The velocity structure of the lunar crust

Seismic refraction data, obtained at the Apollo 14 and 16 sites, when combined with other lunar seismic data, allow a compressional wave velocity profile of the lunar near-surface and crust to be derived. The regolith, although variable in thickness over the lunar surface, possesses surprisingly similar seismic properties. Underlying the regolith at both the Apollo 14 Fra Mauro site and the Apollo 16 Descartes site is low-velocity brecciated material or impact derived debris. Key features of the lunar seismic velocity profile are: (i) velocity increases from 100–300 m s^–1 in the upper 100 m to 4 km s^–1 at 5 km depth, (ii) a more gradual increase from 4 km s^–1 to 6 km s^–1 at 25 km depth, (iii) a discontinuity at a depth of 25 km and (iv) a constant value of 7 km s^–1 at depths from 25 km to about 60 km. The exact details of the velocity variation in the upper 5 to 10 km of the Moon cannot yet be resolved but self-compression of rock powders cannot duplicate the observed magnitude of the velocity change and the steep velocity-depth gradient. Other textural or compositional changes must be important in the upper 5 km of the Moon. The only serious candidates for the lower lunar crust are anorthositic or gabbroic rocks.Paper dedicated to Professor Harold C. Urey on the occasion of his 80th birthday on 29 April, 1973.     

Large-scale Vertical Momentum,Kinetic Energy and Moisture Fluxes in the Antarctic Sea-ice Region

There are very strong thermal gradients between the Antarctic continent and the sea-ice zone, and between that zone and the ocean to the north. As a result of these contrasts the sea-ice domain is one of strong cyclogenesis and high cyclone frequency. In this study we explore many aspects of that cyclonic behaviour and investigate the manner in which these systems influence, and are influenced by, the sea ice. Using the NCEP-DOE re-analyses (1979–2002) we have determined variables that are proportional to the mean of the wind stress and the mean rate at which mechanical energy is imparted to the surface. Using two decompositions of the wind field we have obtained estimates of how much of these fluxes are contributed to by the transient eddies. We find these to be significant over the sea ice and the ocean to the north, particularly when a new decomposition is used. The presence of frequent and vigorous cyclones is a central factor that determines the positive mean freshwater flux over the sea-ice zone in all seasons. This transfer to the ocean is smallest in summer (0.49 mm day⁻¹) and assumes a maximum of 1.27 mm day⁻¹ in winter.     

Regional regression models for hydro‐climate change impact assessment

Hydro‐climatic impacts in water resources systems are typically assessed by forcing a hydrologic model with outputs from general circulation models (GCMs) or regional climate models. The challenges of this approach include maintaining a consistent energy budget between climate and hydrologic models and also properly calibrating and verifying the hydrologic models. Subjective choices of loss, flow routing, snowmelt and evapotranspiration computation methods also increase watershed modelling uncertainty and thus complicate impact assessment. An alternative approach, particularly appealing for ungauged basins or locations where record lengths are short, is to predict selected streamflow quantiles directly from meteorological variable output from climate models using regional regression models that also include physical basin characteristics. In this study, regional regression models are developed for the western Great Lakes states using ordinary least squares and weighted least squares techniques applied to selected Great Lakes watersheds. Model inputs include readily available downscaled GCM outputs from the Coupled Model Intercomparison Project Phase 3. The model results provide insights to potential model weaknesses, including comparatively low runoff predictions from continuous simulation models that estimate potential evapotranspiration using temperature proxy information and comparatively high runoff projections from regression models that do not include temperature as an explanatory variable. Copyright © 2014 John Wiley & Sons, Ltd.     

Late Ordovician island‐arc volcanic rocks,northern Capertee Zone,Lachlan Fold Belt,New South Wales

The Cape Hoskins volcanoes form part of the Quaternary volcanic island arc that extends from Rabaul in the east to the Schouten Islands in the west, and they overlie the northerly dipping New Britain Benioff Zone. The products of the volcanoes range in composition from basalt to rhyolite, and are normative in quartz and hypersthene. They contain phenocrysts of plagioclase and subordinate augite, hypersthene, and in most samples iron‐titanium oxides; some samples also contain olivine or quartz or both, and some pumice contains hornblende and, rarely, biotite.

Chemical analyses of 29 volcanic rocks are presented; 22 were also analysed for 17 minor elements — Rb, Ba, Sr, Pb, Zn, Cu, Zr, Y, Ni, Co, Sc, Cr, V, Ga, B, U, and Th.

Chemically the rocks have many of the characteristics of the ‘island arc tholeiitic series’, but do not show a pronounced relative enrichment in iron and appear to be relatively enriched in Sr. Compared with volcanic rocks from the northern part of the Willaumez Peninsula, they are lower in K (but not Na), Ti, Rb, Ba, Zr, Pb, Th, Ni, and probably also V, Cu, and Zn: these differences are attributed to the greater depth of the Benioff Zone beneath the Willaumez Peninsula. The more basic of the Cape Hoskins rocks are similar in most respects to lavas of comparable composition from Ulawun volcano to the east.     

Bulk flow and shear moments of the SFI++ survey

We find the nine bulk flow and shear moments from the SFI++ survey, as well as for subsamples of group and field galaxies. We constrain the velocity power spectrum shape parameter Γ in linear theory using these moments. A likelihood function for Γ was found after marginalizing over the power spectrum amplitude  σ₈Ω^0.6_m  using constraints obtained from comparisons between redshift surveys and peculiar velocity data. We have estimated the velocity noise  σ_*  from the data since without it our results may be biased. We also performed a statistical analysis of the difference between the field and group catalogues and found that the results from each reflect the same underlying large-scale flows. We found that we can constrain the power spectrum shape parameter to be  Γ= 0.15^+0.18_−0.08  for the groups catalogue and  Γ= 0.09^+0.04_−0.04  for the field galaxy catalogue in fair agreement with the value from Wilkinson Microwave Anisotropy Probe .     

Liquid composition-dependence of calcium isotope fractionation during diffusion in molten silicates

Liquid phase diffusion experiments were carried out to determine whether diffusive isotopic fractionation of a major chemical element (Ca) varies with chemical composition in high-temperature molten silicates. The objective was to determine how differences in silicate liquid structure, such as the ratio of bridging to non-bridging oxygen atoms, as well as bulk transport properties such as viscosity, relate to isotope discrimination during diffusion. This information, in turn, may relate to the lifetimes and sizes of multi-atom structures in the liquid. Diffusion couples consisting of juxtaposed natural mafic and felsic liquids were held at T = 1450 °C and P = 1.0 GPa for durations of 12-24 h in a standard piston-cylinder assembly. Experiments were done using different mafic endmember compositions (two tholeiitic basalts and a ugandite) and a single rhyolite composition. Major-element diffusion profiles and Ca isotope profiles were measured on the recovered quenched glasses. The starting materials were isotopically indistinguishable, but ⁴⁴Ca/⁴⁰Ca variations of ca. 5‰ arose due to a mass dependence of the Ca diffusion coefficients. Results indicate that the mass dependence of Ca diffusion coefficients varies with the magnitude and direction of aluminum gradients and the viscosity of the liquid. Some Ca fractionations result mainly from Al gradients.A simplified multicomponent diffusion model was used to model the experimental results. The model allows for diffusion of Ca in response to gradients in the concentrations of both CaO as well as Al₂O₃, and the model results are consistent with the inferred existence of at least two distinct species of Ca. The magnitude of isotopic discrimination during diffusion also appears to be stronger on the rhyolite versus the basalt/ugandite side of diffusion couples. The results can largely be accounted for by an adaptation of the model of Dingwell (1990), whereby in high silica liquids, Ca diffuses largely by site hopping through a quasi-stationary aluminosilicate matrix, producing strong isotopic effects because the Ca diffusion is not strongly correlated with the movement of the framework atoms. In low-silica liquids, Ca diffusion is correlated with the movement of the other components and there is less mass discrimination. Combining our Ca results with Ca, Mg, and Li data from previous studies, we show that this model can explain most of the cation- and composition-dependence of diffusive isotopic fractionations observed thus far. A key parameter controlling isotopic discrimination is the ratio of the elemental (Ca, Mg, Li) diffusivity to the Eyring (or Si) diffusivity. However, all experiments done so far also exhibit isotopic features that are not yet fully explained; some of these may relate to small temperature gradients in the capsules, or to more complex coupling effects that are not captured in simplified diffusion models.     

Aggregation of montmorillonite and organic matter in aqueous media containing artificial seawater

Background  

The dispersion-aggregation behaviors of suspended colloids in rivers and estuaries are affected by the compositions of suspended materials (i.e., clay minerals vs. organic macromolecules) and salinity. Laboratory experiments were conducted to investigate the dispersion and aggregation mechanisms of suspended particles under simulated river and estuarine conditions. The average hydrodynamic diameters of suspended particles (representing degree of aggregation) and zeta potential (representing the electrokinetic properties of suspended colloids and aggregates) were determined for systems containing suspended montmorillonite, humic acid, and/or chitin at the circumneutral pH over a range of salinity (0 – 7.2 psu).