硫酸侵蚀碳酸盐岩对长江河水DIC循环的影响

对长江及其主要支流河水水化学和溶解无机碳（DIC）同位素组成（δ13GDIC）进行了研究。河水阳离子组成以Ca^2＋、Mg^2＋为主,阴离子以HCO3-、SO4^2-为主,水化学组成主要受流域碳酸盐岩矿物的化学侵蚀控制。DIC含量为0．3～2．5mmol／L,从上游到河口逐渐降低。δ13CDIC值为-12．0‰-3．4‰,与DIC含量具有相似的变化趋势。H2CO3溶解碳酸盐岩是控制河水DIC来源及其占δGDIC组成的主要机制。H2SO4溶解碳酸盐岩加剧了流域碳酸盐岩的化学侵蚀,一方面导致了河水的DIC含量增加,另一方面也使河水的δ13GDIC值升高。     

Evaluation of one-dimensional in situ leaching processes

A methodology to characterizing processes of in situ leaching is developed to investigate various parameters that may affect the recovery of a valuable mineral and assure a successful application of the in situ leaching technology. The governing equations of in situ leaching processes for the one-dimensional case are solved both analytically and numerically for both the consumption rate of a lixiviant and the production rate of a target mineral. A numerical simulator, which is developed to evaluate coupled effects among leaching kinetics, solution flow and transport of the dissolved mineral species in saturated ore deposits, is validated against the steady-state solutions and applied to investigate the transient effects of various parameters on the mineral recovery. Results from the evaluation indicate that there exists an optimal flow velocity range of leach solution for the effective leaching of a particular ore deposit. The determination of this optimal leaching velocity may become a key to the design of a real in situ leach mine. Results of the parameter sensitivity study illustrate the relative importance of other parameters such as porosity, ore grade, and reaction rate. Copyright © 1999 John Wiley & Sons, Ltd.     

Authigenic carbonates in methane seeps from the Norwegian sea: Mineralogy, geochemistry, and genesis

Authigenic carbonates in the caldera of an Arctic (72°N) submarine mud volcano with active CH₄bearing fluid discharge are formed at the bottom surface during anaerobic microbial methane oxidation. The microbial community consists of specific methane-producing bacteria, which act as methanetrophic ones in conditions of excess methane, and sulfate reducers developing on hydrogen, which is an intermediate product of microbial CH₄ oxidation. Isotopically light carbon (δ¹³C_av =−28.9%0) of carbon dioxide produced during CH₄ oxidation is the main carbonate carbon source. Heavy oxygen isotope ratio (δ¹⁸O_av = 5%0) in carbonates is inherited from seawater sulfate. A rapid sulfate reduction (up to 12 mg S dm⁻³ day⁻¹) results in total exhausting of sulfate ion in the upper sediment layer (10 cm). Because of this, carbonates can only be formed in surface sediments near the water-bottom interface. Authigenic carbonates occurring within sediments occur do notin situ. Salinity, as well as CO ₃ ²⁻ /Ca and Mg/Ca ratios, correspond to the field of nonmagnesian calcium carbonate precipitation. Calcite is the dominant carbonate mineral in the methane seep caldera, where it occurs in the paragenetic association with barite. The radiocarbon age of carbonates is about 10000 yr.     

Detailed mineralogical-geochemical study of a large spinel Lherzolite xenolith in alkali basalt of Shavaryn Tsaram paleovolcano,Mongolia

Mineralogical-geochemical data obtained on a large xenolith of spinel lherzolite from basanites of Shavaryn Tsaram volcano (Middle Pleistocene) provide evidence that the xenolith was affected by heat and fluid that came from the basalt melt and induced geochemical heterogeneity of the xenolith. Olivine crystals from the central portion of the xenolith contain much more CaO than this mineral from the peripheral zones of the xenolith as well as in xenocrystals of the host basalts. The large xenolith was unevenly annealed by the host basalt melt, and this predetermined the heterogeneous diffusion-controlled “purification” of olivine crystals from their CaO admixture. The xenolith is heterogeneously enriched in LREE and some trace elements (Zr, Hf, Nb, Th, and U), and their distribution demonstrates unclearly pronounced concentric zoning: these elements enriched the outer portions of the xenolith. The enrichment of the xenolith in LREE and other mobile trace elements is explained by their occurrence not only as structurally bound (isomorphic) components in minerals but also in the form of nonstructural admixtures (contaminant), as minute grains of compounds hosted in the interstitial space and tiny cracks cutting mineral grains. The enrichment of the xenolith in these admixtures proceeded via their infiltration-controlled introduction with fluid from the basalt along minute cracks.     

Kyanite–sillimanite metamorphism of the Precambrian complexes,Transangarian region of the Yenisei Ridge

Four Precambrian metamorphic complexes in the vicinity of regional faults in the Transangarian region of the Yenisei Ridge were examined. Based on geothermobarometry and P-T path calculations, our geological and petrological studies showed that the Neoproterozoic medium-pressure metamorphism of the kyanite–sillimanite type overprinted regionally metamorphosed low-pressure andalusite-bearing rocks at about 850 Ma. A positive correlation between rock ages and P-T estimates for the kyanite-sillimanite metamorphism provide evidence of the regional structural and tectonic heterogeneity. The medium-pressure metamorphism was characterized by (1) the development of deformational structures and textures, and kyanite-bearing blastocataclasites (blastomylonites) with sillimanite, garnet, and staurolite after andalusite-bearing regional metamorphic rocks; (2) insignificant apparent thickness of the zone of medium-pressure zonal metamorphism (from 2.5 to 7 km), which was localized in the vicinity of the overthrusts; (3) a low metamorphic field gradient during metamorphism (from 1–7 to 12 °C/km); and (4) a gradual increase in lithostatic pressure towards the thrust faults. These specific features are typical of collisional metamorphism during overthrusting of continental blocks and are evidence for near-isothermal loading. This event was justified within the framework of the crustal tectonic thickening model via rapid overthrusting and subsequent rapid uplifting and erosion. The results obtained allowed us to consider medium-pressure kyanite-bearing metapelites as a product of collision metamorphism, formed either by unidirectional thrusting of rock blocks from Siberian craton onto the Yenisei Ridge in the zones of regional faults (Angara, Mayakon, and Chapa areas) or by opposite movements in the zone of splay faults of higher orders (Garevka area).     

VLA observations of class I methanol masers in the region of low-mass star formation L1157

We present the results of VLA observations of a maser candidate in the low-mass star formation region L1157 in the 7₀-6₁ A ⁺ transition at 44 GHz. The line is emitted by a compact, undoubtedly maser source associated with clump B0a, which is seen in maps of L1157 in thermal lines of methanol and other molecules. A much weaker compact source is associated with clump B1a, which is brighter than B0a in thermal methanol lines. The newly detected masers may form in thin layers of turbulent post-shock gas. In this case, the maser emission may be beamed, so that only an observer located in or near the planes of the layers can observe strong masers. On the other hand, the maser lines are double with a “red” asymmetry, indicating that the masers may form in collapsing clumps. A detailed analysis of collapsing-cloud maser models and their applicability to the masers in L1157 will be developed in subsequent papers.     

Crystallization Orders and Phase Chemistry of Glassy Lavas from the Pillow Sequences, Troodos Ophiolite, Cyprus

Three genetically unrelated magma suites are found in the extrusivesequences of the Troodos ophiolite, Cyprus. A stratigraphicallylower pillow lava suite contains andesite and dacite glassesand shows the crystallization order plagioclase; augite, orthopyroxene;titanomagnetite (with the pyroxenes appearing almost simultaneously).These lavas can in part be correlated chemically and mineralogicallywith the sheeted dikes and the upper part of the gabbro complexof the ophiolite. The second magma suite is represented in astratigraphically upper extrusive suite and contains basalticandesite and andesite glasses with the crystallizaton orderchromite; olivine; Ca-rich pyroxene; plagioclase. This magmasuite can be correlated chemically and mineralogically withparts of the ophiolitic ultramafic and mafic cumulate sequence,which has the crystallization order olivine; Ca-rich pyroxene;orthopyroxene; plagioclase. The third magma suite is representedby basaltic andesite lavas along the Arakapas fault zone andshows a boninitic crystallization order olivine; orthopyroxene;Ca-rich pyroxene; plagioclase. One-atmosphere, anhydrous phaseequilibria experiments on a lava from the second suite indicateplagioclase crystallization from 1225?C, pigeonite from 1200?C,and augite from 1165?C. These experimental data contrast withthe crystallization order suggested by the lavas and the associatedcumulates. The observed crystallization orders and the presenceof magmatic water in the fresh glasses of all suites are consistentwith evolution under relatively high partial water pressures.In particular, high P_H2O (1–3 kb) can explain the lateappearances of plagioclase and Ca-poor pyroxene in the majorityof the basaltic andesite lavas as the effects of suppressedcrystallization temperatures and shifting of cotectic relations.The detailed crystallization orders are probably controlledby relatively minor differences in the normative compositionsof the parental magmas. The basaltic andesite lavas are likelyto reach augite saturation before Ca-poor pyroxene saturation,whereas the Arakapas fault zone lavas, which have relativelyless normative diopside and more quartz, reached the Ca-poorpyroxene-olivine reaction surface and crystallized Ca-poor pyroxeneafter olivine.