In situ Raman observation of the crystallization in NaNO3–Na2SO4–H2O solution droplets

Several double salts have been detected in building materials and most of these salts are incongruently soluble compounds. In contrast to single salts, however, no systematic investigations of the crystallization behavior and deleterious effects of incongruently soluble double salts exist. To assess the damage potential of these salts, a systematic investigation of their highly complex behavior is desirable. This paper deals with the crystallization behavior of various solids in the ternary mixed NaNO₃–Na₂SO₄ system including the formation of the double salt darapskite, Na₃NO₃SO₄·H₂O. The crystallization sequence during droplet evaporation experiments at room conditions was determined using Raman and polarization microscopy. The basic idea of this research is to use deviations of the crystallization sequence of a salt or a mixed salt solution from the equilibrium pathway as an indicator to detect the degree of supersaturation. The observed crystallization pathway includes the formation of the metastable phases Na₂SO₄(III), Na₂SO₄(V) and darapskite. The experimental observations are discussed on the basis of the NaNO₃–Na₂SO₄–H₂O phase diagram and the results provide evidence for crystal growth from highly supersaturated solutions in both systems. If the crystals growing under these conditions are confined, these supersaturations result in substantial crystallization pressures.     

Groundwater Resources and Their Role in Water Supply to Crimea

The processes of formation and distribution of the resources of fresh groundwater and surface water in the territory of Crimea Peninsula are considered. Water availability in the natural–historic and administrative regions of the republic is characterized. The proportions between different categories of groundwater resources are shown with their role in water supply to Crimea taken into account. The presentday development of groundwater resources is analyzed and the possible increase in water consumption meeting geoecological requirements is substantiated.     

Statewide Estimates of Undiscovered Deposits of Gold,Silver, Copper,Lead, and Zinc

Estimates of the number of undiscovered deposits on a statewide basis offer a different perspective on the nation's undiscovered resources of gold, silver, copper, lead, and zinc. Mean estimates of the number of undiscovered deposits statewide were extracted from the estimates of undiscovered deposits nationwide. More than 50 undiscovered deposits are estimated to occur in Alaska, Arizona, Nevada, and Wisconsin. Estimating the number of undiscovered deposits statewide serves as a measure of a state's total remaining mineral resources in known conventional deposit types.     

THE STUDY OF THE GENESIS OF SURFACE WATERS BY OBSERVING THEIR ELECTRICAL RESISTIVITIES*

Specific electrical resistivity of natural waters contains information on their genesis. The authors propose to conduct mass and regime observations of this parameter in river and stream beds. The electrical resistivities in streams flowing from under a glacier reveal details formed at the same time as the glacier. Observations in the beds of big rivers show a gradual increase in water salinity overlain by reductions by inflowing glacial waters. The diurnal and annual trend of changes in the electrical conductivity of water associated with the change in the balance of glacial and ground waters has been established near to glaciers. Resistivity observations help to locate discharge sites of sub-permafrost waters, for water.     

A Review of “Hurricanes of the Gulf of Mexico”

Books reviewed:

Bassin, Mark, Imperial Visions: Nationalist Imagination and Geographical Expansion in the Russian Far East, 1840 – 1865

Shortridge, James R., Our Town on the Plains: J. J. Pennell's Photographs of Junction City, Kansas, 1893 – 1922

Jakle, John A. and Sculle, Keith A., Fast Food: Roadside Restaurants in the Automobile Age

Boeschenstein, Walter, Historic American Towns along the Atlantic Coast

McKee, Jesse O., Ethnicity in Contemporary America: A Geographical Appraisal

Luciuk, Lubomyr Y., Searching for Place: Ukrainian Displaced Persons, Ottawa, and the Migration of Memory

Hausladen, Gary, Places for Dead Bodies

Phillips, Richard, Watt, Diane and Shuttleton, David, De-Centering Sexualities: Politics and Representations beyond the Metropolis

Goldin, Liliana R., Identities on the Move, Transnational Processes in North America and the Caribbean Basin

McDonald, David A., On Borders: Perspectives on International Migration in Southern Africa

Fox, Roddy and Rowntree, Kate, The Geography of South Africa in a Changing World

Takeuchi, Keiichi, Modern Japanese Geography: An Intellectual History

Amery, Hussein A., and Wolf, Aaron T., Water in the Middle East: A Geography of Peace

Karl, Thomas R., Nicholls, Neville and Ghazi, Anver, Weather and Climate Extremes: Changes, Variations, and a Perspective from the Insurance Industry

Pittman, Blair, Texas Caves     

Flow and form in rehabilitation of large-river ecosystems: An example from the Lower Missouri River

On large, intensively engineered rivers like the Lower Missouri, the template of the physical habitat is determined by the nearly independent interaction of channel form and flow regime. We evaluated the interaction between flow and form by modeling four combinations of modern and historical channel form and modern and historical flow regimes. The analysis used shallow, slow water (shallow-water habitat, SWH, defined as depths between 0 and 1.5 m, and current velocities between 0 and 0.75 m/s) as an indicator of habitat that has been lost on many intensively engineered rivers and one that is thought to be especially important in rearing of young fishes. Two-dimensional hydrodynamic models for modern and historical channels of the Lower Missouri River at Hermann, Missouri, indicate substantial differences between the two channels in total availability and spatial characteristics of SWH. In the modern channel, SWH is maximized at extremely low flows and in overbank flows, whereas the historical channel had substantially more SWH at all discharges and SWH increased with increasing discharge. The historical channel form produced 3–7 times the SWH area of the modern channel regardless of flow regime. The effect of flow regime is evident in increased within-year SWH variability with the natural flow regime, including significant seasonal peaks of SWH associated with spring flooding. Comparison with other reaches along the Lower Missouri River indicates that a) channel form is the dominant control of the availability of habitat even in reaches where the hydrograph is more intensively altered, and b) rehabilitation projects that move toward the historical condition can be successful in increasing topographic diversity and thereby decreasing sensitivity of the availability of habitat to flow regime. The relative efficacy of managing flow and form in creating SWH is useful information toward achieving socially acceptable rehabilitation of the ecosystem in large river systems.     

Integration of reflection seismic and sediment grain-size data from Lake Khubsugul (Northern Mongolia): a reply to Prokopenko and Kendall

Prokopenko and Kendall (J Paleolimnol doi:, 2008) criticise the work presented in Fedotov et al. (J Paleolimnol 39:335–348, 2008), and instead propose an alternative interpretation for the grain-size evolution recorded in the KDP-01 core, retrieved from the central part of Lake Khubsugul. Their interpretation is based (i) on a seismic-stratigraphic re-interpretation of sparker seismic profile khub012 (which they copied from Fedotov et al. (EOS Trans 87:246–250, 2006)), (ii) on the presupposition that changes in lake level are the dominant control on facies distribution in Lake Khubsugul, and (iii) on the invalidation of our age-depth model. In this reply to their comment, we demonstrate that they interpreted seismic artefacts and geometries caused by changes in profile orientation as true stratigraphic features and that the lake-level reconstruction they derive from this interpretation is therefore incorrect. We also demonstrate that their grain-size predictions, which they consider to be predominantly driven by changes in lake level, are inconsistent with the measured sulphate concentration, which is a demonstrated proxy of lake level in Lake Khubsugul, and with the measured grain-size record. Finally, we point out that even if there would be a problem with the age-depth model, this problem would not affect the part of the sedimentary sequence discussed in Fedotov et al. (J Paleolimnol 39:335–348, 2008).     

STRUCTURE AND COMPOSITION OF A WATERSHED-SCALE SEDIMENT INFORMATION NETWORK

A "Watershed-Scale Sediment Information Network" (WaSSIN), designed to complement UNESCO’s International Sedimentation Initiative, was endorsed as an initial project by the World Association for Sedimentation and Erosion Research. WaSSIN is to address global fluvial-sediment information needs through a network approach based on consistent protocols for the collection, analysis, and storage of fluvial-sediment and ancillary information at smaller spatial scales than those of the International Sedimentation Initiative. As a second step of implementation, it is proposed herein that the WaSSIN have a general structure of two components, (1) monitoring and data acquisition and (2) research. Monitoring is to be conducted in small watersheds, each of which has an established database for discharge of water and suspended sediment and possibly for bed load, bed material, and bed topography. Ideally, documented protocols have been used for collecting, analyzing, storing, and sharing the derivative data. The research component is to continue the collection and interpretation of data, to compare those data among candidate watersheds, and to determine gradients of fluxes and processes among the selected watersheds. To define gradients and evaluate processes, the initial watersheds will have several common attributes. Watersheds of the first group will be: (1) six to ten in number, (2) less than 1000 km2 in area, (3) generally in mid-latitudes of continents, and (4) of semiarid climate. Potential candidate watersheds presently include the Weany Creek Basin, northeastern Australia, the Zhi Fanggou catchment, northern China, the Eshtemoa Watershed, southern Israel, the Metsemotlhaba River Basin, Botswana, the Aiuaba Experimental Basin, Brazil, and the Walnut Gulch Experimental Watershed, southwestern United States.     

Inductive magnetic footpoint tracking by combining the minimum energy fit with the local correlation tracking and doppler velocity

Time-dependent magneto-hydrodynamic simulations of active region coronal magnetic field require the underlying photospheric magnetic footpoint velocities. The minimum energy fit (MEF) is a new velocity inversion technique to infer the photospheric magnetic footpoint velocities using a pair of vector magnetograms, introduced by Longcope (2004). The MEF selects the smallest overall flow from several consistent flows by minimizing an energy functional. The inferred horizontal and vertical flow fields by the MEF can be further constrained by incorporating the partial or imperfect velocity information obtained through independent means. This hybrid method is expected to give a velocity close to the true magnetic footpoint velocity. Here, we demonstrate that a combination of the MEF, the local correlation tracking (LCT) and Doppler velocity is capable of inferring the velocity close to the photospheric flow.