Bioconcentration factors for petroleum hydrocarbons, PAHs, LABs and biogenic hydrocarbons in the blue mussel

Bioconcentration factors (K_bc) for petroleum hydrocarbons, PAHs, LABs and biogenic hydrocarbons in Mytilus edulis were measured in field experiments using time-integrating water samplers. Seven deployments at five sites gave lipid weight K_bcs for total hydrocarbons ranging from 0.99 × 10⁶ to 3.1 × 10⁶ (mean 1.6 × 10⁶)—a narrower range than has been obtained previously. Bioconcentration factors for the PAHs were similar to those for total hydrocarbons where the major hydrocarbon source was oil. However, at other sites the factors for PAHs were an order of magnitude lower than those for petroleum and for hydrocarbons originating from algae. Compositional profiles for the linear alkyl benzenes (LABs) suggested that these compounds were assimilated primarily from the dissolved phase, despite their greater abundance on particles.     

Effect of spatial resolution on regionalization of hydrological model parameters

Lack of availability of historical data series is one of the major hindrances in hydrological modelling. Regionalization of hydrological model parameters is one of the solutions to obtain the parameters for ungauged basins. Recently, lots of methodologies have been developed. They can be categorized as model calibration then fitting regression between model parameters and catchments characteristics, using some kind of transfer function. The aim of this study was to compare different regionalization methods as well as to look how the spatial resolution affects regionalization. In this study, a modified Lipschitz and monotony condition was used for regionalization. To identify the effect of the model resolution, the parameters of a distributed and semi‐distributed version of the Hydrologiska Byråns Vattenbalansavdelning (HBV) model were regionalized. The study was conducted at the upper Neckar catchment of southwest Germany. It has been found that the combination of Lipschitz and monotony condition has performed reasonably. It has been seen that the distributed model structure has outperformed the semi‐distributed model structure. It shows under present data conditions that higher model resolution can describe processes of ungauged basins reasonably. Copyright © 2011 John Wiley & Sons, Ltd.     

Sm–Nd and Sr isotope systematics of scheelite from the giant Au(–W) deposit Muruntau (Uzbekistan): implications for the age and sources of Au mineralization

The application of the Sm-Nd isotope system of scheelite to dating of low-sulfide, quartz-vein hosted Au mineralization is still under discussion. In the present work, new Sm-Nd and Rb-Sr data for scheelite from the giant Muruntau/Myutenbai Au deposit (Kyzylkum, Western Uzbekistan) are discussed. Based on the geological relationship, mineralogical properties, and trace element characteristics, two types of scheelite can be distinguished within the deposit. The first one is represented by early bluish luminescent and weakly coloured scheelite (generation 1) found within strongly deformed flat quartz veins. The apparent isochron defined by this scheelite (351ᆪ Ma) is interpreted as a mixing line. Typically brownish to orange and yellowish luminescent scheelite from steeply dipping veins (generation 2) defines a Sm-Nd isochron age of 279ᆦ Ma ()_Nd=-9.5ǂ.3; MSWD: 1.5). No evidence for mixing or disturbance by late alteration were found for these scheelites. This Sm-Nd isochron age agrees with the Rb-Sr and K-Ar age range for wall rock alteration in this deposit reported previously. The age of 280 Ma is interpreted to date the high-grade ore formation in the Muruntau deposit. There are currently no reliable age data available on the magmatic events in the Muruntau region. Probably, there is some overlap in time of the Hercynian gold deposition with the intrusion of lamprophyric dykes. The Nd and Sr isotopic signatures of scheelite define the wall rocks (mainly metasiltstones and metasandstones) as the most probable sources for these elements in scheelite.     

The kinematic dynamo action of spiralling convective flows

We consider the kinematic production of magnetic fields in a sphere by velocity fields dominated by differential rotation and spiralling convective cells. The high magnetic Reynolds number limit of Braginsky (1964) is considered and formulae are derived allowing an α-effect parametrization of such flows to be easily calculated. This permits an axisymmetric system to be investigated in parallel with the direct 3-D numerical computations. Good agreement between the asymptotic and 3-D calculations is found. The 'spiralling' property typical of convective motion in rotating spheres is important in terms of dynamo action; the differential rotation coexisting with this feature is also vital. Indeed, it is the presence of both features which allows the analysis of Braginsky to be employed. With flows approximating the columnar form anticipated for rapidly rotating convection, dynamo action is relatively easily achieved for all azimuthal wavenumbers; modes of differing wavenumbers interact almost by a simple superposition. With flows of more complex latitudinal form, the mutual interactions between modes become more complicated. For columnar-type flows, dipole magnetic fields are favoured when the sense of outward spiralling is prograde and the zonal flow is eastwards, as is physically preferred.     

Recherches complémentaires sur le bases du calculateur météorologique «Temp»

Résumé La formule de base, traduisant une propriété analytique d'une classe très générale de fonctions, est un corollaire du théorème fondamental démontré dans un mémoire précédent, d'après lequel, étant donnés une fonction continue,p(, ,t) des points (, ) d'une surface régulière fermée et du temps et le champ d'un vecteur vitesse de transfert ou d'advection tangent à et ayant des lignes de flux fermées et régulières, il existe un opérateur spatial, linéaire, non singulierA tel que la fonctionA(p+Const.) soit purement advective par rapport a (sans creusement ni comblement). Ce théorème peut être exprimé par l'équation , où est un opérateur spatial, linéaire et non singulier, fonction deA.La détermination de peut être faite, soit en comparant deux formes différentes de la solution générale de l'équation en , soit en utilisant un raisonnement a priori très simple. On arrive ainsi au résultat pour un certain scalaireu(, ).Dans le cas oùp(, ,t) est la perturbation de la pression sur la surface du géoïde l'équation résulte aussi, comme nous l'avons montré dans le mémoire précédent, de notre théorie hydrodynamique des perturbations. On montre ici que la même équation peut encore être déduite de l'équation de continuité associée à la condition d'équilibre quasi statique selon la verticale.Comme applications de la formule de base (solution générale de l'équation enM), on étudie les problèmes suivants: 1^o creusement et comblement en général; 2^o creusement et comblement des centres et des cols; 3^o mouvement des centres et des cols; 4^o instabilité d'un champ moyen; 5^o propriétés spatiales des champsp(, ,t) et des vecteurs d'advection analytiques.Après une discussion des erreurs de la prévision d'un champp(, ,t) par la formule de base, du fait des erreurs des observations et du fonctionnement du calculateur, on examine quelques particularités du transfert ou advection d'un champf ₀(, ) par le vecteur . Enfin, le dernier chapitre du mémoire donne des éclaircissements complémentaires sur la structure du calculateur électronique «Temp» (qui effectue automatiquement les opérations mathématiques de la formule de base) et expose l'état actuel de sa construction.

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Summary The basic formula, expressing an analytical property of a very general class of functions, is a corollary of the fundamental theorem, proved in a previous paper, according to which, given a functionp(, ,t) of the points (, ) of a closed regular surface and of the time, and a transfer or advection velocity vector tangent to and having regular closed streamlines, there is a spatial, linear, non singular operatorA such thatA(p+const.) is a purely advective function in respect to (no deepening). This theorem can be expressed by the equation where is a spatial, linear, non singular operator depending onA.The determination of can be attained, either by the comparison of two different forms of the general solution of the -equation, or by a simple a priori reasonning. The conclusion is thus reached that for a certain scalaru(, ).Whenp(, ,t) is the pressure perturbation at sea level, it was shown, in the preceding paper, that the equation can also be derived from our hydrodynamical perturbation theory. We now show that for this particular case, the same equation is also a consequence of the equation of continuity together with the condition of quasi statical vertical equilibrium.The following problems are then analysed by means of the basic formula: 1^o deepening and filling in general; 2^o deepening and filling of the centres and cols; 3^o motion of the centres and cols; 4^o instability of a mean field; 5^o spatial properties of the analytical fields and advection vectors .The errors in the forecast of a field,p(, ,t) by means of the basic formula, due to the observational and computational errors, are discussed, and some peculiarities of the transfer or advection of a fieldf ₀(, ) by are examined. Finally, complementary points are disclosed on the structure of the electronic computer «Temp» which performs automatically the mathematical operations of the basic formula, and a brief report is given of the present state of its construction.

     

ON THE BREMMER SERIES DECOMPOSITION: EQUIVALENCE BETWEEN TWO DIFFERENT APPROACHES*

A Bremmer Series decomposition of the solution y(t) to the lossless wave equation in layered media is where the y_j(t) are physically meaningful constituents (i.e., y₁(t) are primaries, y₂(t) are secondaries, etc.). This paper reviews Mendel's state space models for generating the constituents; reviews Bremmer's integral equation models for generating the constituents; and demonstrates how Mendel's state space models can be obtained by a careful decomposition of Bremmer's integral equation models. It shows that Mendel's equations can be viewed as approximate numerical solutions of Bremmer's integral equations. In a lossless homogeneous medium, the approximations become exact.     

Structural controls of lode-gold mineralization by mafic dykes in late-Paleozoic granitoids of the Kochkar district, southern Urals, Russia

The Kochkar gold district in the East Uralian Zone of the southern Urals is located in late-Paleozoic granite gneisses of the Plast massif. Gold mineralization is associated with tabular quartz lodes that are preferentially developed along the margins of easterly trending mafic dykes. Fabric development indicates that dykes had a profound influence on the development of shear zones in granitoids. ENE- and SE-trending dykes have been reactivated as dextral and sinistral oblique strike-slip shear zones, respectively, forming a set of approximately conjugate shear zones related to the Permian, regional-scale E-W directed shortening. Dyke-shear zone relationships in the Plast massif are the result of strain refraction due to the presence of biotite-rich, incompetent dykes in more competent granite-gneisses. Deformation and the formation of associated gold-quartz lodes occurred close to peak-metamorphic, upper-greenschist to lower-amphibolite facies conditions. Strain refraction has resulted in partitioning of the bulk strain into a component of non-coaxial mainly ductile shear in mafic dykes, and a component of layer-normal pure shear in surrounding granitoids where deformation was brittle-ductile. Brittle fracturing in granitoids has resulted in the formation of fracture permeabilities adjacent to sheared dykes, that together with the layer-normal dilational component, promoted the access of mineralizing fluids. Both ore-controlling dykes and gold-quartz lodes were subsequently overprinted by lower greenschist-facies, mainly brittle fault zones and associated hydrothermal alteration that post-date gold mineralization. Received: 15 October 1998 / Accepted: 18 August 1999     

Rock albedo and monitoring of thermal conditions in respect of weathering: some expected and some unexpected results

Broadly speaking, there is, at least within geomorphic circles, a general acceptance that rocks with low albedos will warm both faster and to higher temperatures than rocks with high albedos, reflectivity influencing radiative warming. Upon this foundation are built notions of weathering in respect of the resulting thermal differences, both at the grain scale and at the scale of rock masses. Here, a series of paving bricks painted in 20 per cent reflectivity intervals from black through to white were used to monitor albedo‐influenced temperatures at a site in northern Canada in an attempt to test this premise. Temperatures were collected, for five months, for the rock surface and the base of the rock, the blocks being set within a mass of local sediment. Resulting thermal data did indeed show that the dark bricks were warmer than the white but only when their temperatures were equal to or cooler than the air temperature. As brick temperature exceeded that of the air, so the dark and light bricks moved to parity; indeed, the white bricks frequently became warmer than the dark. It is argued that this ‘negating’ of the albedo influence on heating is a result of the necessity of the bricks, both white and black, to convect heat away to the surrounding cooler air; the darker brick, being hotter, initially convects faster than the white as a product of the temperature difference between the two media. Thus, where the bricks become significantly hotter than the air, they lose energy to that air and so their respective temperatures become closer, the albedo influence being superceded by the requirement to equilibrate with the surrounding air. It is argued that this finding will have importance to our understanding of weathering in general and to our perceptions of weathering differences between different lithologies. Copyright © 2005 John Wiley & Sons, Ltd.