Metamorphic veining and mass transfer in a chemically closed system: a case study in Alpine metabauxites (western Vanoise)

In western Vanoise (French Alps), karstic pockets of Triassic‐to‐Jurassic metabauxites embedded in carbonate rocks and containing several generations of metamorphic veins were studied. During blueschist facies metamorphism, a cumulative amount of ～13 vol% of water is inferred to have been produced locally by successive dehydration reactions, and part of this fluid remained in the bauxitic lenses during most of the metamorphic cycle. Field and geochemical evidence show that these rocks have been isolated from large‐scale fluid flow (closed‐system behaviour). It is proposed that the internally derived fluid has promoted the opening of fluid‐filled open spaces (as attested by the euhedral habits of vein minerals) and served as medium for mass transfer from rock to vein. Indeed, the vein infill is obviously the result of chemical interactions, at the millimetre‐to‐centimetre scale, between the rock minerals and the locally produced aqueous fluid. Two vein types can be distinguished based on mineralogical and textural features: (i) some veins are filled with newly formed products of either prograde (chloritoid) or retrograde (chlorite) metamorphic reactions; in this case, fluid‐filled open spaces seem to offer energetically favourable nucleation/growth sites; (ii) the second vein type is infilled with cookeite or pyrophyllite, that were present in the host rock prior to the vein formation. In this closed chemical system, the components for the vein infill minerals have been transferred from rock to vein through the fluid, in a dissolution–transport–precipitation process, possibly stress‐assisted. These different vein generations all contain Al‐rich mineral infills, suggesting that Al was a mobile element (cm scale) during metamorphism. In these HP rocks, fluid flow may have been restricted, and if so mass transfer occurred by diffusion in an almost stagnant fluid. Metamorphic veins can be seen as witnesses of fluid and mass redistribution that partly accommodate the rock deformation (lateral segregation).     

Investigation of Failure Mechanisms and Migration of Organic Chemicals at Wilsonville, Illinois

Ground water contamination was discovered in 1981 in a monitoring well at the Earthline disposal facility near Wilsonville, Illinois. Organic chemicals had migrated at a rate 100 to 1000 times greater than predicted when the site received its permit to operate in 1978. Postulated failure mechanisms included migration through previously unmapped permeable zones, subsidence of an underground mine, organic-chemical and clay-mineral interactions, acid-mine drainage and clay interactions, trench-cover settlement, and erosion.
In this investigation, the Illinois State Geological Survey found the primary reason for the rapid migration: the presence of previously undetermined fractures and joints in glacial till. The inaccurate predictions of hydraulic conductivity were based on laboratory-determined values that did not adequately measure the effects of fractures and joints on the transit time calculations. Field-measured hydraulic conductivity values were generally 10 to 1000 times greater than their laboratory-measured counterparts, thus largely accounting for the discrepancy between predicted and actual migration rates in the transit time calculations. The problem was compounded, however, by the burial of liquid wastes and by trench covers that allowed excess surface runoff to enter the trenches. Organic-chemical and clay-mineral interactions may also have exacerbated the problem in areas where liquid organic wastes were buried.     

Estimating climate changes in the northern hemisphere in the 21st century under alternative scenarios of anthropogenic forcing

Possible changes in the climate characteristics of the Northern Hemisphere in the 21st century are estimated using a climate model (developed at the Obukhov Institute of Atmospheric Physics (OIAP), Russian Academy of Sciences) under different scenarios of variations in the atmospheric contents of greenhouse gases and aerosols, including those formed at the OIAP on the basis of SRES emission scenarios (group I) and scenarios (group II) developed at the Moscow Power Engineering Institute (MPEI). Over the 21st century, the global annual mean warming at the surface amounts to 1.2?C2.6°C under scenarios I and 0.9?C1.2°C under scenarios II. For all scenarios II, starting from the 2060s, a decrease is observed in the rate of increase in the global mean annual near-surface air temperature. The spatial structures of variations in the mean annual near-surface air temperature in the 21st century, which have been obtained for both groups of scenarios (with smaller absolute values for scenarios II), are similar. Under scenarios I, within the extratropical latitudes, the mean annual surface air temperature increases by 3?C7°C in North America and by 3?C5°C in Eurasia in the 21st century. Under scenarios II, the near-surface air temperature increases by 2?C4°C in North America and by 2?C3°C in Eurasia. An increase in the total amount of precipitation by the end of the 21st century is noted for both groups of scenarios; the most significant increase in the precipitation rate is noted for the land of the Northern Hemisphere. By the late 21st century, the total area of the near-surface permafrost soils of the land of the Northern Hemisphere decreases to 3.9?C9.5 10⁶ km² for scenarios I and 9.7?C11.0 × 10⁶ km² for scenarios II. The decrease in the area of near-surface permafrost soils by 2091?C2100 (as compared to 2001?C2010) amounts to approximately 65% for scenarios I and 40% for scenarios II. By the end of the 21st century, in regions of eastern Siberia, in which near-surface permafrost soils are preserved, the characteristic depths of seasonal thawing amount to 0.5?C2.5 m for scenarios I and 1?C2 m for scenarios II. In western Siberia, the depth of seasonal thawing amounts to 1?C2 m under both scenarios I and II.     

Sea surface wind and Sea ice in the Barents Sea using microwave sensing data from Meteor-M N1 and GCOM-W1 satellites in January–March 2013

Application of satellite passive microwave sensing for the retrieval of key climatic parameters in the Barents Sea is considered. Fields of surface wind, atmosphere water vapor content and cloud liquid water content were found from MTVZA-GY radiometer onboard the Meteor-M N1 satellite and AMSR2 onboard the GCOM-W1 satellite with the use of original algorithms. The fields are in a good agreement with the ancillary remote and in situ measurements, which follows from the analysis of the evolution of the extra tropical and polar cyclones and cold air outbreaks with storm winds leading to intense air-sea interaction, and the formation and drift of sea ice.     

Holocene environmental change and the accumulation–erosion balance of sheltered river-mouth sediments, Göteborg, SW Sweden

Holocene sedimentological change was investigated in 15 sediment piston cores (250 cm long) from the mouth of the Göta älv River, outside of Göteborg, which is sheltered by an archipelago. The main objective was to interpret recent, natural and human-induced influences upon the accumulation–erosion balance and the sedimentary environment from Holocene sediment units. The five main units are: consolidated glaciomarine clay (Facies gC) lowermost, consolidated estuarine clay (Facies dC), soft sub-recent sediment (Facies omC and Facies C) uppermost and dumped sediment (Facies D) in some parts of the study area. The sediment facies are divided by two major hiatuses: (a) the early Holocene hiatus between Facies gC and dC involves a time gap of at least 7000 years, ending at ca. 4000 BP and (b) the late Holocene hiatus between the consolidated clays (Facies gC and dC) and Facies omC spans 1000 years and ends ca. 50 BP (i.e. 100 years ago). Both hiatuses probably relate to the effects of isostatic land uplift. Surface sediments consist mainly of an organic-matter-rich clay facies, suggesting changes in the trophic state of the estuary during the last 100 years. Together with human-induced increased river erosion and loss of accommodation space in the estuary, this caused the onset of sedimentation in the estuary. The recent sediments are contaminated with heavy metals (Cu, Zn, Pb, Hg), with highest concentrations in the lower part of Facies omC.     

Land-derived pollutant hydrocarbons

Evidence is given for the derivation of oil pollution from on-shore sources and for a possible relation between its concentration in estuarine sediment and in the lipids of the sediment biomass.     

Petrological and geochemical characteristics of Plio-Pleistocene Volcanics from Ponza Island (Tyrrhenian Sea, Italy)

Summary Volcanic rocks on Ponza Island (Tyrrhenian Sea, central Italy) consist of Pliocene submarine rhyolites and Pleistocene subaerial trachyte and comendite lavas. Chemical variations and the homogeneous Sr and Nd isotopic signatures within the analyzed Pliocene rocks are ascribed to crystal fractionation. The absolute isotopic values, however, indicate the important role of a crustal component in the origin of these magmas. The very high-silica rocks were probably derived from a superimposed mechanism which may have been connected to the ascent of hydrothermal magmatic fluids. Compositional and ⁸⁷Sr/⁸⁶Sr variations at constant ¹⁴³Nd/¹⁴⁴Nd values in the Pleistocene rocks are likely due to fractionation of the observed phenocryst assemblage, possibly coupled with minor crustal interaction. These processes, however, cannot account for the extreme enrichment of many incompatible trace elements in the comendites. Some evidence suggests the influence of a halogen- and/or CO₂-rich volatile phase. Received February 17, 2000; revised version accepted November 29, 2000     

Magnetization properties of intrusive/extrusive rocks from East Maio (Republic of Cape Verde) and their geological implications

Summary. The remanent magnetization of intrusive/extrusive rocks of the 'basement' complex of East Maio constitutes four components that define two different axes of magnetization, at around dec. 328, inc. 12 and dec. 007, inc. 14 respectively. In general, two or more components co-exist in separate specimens or sites but both axes are present most frequently in the normal sense. The NNW-striking axis, the B-axis, fits very well with the Upper Cretaceous polar wander path for Africa. It is consequently inferred that the major phase of sheet intrusions in Maio dates from this time, probably from the interval 90–70 Myr bp. Comparisons of the directional dispersions in the folded and unfolded states suggest that this injection phase post-dates the uplift of the Central Igneous Complex of the island. The second axis of magnetization, the A -axis, agrees very well with late Teritary—Quaternary palaeomagnetic data for Africa and the Canary Islands. The A -axis is therefore regarded as of secondary origin, being the consequence of a thermal/ chemical overprint during the Miocene—Pliocene volcanism on the island. The occurrence of a 50–70 Myr long period of volcanic quiescence and erosion, between the termination of the early igneous activity (Upper Cretaceous) and the rejuvenated magmatism in Miocene/Pliocene time, is compatible with similar observations in the Canary Islands. In contrast to the palaeomagnetic conclusions, the K/Ar data only give ages around 10 Myr. The unusually young isotope dates are regarded as being due to an almost complete age resetting and are seen in conjuction with the overprinted magnetization. This explanation is further supported by the fact that K/Ar results of pillow lavas underlying Upper Jurassic limestones only give Tertiary ages.     

Tide-induced variability in beach surface moisture: Observations and modelling

The moisture content w_s of a beach surface strongly controls the availability of sand for aeolian transport. Our predictive capability of the spatiotemporal variability in w_s, which depends to a large extent on water table depth, is, however, limited. Here we show that water table fluctuations and surface moisture content observed during a 10-day period on a medium-grained (365μm) planar (1:30) beach can be predicted well with the nonlinear Boussinesq equation extended to include run-up infiltration and a soil–water retention curve under the assumption of hydrostatic equilibrium. On the intertidal part of the beach the water table is observed and predicted to continuously fall from the moment the beach surface emerges from the falling tide to just before it is submerged by the incoming tide. We find that on the lower 30% of the intertidal beach the water table remains within 0.1–0.2 m from the surface and that the sand is always saturated (w_s≈20%, by mass). Higher up on the intertidal beach, the surface can dry to about 5% when the water table has fallen to 0.4–0.5 m beneath the surface. Above the high-tide level the water table is always too deep (>0.5 m) to affect surface moisture and, without precipitation, the sand is dry (w_s < 5 − 8%). Because the water table depth on the emerged part of the intertidal beach increases with time irrespective of whether the (ocean) tide falls or rises, we find no need to include hysteresis (wetting and drying) effects in the surface-moisture modelling. Model simulations suggest that at the present planar beach only the part well above mean sea level can dry sufficiently (w_s < 10%) for sand to become available for aeolian transport. ©2018 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

Drying climate in Ghana over the period 1960–2005: evidence from the resampling-based Mann-Kendall test at local and regional levels

Abstract

Trends in rainfall series were investigated at 16 stations in Ghana over the period 1960–2005. Time series were first de-correlated using an effective pre-whitening methodology and then submitted to the resampling-based Mann-Kendall test. Field significances were assessed using the regional average Kendall statistic. Although no significant changes were observed in annual rainfall, the analysis reveals: (a) a reduction in the number of wet season days totalling less than 20 mm of rainfall, between latitudes 6° and 9.5°N; (b) a delay (about 0.5 d year^‐1) in the wet season onset at several locations throughout the country; and (c) a lengthening (about 0.1 d year^‐1) of rainless periods during the wet season in the south and centre of Ghana. All these changes, which remained insignificant at more than half of the individual stations, were found to be regionally significant at the 95% confidence level. The results highlight the importance of evaluating regional significance when investigating climate trends.

Editor Z.W. Kundzewicz

Citation Lacombe, G., McCartney, M., and Forkuor, G., 2012. Drying climate in Ghana over the period 1960–2005: evidence from the resampling-based Mann-Kendall test at local and regional levels. Hydrological Sciences Journal, 57 (8), 1594–1609.