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991.
V.B. Bazarova M.S. Lyashchevskaya T.R. Makarova R.A. Makarevich L.A. Orlova 《Russian Geology and Geophysics》2018,59(11):1410-1418
Overbank deposits in the Komissarovka River valley consist of alternating silt, clay silt, sand, and soils produced by lacustrine, alluvial, and aeolian deposition and by soil formation. Silt and sand layers in the lower part of the section correlate with the events of Early Holocene transgression and Middle Holocene regression of Lake Khanka. Deposition in the lowermost reaches of the Komissarovka River provides a faithful record of local Holocene landscapes controlled by level changes in Lake Khanka. 相似文献
992.
Scientists from all over the world try to incorporate multi-disciplinary precursors to forecast the earthquake on a short-term basis. The authors here have analyzed outgoing longwave radiations acquired from polar-orbiting National Oceanic and Atmospheric Adminstration (NOAA) satellites and long-period infrasound waves recorded by the ground observatories in China prior to the recent Bonin Islands, Japan region earthquake which occurred on May 30, 2015 with the magnitude of 7.8. The anomalous outgoing longwave radiation (OLR) was observed on May 15, 2015, and was recorded by “NOAA 18” satellite during its “night pass.” Similarly, an abnormal infrasound spike was recorded at the Beijing station on May 17, 2015. The delay in observing anomalous infrasound waves compared to the OLR anomaly is due to these low-frequency waves traveling at low speed with the velocity range of 10–15 m/s. From the analysis of the results, it can be inferred that there is a substantial relation between parameters like OLR and infrasound waves; hence, the authors conclude that it is possible to forecast the earthquake on a short-term basis with reasonable accuracy. 相似文献
993.
M. Hamidzadeh M. Ghassemzadeh A. Tarlani S. Sahebdelfar 《International Journal of Environmental Science and Technology》2018,15(1):93-104
The selective catalytic reduction (SCR) of nitrogen oxides on M/ZSM-5 (M = Cu, Ni, Co) catalysts was investigated. The catalysts were prepared using hydrothermal impregnation of the metal chlorides and nitrates on ZSM-5. The catalysts were characterized by nitrogen absorption/desorption, X-ray diffraction, Fourier transform infrared (FTIR) spectroscopy, ultraviolet–visible diffusion reflection spectroscopy (UV–Vis DRS), temperature-programmed reduction (TPR), N2O chemisorption and ammonia temperature-programmed desorption. The performance tests for SCR of NO were carried out in a fixed-bed reactor from 250 to 400 °C. During the impregnation, part of the aluminum was eliminated from the zeolite framework due to the acidity of the metal salt solution and heating process as indicated by the reduction in the intensity of XRD peaks and variations in the positions of the FTIR vibrational bands. The Cu(Cl)/ZSM-5 catalyst exhibited NO conversions over 90% over the entire temperature range. The other catalysts showed comparable activities, but the catalysts prepared with chloride salt precursors demonstrated higher activity than those based on nitrate as the precursor. Moreover, the TPR reduction peaks of the metal ion in catalysts prepared with chloride precursor were lower, and their UV–Vis absorption bands revealed bathochromic transfers with higher intensities. Concurrent with these changes, the activity of the catalyst increased. The TPR profiles indicated that Cu and Ni both had an oxidation number of +2, whereas Co was present in the oxidation number of +2 and +3. The mass transfer limitation analysis showed that for particles in millimeter size range or larger significant intra-particle mass transfer limitation would be expected. 相似文献
994.
M. Narayanasamy D. Dhanasekaran G. Vinothini N. Thajuddin 《International Journal of Environmental Science and Technology》2018,15(1):119-132
Printed circuit boards contain precious metals. They are produced in large volumes, rendering them an important component of the electronic waste. In view of the heterogeneity of the metals present, reprocessing of electronic waste is a heinous task. The present study focused on leaching of valuable metals from electronic waste printed circuit boards using Aspergillus niger DDNS1. The adaptation phases began at 0.1, 0.5 and 1.0% of fine powder of printed circuit boards with 10% inoculum and were optimized with three effective factors, viz. initial pH, particle size and pulp density, to achieve the maximum simultaneous recovery of the valuable metals. The interactions of these metals were also deciphered using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, Fourier transform infrared spectrum and atomic absorption spectroscopy. The results indicated that extraction of the precious metals was accomplished mainly through the unique organic acids originating from A. niger DDNS1. The initial pH played an important role in the extraction of the precious metals and the metals precipitate formation. The leaching rate of the metals was generally higher at low powder dosage of printed circuit boards. The toxicity of the printed circuit boards had little effect on two-step bioleaching at the pulp density of 0.1% compared to one-step bioleaching. The two-step bioleaching process was followed under organic acid-forming conditions for the maximum mobilization of metals. Thus, the precious metals from printed circuit boards could be mobilized through fungal bioleaching which promises an important industrial application in recycling of electronic wastes. 相似文献
995.
U-Pb isotopic thermochronometry of rutile, apatite and titanite from kimberlite-borne lower crustal granulite xenoliths has been used to constrain the thermal evolution of Archean cratonic and Proterozoic off-craton continental lithosphere beneath southern Africa. The relatively low closure temperature of the U-Pb rutile thermochronometer (~400-450 °C) allows its use as a particularly sensitive recorder of the establishment of "cratonic" lithospheric geotherms, as well as subsequent thermal perturbations to the lithosphere. Contrasting lower crustal thermal histories are revealed between intracratonic and craton margin regions. Discordant Proterozoic (1.8 to 1.0 Ga) rutile ages in Archean (2.9 to 2.7 Ga) granulites from within the craton are indicative of isotopic resetting by marginal orogenic thermal perturbations influencing the deep crust of the cratonic nucleus. In Proterozoic (1.1 to 1.0 Ga) granulite xenoliths from the craton-bounding orogenic belts, rutiles define discordia arrays with Neoproterozoic (0.8 to 0.6 Ga) upper intercepts and lower intercepts equivalent to Mesozoic exhumation upon kimberlite entrainment. In combination with coexisting titanite and apatite dates, these results are interpreted as a record of postorogenic cooling at an integrated rate of approximately 1 °C/Ma, and subsequent variable Pb loss in the apatite and rutile systems during a Mesozoic thermal perturbation to the deep lithosphere. Closure of the rutile thermochronometer signals temperatures of °C in the lower crust during attainment of cratonic lithospheric conductive geotherms, and such closure in the examined portions of the "off-craton" Proterozoic domains of southern Africa indicates that their lithospheric thermal profiles were essentially cratonic from the Neoproterozoic through to the Late Jurassic. These results suggest similar lithospheric thickness and potential for diamond stability beneath both Proterozoic and Archean domains of southern Africa. Subsequent partial resetting of U-Pb rutile and apatite systematics in the cratonic margin lower crust records a transient Mesozoic thermal modification of the lithosphere, and modeling of the diffusive Pb loss from lower crustal rutile constrains the temperature and duration of Mesozoic heating to °C for ka. This result indicates that the thermal perturbation is not simply a kimberlite-related magmatic phenomenon, but is rather a more protracted manifestation of lithospheric heating, likely related to mantle upwelling and rifting of Gondwana during the Late Jurassic to Cretaceous. The manifestation of this thermal pulse in the lower crust is spatially and temporally correlated with anomalously elevated and/or kinked Cretaceous mantle paleogeotherms, and evidence for metasomatic modification in cratonic mantle peridotite suites. It is argued that most of the geographic differences in lithospheric thermal structure inferred from mantle xenolith thermobarometry are likewise due to the heterogeneous propagation of this broad upper mantle thermal anomaly. The differential manifestation of heating between cratonic margin and cratonic interior indicates the importance of advective heat transport along pre-existing lithosphere-scale discontinuities. Within this model, kimberlite magmatism was a similarly complex, space- and time-dependent response to Late Mesozoic lithospheric thermal perturbation. 相似文献
996.
W. Bae D. Han E. Kim R. A. de Toledo K. Kwon H. Shim 《International Journal of Environmental Science and Technology》2016,13(7):1675-1684
The upflow anaerobic sludge blanket process followed by the biological aerated filter process was employed to improve the removal of color and recalcitrant compounds from real dyeing wastewater. The highest removal efficiency for color was observed in the anaerobic process, at 8-h hydraulic retention time, seeded with the sludge granule. In the subsequent aerobic process packed with the microbe-immobilized polyethylene glycol media, the removal efficiency for chemical oxygen demand increased significantly to 75 %, regardless of the empty bed contact time. The average influent non-biodegradable soluble chemical oxygen demand was 517 mg/L, and the average concentration in effluent from the anaerobic reactor was 363 mg/L, suggesting the removal of some recalcitrant matters together with the degradable ones. The average non-biodegradable soluble chemical oxygen demand in effluent from the aerobic reactor was 87, 93, and 118 mg/L, with the removal efficiency of 76, 74, and 67 %, at 24-, 12-, and 8-h empty bed contact time, respectively. The combined anaerobic sludge blanket and aerobic cell-entrapped process was effective to remove the refractory compounds from real dyeing wastewater as well as in reducing organic loading to meet the effluent discharge limits. This integrated process is considered an effective and economical treatment technology for dyeing wastewater. 相似文献
997.
V. O. Davydova V. D. Shcherbakov P. Yu. Plechov 《Moscow University Geology Bulletin》2018,73(5):444-450
Intrusion of magma of contrasting composition into a magma chamber often triggers eruptions of arc volcanoes. Application of the diffusion chronometry method allowed us to determine the time when fresh magma was supplied to the shallow chamber of Bezymianny volcano in the case of six eruptions in 2006–2012 and to compare them to the recorded seismic activity of this volcano. Two types of eruptions of Bezymianny volcano were distinguished, with a contrasting orthopyroxene rim being formed in the respective magmas (a) up to 3 years and (b) up to 2 months before the beginning of an eruption. It was shown that these differences are caused by two different paths of magma supply to the shallow chamber of Bezymianny volcano. 相似文献
998.
Caledonian high-pressure metamorphism in the Strona-Ceneri Zone (Southern Alps of southern Switzerland and northern Italy) 总被引:3,自引:0,他引:3
The Strona-Ceneri Zone comprises a succession of polymetamorphic, pre-Alpidic basement rocks including ortho- and paragneisses,
metasedimentary schists, amphibolites, and eclogites. The rock pile represents a Late Proterozoic or Palaeozoic subduction
accretion complex that was intruded by Ordovician granitoids. Eclogites, which occur as lenses within the ortho-paragneiss
succession and as xenoliths within the granitoids record a subduction related high-pressure event (D1) with peak metamorphic
conditions of 710 ± 30 °C at 21.0 ± 2.5 kbar. After isothermal uplift, the eclogites experienced a Barrowtype (D2) tectonometamorphic
overprint under amphibolite facies conditions (570-630 °C, 7-9 kbar). U-Pb dating on zircon of the eclogites gives a metamorphic
age of 457 ± 5 Ma, and syn-eclogite facies rutile gives a 206Pb/238U age of 443 ± 19 Ma classifying the subduction as a Caledonian event. These data show that the main tectonometamorphic evolution
of the Strona-Ceneri Zone most probably took place in a convergent margin scenario, in which accretion, eclogitization of
MOR-basalt, polyphase (D1 and D2) deformation, anatexis and magmatism all occurred during the Ordovician. Caledonian high-pressure
metamorphism, subsequent magmatism and Barrow-type metamorphism are believed to be related to subduction and collision within
the northern margin of Gondwana.
Editorial handling: Edwin Gnos 相似文献
999.
Zoning of diamonds from the Mir kimberlite pipe: Results of Fourier-transformed infrared spectroscopy 总被引:1,自引:0,他引:1
Plates prepared of diamonds from the Mir kimberlite pipe were examined with FTIR spectroscopy. It is shown that B1 defects were formed by annealing during crystal growth, whereas B2 centers arose after growth cessation. The development of B2 centers in a natural diamond is the secondary process with respect to the aggregation of the nitrogen admixture. The kinetics of this process is related to the breakdown of an oversaturated solid solution. The results obtained make it possible to estimate the temperature and duration of natural diamond growth. 相似文献
1000.
The pre-Mesozoic, mainly Variscan metamorphic basement of the Col de Bérard area (Aiguilles Rouges Massif, External domain)
consists of paragneisses and micaschists together with various orthogneisses and metabasites. Monazite in metapelites was
analysed by the electron microprobe (EMPA-CHIME) age dating method. The monazites in garnet micaschists are dominantly of
Variscan age (330–300 Ma). Garnet in these rocks displays well developed growth zonations in Fe–Mg–Ca–Mn and crystallized
at maximal temperatures of 670°C/7 kbar to the west and 600°C/7–8 kbar to the east. In consequence the monazite is interpreted
to date a slightly pressure-dominated Variscan amphibolite-facies evolution. In mylonitic garnet gneisses, large metamorphic
monazite grains of Ordovician–Silurian (~440 Ma) age but also small monazite grains of Variscan (~300 Ma) age were discovered.
Garnets in the mylonitic garnet gneisses display high-temperature homogenized Mg-rich profiles in their cores and crystallized
near to ~800°C/6 kbar. The Ordovician–Silurian-age monazites can be assigned to a pre-Variscan high-temperature event recorded
by the homogenised garnets. These monazite age data confirm Ordovician–Silurian and Devonian–Carboniferous metamorphic cycles
which were already reported from other Alpine domains and further regions in the internal Variscides. 相似文献