GGR Biennial Review: Atomic Absorption,Inductively Coupled Plasma-Atomic Emission Spectrometry,Neutron Activation Analysis and X-Ray Fluorescence Spectrometry Review for 2008–2009

This review describes developments major and in trace element determination using atomic absorption spectroscopy (AAS), inductively coupled plasma-atomic emission spectrometry (ICP-AES), instrumental neutron activation analysis (INAA), and X-ray fluorescence (XRF) spectrometry that were reported in 2008 and 2009. Publication levels were comparable to those of previous years, except for XRF which showed an increase in the number of articles published in the past 2 years. In terms of number of publications and impact, the most active field was AAS, while INAA was the least active. As expected for well-established and mature methods, novel developments for all four analytical techniques were relatively sparse. For AAS, the most notable publications concerned developments in sample introduction, particularly focussing on solid samples, increasing analyte sensitivity, and higher sample throughput. For ICP-AES, publication of developments in sample introduction, remediation of matrix effects and calibration continues. Compared with past years, there was a clear focus on sample preconcentration methods, but very few publications reporting new hyphenated speciation methods. For INAA, there were several publications exploring the accuracy and robustness of the method, as well as the requirements for INAA to meet criteria for a primary method of measurement. Two other related techniques, delayed neutron activation analysis, and prompt gamma activation analysis, were also described. Hyphenated XRF techniques showed interesting developments in enabling XRF and XRD analysis on the same spot, and further work characterising and calibrating three-dimensional micro-XRF shows promising results for investigating sample heterogeneity.     

A generalization of Szebehely's equation for three dimensions

Szebehely's equation for the potential generating a prescribed family of orbits in two dimensions is generalized for three-dimensional orbits. A simultaneous system of first-order linear partial differential equations is derived for the determination of the potential in the three-dimensional case. Solutions of this system are found in several cases including Kepler's problem too.Paper presented at the 1981 Oberwolfach Conference on Mathematical Methods in Celestial Mechanics.This paper is dedicated to Professor Victor Szebehely on the occasion of his 60th birthday.     

Landscape planning in the Transcaucasia

We have developed the planning documents for model territories of a different dimension: the landscape program of Adzharia (Georgia), the landscape structure plan for the Lake Sevan watershed basin (Armenia), and the landscape plan for the Shirvan National Park (Azerbaijan). Variants of the solution of regional natural-ecological problems are proposed, and the measures for implementation of the target concepts are substantiated.     

Cave air and hydrological controls on prior calcite precipitation and stalagmite growth rates: Implications for palaeoclimate reconstructions using speleothems

Hourly resolved cave air P_CO2 and cave drip water hydrochemical data illustrate that calcite deposition on stalagmites can be modulated by prior calcite precipitation (PCP) on extremely short timescales. A very clear second-order covariation between cave air P_CO2 and drip water Ca²⁺ concentrations during the winter months demonstrates the effects of degassing-induced PCP on drip water chemistry. Estimating the strength of the cave air P_CO2 control on PCP is possible because the PCP signal is so clear; at our drip site a one ppm shift in Ca²⁺ concentrations requires a P_CO2 shift of between 333 and 667 ppm. This value will undoubtedly vary from site to site, depending on drip water flow rate, residence time, drip water-cave air P_CO2 differential, and availability of low P_CO2 void spaces in the vadose zone above the cave. High-resolution cave environmental measurements were used to model calcite deposition on one stalagmite in Crag Cave, SW Ireland, and modelled growth over the study period (222 μm over 171 days) is extremely similar to the amount of actual calcite growth (240 μm) over the same time interval, strongly suggesting that equations used to estimate stalagmite growth rates are valid. Although cave air P_CO2 appears to control drip water hydrochemistry in the winter, drip water dilution caused by rain events may have played a larger role during the summer, as evidenced by a series of sudden drops in Ca²⁺ concentrations (dilution) followed by much more gradual increases in drip water Ca²⁺ concentrations (slow addition of diffuse water). This research demonstrates that PCP on stalactites, cave ceilings, and void spaces within the karst above the cave partially controls drip water chemistry, and that thorough characterisation of this process at individual caves is necessary to most accurately interpret climate records from those sites.     

Far field effects of Alpine plate tectonism in the Iberian microplate recorded by fault-related denudation in the Spanish Central System

Apatite fission track analysis was performed on 56 samples from central Spain to unravel the far field effects of the Alpine plate tectonic history of Iberia. The modelled thermal histories reveal complex cooling in the Cenozoic, indicative of intermittent denudation. Accelerated cooling events occurred across the Spanish Central System (SCS) from the Middle Eocene to Recent. These accelerated cooling events resulted in up to 2.8±0.9 km of denudation in the western Sierra de Gredos and 3.6±1.0 km in the central and eastern Gredos (assuming a paleogeothermal gradient of 28±5 °C and a surface temperature of 10 °C). The greatest amount of denudation (5.0±1.6 km) occurred in the Sierra de Guadarrama. Accompanying rock uplift was 4.7±1.0 and 5.9±1.6 km in the eastern Gredos and Guadarrama, respectively. Most denudation in the Gredos occurred from the Middle Eocene to the Early Miocene and can be related to the N–S stress field, induced by the Pyrenean compression. In the Guadarrama, the greatest denudation was Pliocene to Recent of age and seems related to the ongoing NW–SE Betic compression. The fact that the formation of the E–W trending Gredos coincides with the N–S Pyrenean compression and the creation of the present day morphology of the NE–SW trending Guadarrama with the younger NW–SE Betic compression, indicates that they record the far field effects of Alpine plate tectonics on Iberia. The trend of pre-existing lineaments was of major importance in influencing the style and magnitude of these of far field effects.     

Stratigraphic architecture of the fluvio-lacustrine deposits, Bathan Formation, Al-Rehaili area, North Jeddah, Saudi Arabia

A siliciclastic-dominated succession (～11 m thick) underlying Harrat Rahat, belonging to the Miocene–Pliocene Bathan Formation is recently exposed at Al-Rehaili area, North Jeddah, Saudi Arabia. It covers a wide spectrum of grain sizes varying from clay-rich mudstones to cobble grade conglomerate and consists of a variety of facies vary from fluvial to marginal and open lacustrine deposited in a half-graben basin formed along the eastern margin of the extensional Red Sea Basin. Field-based sedimentologic investigation enables to identify ten facies grouped into three facies associations (A–C). The depositional history is subdivided into two stages. The first stage represents deposition in gravel to sand-dominated fluvial system sourced from a southern source and grade northward into lacustrine delta and open lacustrine setting. The second stage on the other hand includes deposition of fluvial channels running in E–W direction with attached bank sand bar. Sequence stratigraphic interpretations of the lacustrine deposits enable to identify three unconformity-bounded sequences (SQ_1–3). The basal sequence is incomplete, consisting of three aggradationally to progradationally stacked delta plain and delta front parasequences. The second sequence is sharply and erosively overlying a red paleosol bed that defines the upper boundary of the first sequence. It includes two system tracts; upward-fining and deepening lacustrine offshore mudstones of the transgressive system tracts unconformably overlain by red paleosol of the regressive systems tracts. The top of this sequence is delineated at the sharp transgressive surface of erosion at the base of delta mouth bar deposits of sequence 3. Changes in the accommodation and sedimentation rates by basin subsidence under the influence of tectonics and sediment compaction and loading as well as climatic oscillation between semi-arid to arid conditions were the major controls on the fluvio-lacustrine sedimentation and their facies distribution. Tectonic reorganization of the drainage system resulted in the formation of E–W flowing fluvial streams in the second stage.