A high‐resolution relative time scale for the Viséan Stage (Carboniferous) of the Kulm Basin (Rhenish Mountains,Germany)

The Viséan (Carboniferous) sedimentary succession of the basinal Kulm facies (Rhenish Mountains) was investigated in detail in order to achieve a high‐resolution stratigraphic subdivision and correlation. Additionally, the ranges of fossil index taxa (ammonoids), fossil marker beds, volcaniclastic horizons and sedimentary features (e.g. colour changes) were integrated in the correlation. As a result, a comprehensive database was compiled, which contains 190 stratigraphic events of the Viséan interval of this area. Several sections are almost completely composed of shales, which are regarded to represent a slow but constant basinal background sedimentation of the Kulm facies. The thickness of lithological homogeneous sections thus indicates an approximately linear record of time and the average thicknesses of biozones and positions of stratigraphic events can easily be calculated from the compiled database. The result is an approximately time‐linear biostratigraphic scale for the Viséan Stage of the Kulm Basin. Given a numerical length of the Viséan Stage of ca. 19 Ma, 190 stratigraphic events give a mean resolution of 100 000 years. This is unique in Palaeozoic stratigraphy. Copyright © 2008 John Wiley & Sons, Ltd.     

Diterpenoid compounds and other lipids in deep-sea sediments and their geochemical significance

Cyclic diterpenoid compounds have been found by various investigators in the geosphere (e.g. fossil resins, coals, soil, shale and deep-sea sediments). These compounds occur in significant amounts only in higher plants and are therefore potential markers of terrigenous plant lipids.Diterpenoids with the abietane skeleton (mainly dehydroabietic acid) have been identified in the lipids of sediment samples from the northeast Pacific Ocean, Black Sea and North Atlantic Ocean. The presence of these resin-derived compounds correlated with the terrigenous clay components and with the presence of pollen. The presence of polycyclic diterpenoids was also correlated with the distribution patterns and inferred sources of other sediment lipid constituents (e.g. n-alkanes, n-fatty acids, etc.).Potamic transport, followed by turbidite redistribution are the probable input mechanisms of these resin-derived compounds to the deep-sea sediments. These diterpenoids appear to be excellent biological markers of resinous higher plants.     

PLL Tracking Performance in the Presence of Oscillator Phase Noise

The tracking performance of a Phase Lock Loop (PLL) is affected by the influence of several error sources. In addition to thermal noise and dynamic stress error, oscillator phase noise can cause significant phase jitter which degrades the tracking performance. Oscillator phase noise is usually caused by two different effects: Allan deviation phase noise is caused by frequency instabilities of the receiver's reference oscillator and the satellite's frequency standard. It can be termed as system-inherent phase noise and is relevant for both static and dynamic applications. “External” phase noise, however, is caused by vibration and is a major problem for dynamic applications. In the context of this paper, both types of phase noise will be modeled and the resulting integrals will be evaluated for PLLs up to the third order. Besides, phase jitter induced by thermal noise and signal dynamics will also be discussed, thus providing all necessary formulas for analyzing the performance of a phase lock loop in case of different forms of stress. Since the main focus is centered on the effects of oscillator phase noise, the overall PLL performance is graphically illustrated with and without consideration of oscillator phase noise. © 2002 Wiley Periodicals, Inc.     

Microfacies and diagenesis of older Pleistocene (pre‐last glacial maximum) reef deposits,Great Barrier Reef,Australia (IODP Expedition 325): A quantitative approach

During Integrated Ocean Drilling Program Expedition 325, 34 holes were drilled along five transects in front of the Great Barrier Reef of Australia, penetrating some 700 m of late Pleistocene reef deposits (post‐glacial; largely 20 to 10 kyr bp ) in water depths of 42 to 127 m. In seven holes, drilled in water depths of 42 to 92 m on three transects, older Pleistocene (older than last glacial maximum, >20 kyr bp ) reef deposits were recovered from lower core sections. In this study, facies, diagenetic features, mineralogy and stable isotope geochemistry of 100 samples from six of the latter holes were investigated and quantified. Lithologies are dominated by grain‐supported textures, and were to a large part deposited in high‐energy, reef or reef slope environments. Quantitative analyses allow 11 microfacies to be defined, including mixed skeletal packstone and grainstone, mudstone‐wackestone, coral packstone, coral grainstone, coralline algal grainstone, coral‐algal packstone, coralline algal packstone, Halimeda grainstone, microbialite and caliche. Microbialites, that are common in cavities of younger, post‐glacial deposits, are rare in pre‐last glacial maximum core sections, possibly due to a lack of open framework suitable for colonization by microbes. In pre‐last glacial maximum deposits of holes M0032A and M0033A (>20 kyr bp ), marine diagenetic features are dominant; samples consist largely of aragonite and high‐magnesium calcite. Holes M0042A and M0057A, which contain the oldest rocks (>169 kyr bp ), are characterized by meteoric diagenesis and samples mostly consist of low‐magnesium calcite. Holes M0042A, M0055A and M0056A (>30 kyr bp ), and a horizon in the upper part of hole M0057A, contain both marine and meteoric diagenetic features. However, only one change from marine to meteoric pore water is recorded in contrast with the changes in diagenetic environment that might be inferred from the sea‐level history. Values of stable isotopes of oxygen and carbon are consistent with these findings. Samples from holes M0032A and M0033A reflect largely positive values (δ¹⁸O: ?1 to +1‰ and δ¹³C: +1 to +4‰), whereas those from holes M0042A and M0057A are negative (δ¹⁸O: ?4 to +2‰ and δ¹³C: ?8 to +2‰). Holes M0055A and M0056A provide intermediate values, with slightly positive δ¹³C, and negative δ¹⁸O values. The type and intensity of meteroric diagenesis appears to have been controlled both by age and depth, i.e. the time available for diagenetic alteration, and reflects the relation between reef deposition and sea‐level change.     

Enhancing mobile applications by combination of GNSS and W-CDMA

The location requirements for emergency callers outside urban areas can hardly be fulfilled without global navigation satellite systems (GNSS). Consequently, interest in positioning techniques based on use of a GNSS such as GPS or on the cellular network infrastructure itself is growing rapidly in the mobile-telephone community. Moreover, the increasing demand for commercial location-based services (LBS) has driven cellular-phone and network manufacturers to focus on positioning solutions which are even more accurate than the regulatory mandates for positioning of emergency callers. One example of these upcoming LBS is our PARAMOUNT project, which aims at improving user-friendly info-mobility services for hikers and mountaineers by combining wireless communications (GMTS), satellite navigation (GNSS) and geographic information systems (GIS), based on a mobile client/server architecture. The availability of mobile phones or PDAs with combined GNSS and cellular network-based wireless communication on a high integration level is one primary demand of such LBS applications. Based on this, we will give some initial answers to the question of whether mobile handset architecture synergies exist for the combination of GNSS with wireless location in CDMA cellular wireless networks. In order to identify synergies, we will outline similarities and differences between wireless communication and satellite navigation. In this respect, we pay particular attention to the so-called RAKE receiver architecture employed in mobile CDMA cellular handsets. Our initial investigations will show that the RAKE receiver architecture, on which mobile CDMA cellular handsets are based, will most likely be the one most suitable for achieving synergies between the two positioning techniques within the same mobile handset architecture. Consequently, several receiver components could be used to handle both types of signals (navigation and communications), resulting in a reduction of manufacturing costs and in a decrease in energy consumption. Electronic Publication     

0.99999999 confidence ambiguity resolution with GPS and Galileo

In this short contribution it is demonstrated how integer carrier phase cycle ambiguity resolution will perform in near future, when the US GPS gets modernized and the European Galileo becomes operational. The capability of ambiguity resolution is analyzed in the context of precise differential positioning over short, medium and long distances. Starting from dual-frequency operation with GPS at present, particularly augmenting the number of satellites turns out to have beneficial consequences on the capability of correctly resolving the ambiguities. With a 'double' constellation, on short baselines, the confidence of the integer ambiguity solution increases to a level of 0.99999999 or beyond. Electronic Publication     

Composition and major sources of organic compounds in urban aerosols

Total suspended particles (TSP), collected during June 2002 to July 2003 in Guangzhou, a typical economically developed city in South China, were analyzed for the organic compound compositions using gas chromatography–mass spectrometry (GC/MS). Over 140 organic compounds were detected in the aerosols and grouped into different classes including n-alkanes, hopanoids, polycyclic aromatic hydrocarbons, alkanols, fatty acids, dicarboxylic acids excluding oxalic acid, polyols/polyacids, lignin products, phytosterols, phthalates and water-soluble sugars. The total amounts of the identified organic compounds including unresolved complex mixture (UCM) ranged from 3112 ng/m³ in spring to 5116 ng/m³ in winter, comprising on seasonal average 2.8% of TSP. Primary organic compounds peaked in winter although there are no heating systems burning fuels in Guangzhou. The highest saccharide levels occurred in fall due to agricultural activities. This study demonstrated that utilization of fossil fuels, biomass burning, soil resuspension and plastic/refuse burning are the major contributors to the identified organic compounds in the urban atmosphere of South China.