The distinct metamorphic stages and structural styles of the 1.94–1.86 Ga Snowbird Orogen,Northwest Territories,Canada

Palaeoproterozoic orogenesis within the Archean southeastern Rae craton is related to the initial amalgamation of Laurentia. Characterizing the accompanying tectonic processes during this time has been complicated due to polymetamorphism, which results in the obscuring of the age record of the terranes involved. To improve the knowledge of the tectonic evolution of the South Rae Craton, petrologic and structural analyses are applied in conjunction with in situ trace element chemistry, inclusion barometry, U–Pb monazite and titanite, and Lu–Hf garnet chronology. The data robustly constrain Palaeoproterozoic pressure–temperature–time paths of major deformational events along the southeastern Rae craton margin. D₁ occurred between 1.94 and 1.93 Ga in the Dodge-Snowbird domain, which included prograde burial of metasedimentary rocks, deposited at 2.2–2.0 Ga, and the development of migmatitic layering and east-southeast trending folds (S₁, F₁). Peak metamorphism is recorded in metasedimentary units at c. 1.93 Ga when rocks reached conditions of 9.0–10.5 kbar and 810–830°C. Within the Dodge-Snowbird domain, D₂ imparted north-northeast trending open folds and associated axial planar cleavage (S₂, F₂) between 1.93 and 1.90 Ga during east-west compression that appears to have been synchronous with cooling and exhumation. Later D₂ deformation, localized within the Wholdaia Lake shear zone (WLsz; S_T1), developed in the footwall of this thrust-sense structure at 1,873 ± 5 Ma at conditions of 9.5–11.0 kbar and 820–850°C. The hangingwall Dodge-Snowbird domain had already cooled to below 300°C by then, indicating a significant structural and metamorphic break across the domain's western boundary. A new phase of unroofing (D₃) involved pervasive amphibolite- to greenschist facies extensional shearing (S_T2) within the WLsz, which overprinted S_T1 foliations between 1.87 and 1.86 Ga. Continued greenschist facies shearing younger than 1.86 Ga likely ended by c. 1.83 Ga when lamprophyre dykes cut the structure, which was followed by cooling until c. 1.80 Ga. This work highlights the utility and application of multiple chronometers (zircon, monazite, titanite, garnet) along with structural and petrologic analysis that together can resolve precise orogenic cycles in polymetamorphic terranes that may otherwise be undetected. The time-resolved P–T–D histories derived here enable more robust interpretations regarding the nature and evolution of 1.9 Ga tectonism along the southeast Rae craton margin, which may be used to refine models for Laurentian terrane amalgamation.     

The limited extent of plume-lithosphere interactions during continental flood-basalt genesis: geochemical evidence from Cretaceous magmatism in southern Brazil

It has been suggested that large areas of the Earth's lithospheric mantle undergo pervasive dehydration melting during the impact of mantle plumes and the Early-Cretaceous Paraná-Etendeka continental flood-basalt (CFB) province has repeatedly been cited as evidence of this phenomenon. During the Cretaceous, however, southern Brazil experienced two phases of mafic magmatism. These igneous events occurred ～50?Ma apart and therefore represent distinct episodes of melt genesis in the underlying mantle. The first phase of magmatism, in the Early Cretaceous, included the emplacement of lava flows associated with the Paraná-Etendeka CFB province and also the intrusion of small-volume mafic alkaline magmas (e.g. Anitápolis, Jacupiranga and Juquiá) in the Dom Feliciano and Ribeira mobile belts. During the Late Cretaceous, both sodic and potassic mafic magmas were emplaced on the margin of the adjacent Luis-Alves craton and intrude the flood-basalts at Lages. On the basis of variations in incompatible trace-element concentrations (e.g. Ba?=?1000 to 2000?ppm), initial ⁸⁷Sr/⁸⁶Sr ratios (0.7048–0.7064) and ?_Nd values (?3 to ?12), we suggest that all of the Late-Cretaceous mafic potassic magmas were derived from the subcontinental lithospheric mantle (SCLM) which was metasomatically enriched during the Proterozoic. We propose that these relatively low temperature, volatile-rich, mafic melts provide direct evidence that the underlying SCLM did not melt wholesale during the previous Early-Cretaceous Paraná-Etendeka CFB event. Late-Cretaceous melting of the SCLM beneath southern Brazil may have been caused by heat conduction from either: (1) ponded ～132?Ma Tristan plume-head material; or (2) ～85?Ma Trindade plume-head material channelled southwards between the thick cratonic keels of the Amazonas and São Francisco cratons. The Late-Cretaceous magmatism appears to have been contemporaneous with uplift across southern Brazil and Paraguay; we suggest that both of these phenomena represent the widespread effects of the impact of the Trindade mantle plume on the base of the SCLM. Plate margin stresses and lithospheric extension associated with the opening of the South Atlantic may also have changed the geothermal gradient beneath southern Brazil and contributed to mantle melting.     

Annual cycle of fCO2 under sea-ice and in open water in Prydz Bay, East Antarctica

The annual cycle of dissolved nutrients and the fugacity of CO₂ (fCO₂), calculated from the concentration of dissolved inorganic carbon (DIC) and pH, was studied over a 14-month long period (December 1993 to February 1995) at a site in Prydz Bay near Davis Station, Vestfold Hills, East Antarctica. Significant spring decreases in fCO₂ began under the sea-ice in mid-October, when both water column and sea-ice algal activity resulted in the removal of nutrients and DIC and increased pH. Minimum fCO₂ (<100 μatm) and lowest nutrient and DIC concentrations occurred in December and January. The low summer fCO₂ values were clearly the result of biological activity. The seasonal depletion of dissolved nitrate reached 85% in mid-summer when chlorophyll-a concentrations exceeded 15 mg m⁻³. Oceanic uptake of carbon dioxide from the atmosphere, calculated from the fugacity difference and daily wind speeds, averaged more than 30 mmol m⁻² day⁻¹ during the summer ice-free period. This exchange replaced approximately half of the DIC consumed by biological activity. Apparent nutrient utilisation ratios (C/N/P) were close to Redfield values. In autumn fCO₂ began to rise, continuing slowly well into winter, and reaching a maximum close to modern atmospheric values between July and September. This increase can be attributed to a combination of local remineralisation of organic carbon in the water column and the steady increase in the mixing depth of the water column. At first glance, this suggests that air–sea equilibration occurred in winter despite the sea-ice cover, perhaps by horizontal circulation from regions outside the pack ice, or through openings in the ice. However, the persistent 15 to 20% undersaturation of dissolved oxygen throughout the winter suggests an alternate explanation. The late winter fCO₂ level may represent a characteristic established by global circulation, so that as a result of increasing atmospheric CO₂ concentrations, these Antarctic waters are in transition from being a winter-time source of CO₂ to the atmosphere to becoming a sink. Our fCO₂ observations emphasize the need to address seasonal variations in assessing Antarctic contributions to the oceanic control of atmospheric CO₂.     

Coral reef management in Belize: an approach through integrated coastal zone management

Belize has one of the most extensive reef ecosystems in the Western Hemisphere, comprising one of the largest barrier reefs in the world, three atolls and a complex network of inshore reefs. Until recently, the main impacts were probably from natural events such as hurricanes. However, anthropogenic threats such as sedimentation, agrochemical run-off, coastal development, tourism and overfishing are now of concern. To limit these impacts, Belize is taking the approach of integrated coastal zone management. The programme is building on the existing legislative framework and involves the development of an appropriate institutional structure to co-ordinate management activities in the coastal zone. A Coastal Zone Management Plan is being prepared, which will include many measures that will directly benefit the reefs: a zoning scheme for the coastal zone, incorporating protected areas; legislation and policy guidelines; research and monitoring programmes; education and public awareness campaigns; measures for community participation; and a financial sustainability mechanism.     

Thermo‐mechanical interaction of a large impact melt sheet with adjacent target rock,Sudbury impact structure,Canada

The 1.85 Ga Sudbury Igneous Complex (SIC) and its thermal aureole are unique on Earth with regard to unraveling the effects of a large impact melt sheet on adjacent target rocks. Notably, the formation of Footwall Breccia, lining the basal SIC, remains controversial and has been attributed to impact, cratering, and postcratering processes. Based on detailed field mapping and microstructural analysis of thermal aureole rocks, we identified three distinct zones characterized by static recrystallization, incipient melting, and crystallization textures. The temperature gradient in the thermal aureole increases toward the SIC and culminates in a zone of partial melting, which correlates spatially with the Footwall Breccia. We therefore conclude that assimilation of target rock into initially superheated impact melt and simultaneous deformation after cratering strongly contributed to breccia formation. Estimated melt fractions of the Footwall Breccia amount to 80 vol% and attest to an extreme loss in mechanical strength and, thus, high mobility of the Breccia during assimilation. Transport of highly mobile Footwall Breccia material into the overlying Sublayer Norite of the SIC and vice versa can be attributed to Raleigh–Taylor instability of both units, long‐term crater modification caused by viscous relaxation of crust underlying the Sudbury impact structure, or both.     

Interactions between groundwater and seasonally ice‐covered lakes: Using water stable isotopes and radon‐222 multilayer mass balance models

Interactions between lakes and groundwater are of increasing concern for freshwater environmental management but are often poorly characterized. Groundwater inflow to lakes, even at low rates, has proven to be a key in both lake nutrient balances and in determining lake vulnerability to pollution. Although difficult to measure using standard hydrometric methods, significant insight into groundwater–lake interactions has been acquired by studies applying geochemical tracers. However, the use of simple steady‐state, well‐mixed models, and the lack of characterization of lake spatiotemporal variability remain important sources of uncertainty, preventing the characterization of the entire lake hydrological cycle, particularly during ice‐covered periods. In this study, a small groundwater‐connected lake was monitored to determine the annual dynamics of the natural tracers, water stable isotopes and radon‐222, through the implementation of a comprehensive sampling strategy. A multilayer mass balance model was found outperform a well‐mixed, one‐layer model in terms of quantifying groundwater fluxes and their temporal evolution, as well as characterizing vertical differences. Water stable isotopes and radon‐222 were found to provide complementary information on the lake water budget. Radon‐222 has a short response time, and highlights rapid and transient increases in groundwater inflow, but requires a thorough characterization of groundwater radon‐222 activity. Water stable isotopes follow the hydrological cycle of the lake closely and highlight periods when the lake budget is dominated by evaporation versus groundwater inflow, but continuous monitoring of local meteorological parameters is required. Careful compilation of tracer evolution throughout the water column and over the entire year is also very informative. The developed models, which are suitable for detailed, site‐specific studies, allow the quantification of groundwater inflow and internal dynamics during both ice‐free and ice‐covered periods, providing an improved tool for understanding the annual water cycle of lakes.     

The formation and alteration of the Renazzo-like carbonaceous chondrites I: Implications of bulk-oxygen isotopic composition

To better understand the role of aqueous alteration on the CR chondrite parent asteroid, a whole-rock oxygen isotopic study of 20 meteorites classified as Renazzo-like carbonaceous chondrites (CR) was conducted. The CR chondrites analyzed for their oxygen isotopes were Dhofar 1432, Elephant Moraine (EET) 87770, EET 92042, EET 96259, Gao-Guenie (b), Graves Nunataks (GRA) 95229, GRA 06100, Grosvenor Mountains (GRO) 95577, GRO 03116, LaPaz Ice Field (LAP) 02342, LAP 04720, Meteorite Hills (MET) 00426, North West Africa (NWA) 801, Pecora Escarpment (PCA) 91082, Queen Alexandra Range (QUE) 94603, QUE 99177, and Yamato-793495 (Y-793495). Three of the meteorites, Asuka-881595 (A-881595), GRA 98025, and MET 01017, were found not to be CR chondrites. The remaining samples concur petrographically and with the well-established oxygen-isotope mixing line for the CR chondrites. Their position along this mixing line is controlled both by the primary oxygen-isotopic composition of their individual components and their relative degree of aqueous alteration. Combined with literature data and that of this study, we recommend the slope for the CR-mixing line to be 0.70 ± 0.04 (2σ), with a δ¹⁷O-intercept of −2.23 ± 0.14 (2σ).Thin sections of Al Rais, Shi?r 033, Renazzo, and all but 3 samples analyzed for oxygen isotopes were studied petrographically. The abundance of individual components is heterogeneous among the CR chondrites, but FeO-poor chondrules and matrix are the most abundant constituents and therefore, dominate the whole-rock isotopic composition. The potential accreted ice abundance, physico-chemical conditions of aqueous alteration (e.g. temperature and composition of the fluid) and its duration control the degree of alteration of individual CR chondrites. Combined with literature data, we suggest that LAP 02342 was exposed to lower temperature fluid during alteration than GRA 95229. With only two falls, terrestrial alteration of the CR chondrites complicates the interpretation of their whole rock isotopic composition, particularly in the most aqueously altered samples, and those with relatively higher matrix abundances. We report that QUE 99177 is the isotopically lightest whole rock CR chondrite known (δ¹⁸O = −2.29‰, δ¹⁷O = −4.08‰), possibly due to isotopically light unaltered matrix; which shows that the anhydrous component of the CR chondrites is isotopically lighter than previously thought. Although it experienced aqueous alteration, QUE 99177 provides the best approximation of the pristine CR-chondrite parent body’s oxygen-isotopic composition, before aqueous alteration took place. Using this value as a new upper limit on the anhydrous component of the CR chondrites, water/rock ratios were recalculated and found to be higher than previously thought; ratios now range from 0.281 to 1.157. We also find that, according to their oxygen isotopes, a large number of CR chondrites appear to be minimally aqueously altered; although sample heterogeneity complicates this interpretation.