onboard the Cassini spacecraft reveal that dusty features such as the F ring and the ringlets in the Encke and the Laplace Gaps have distinctive infrared transmission spectra. These spectra show a narrow optical depth minimum at wavelengths around 2.87 μm. This minimum is likely due to the Christiansen Effect, a reduction in the extinction of small particles when their (complex) refractive index is close to that of the surrounding medium. Simple Mie-scattering models demonstrate that the strength of this opacity dip is sensitive to the size distribution of particles between 1 and 100 μm across. Furthermore, the spatial resolution of the occultation data is sufficient to reveal variations in the transmission spectra within and among these rings. In both the Encke Gap ringlets and F ring, the opacity dip weakens with increasing local optical depth, which is consistent with the larger particles being concentrated near the cores of these rings. The Encke Gap ringlets also show systematically weaker opacity dips than the F ring and Laplace Gap ringlet, implying that the former has a smaller fraction of grains less than ∼30 μm across. However, the strength of the opacity dip varies most dramatically within the F ring; certain compact regions of enhanced optical depth lack an opacity dip and therefore appear to have a greatly reduced fraction of grains in the few-micron size range. Such spectrally-identifiable structures probably represent a subset of the compact optically-thick clumps observed by other Cassini instruments. These variations in the ring’s particle size distribution can provide new insights into the processes of grain aggregation, disruption and transport within dusty rings. For example, the unusual spectral properties of the F-ring clumps could perhaps be ascribed to small grains adhering onto the surface of larger particles in regions of anomalously low velocity dispersion.