GGR Biennial Review: Atomic Absorption,Inductively Coupled Plasma-Atomic Emission Spectrometry,Neutron Activation Analysis and X-Ray Fluorescence Spectrometry Review for 2008–2009

This review describes developments major and in trace element determination using atomic absorption spectroscopy (AAS), inductively coupled plasma-atomic emission spectrometry (ICP-AES), instrumental neutron activation analysis (INAA), and X-ray fluorescence (XRF) spectrometry that were reported in 2008 and 2009. Publication levels were comparable to those of previous years, except for XRF which showed an increase in the number of articles published in the past 2 years. In terms of number of publications and impact, the most active field was AAS, while INAA was the least active. As expected for well-established and mature methods, novel developments for all four analytical techniques were relatively sparse. For AAS, the most notable publications concerned developments in sample introduction, particularly focussing on solid samples, increasing analyte sensitivity, and higher sample throughput. For ICP-AES, publication of developments in sample introduction, remediation of matrix effects and calibration continues. Compared with past years, there was a clear focus on sample preconcentration methods, but very few publications reporting new hyphenated speciation methods. For INAA, there were several publications exploring the accuracy and robustness of the method, as well as the requirements for INAA to meet criteria for a primary method of measurement. Two other related techniques, delayed neutron activation analysis, and prompt gamma activation analysis, were also described. Hyphenated XRF techniques showed interesting developments in enabling XRF and XRD analysis on the same spot, and further work characterising and calibrating three-dimensional micro-XRF shows promising results for investigating sample heterogeneity.     

A generalization of Szebehely's equation for three dimensions

Szebehely's equation for the potential generating a prescribed family of orbits in two dimensions is generalized for three-dimensional orbits. A simultaneous system of first-order linear partial differential equations is derived for the determination of the potential in the three-dimensional case. Solutions of this system are found in several cases including Kepler's problem too.Paper presented at the 1981 Oberwolfach Conference on Mathematical Methods in Celestial Mechanics.This paper is dedicated to Professor Victor Szebehely on the occasion of his 60th birthday.     

Atlas of susceptibility to pollution in marinas. Application to the Spanish coast

An atlas of susceptibility to pollution of 320 Spanish marinas is provided. Susceptibility is assessed through a simple, fast and low cost empirical method estimating the flushing capacity of marinas. The Complexity Tidal Range Index (CTRI) was selected among eleven empirical methods. The CTRI method was selected by means of statistical analyses because: it contributes to explain the system's variance; it is highly correlated to numerical model results; and, it is sensitive to marinas' location and typology. The process of implementation to the Spanish coast confirmed its usefulness, versatility and adaptability as a tool for the environmental management of marinas worldwide. The atlas of susceptibility, assessed through CTRI values, is an appropriate instrument to prioritize environmental and planning strategies at a regional scale.     

Far field effects of Alpine plate tectonism in the Iberian microplate recorded by fault-related denudation in the Spanish Central System

Apatite fission track analysis was performed on 56 samples from central Spain to unravel the far field effects of the Alpine plate tectonic history of Iberia. The modelled thermal histories reveal complex cooling in the Cenozoic, indicative of intermittent denudation. Accelerated cooling events occurred across the Spanish Central System (SCS) from the Middle Eocene to Recent. These accelerated cooling events resulted in up to 2.8±0.9 km of denudation in the western Sierra de Gredos and 3.6±1.0 km in the central and eastern Gredos (assuming a paleogeothermal gradient of 28±5 °C and a surface temperature of 10 °C). The greatest amount of denudation (5.0±1.6 km) occurred in the Sierra de Guadarrama. Accompanying rock uplift was 4.7±1.0 and 5.9±1.6 km in the eastern Gredos and Guadarrama, respectively. Most denudation in the Gredos occurred from the Middle Eocene to the Early Miocene and can be related to the N–S stress field, induced by the Pyrenean compression. In the Guadarrama, the greatest denudation was Pliocene to Recent of age and seems related to the ongoing NW–SE Betic compression. The fact that the formation of the E–W trending Gredos coincides with the N–S Pyrenean compression and the creation of the present day morphology of the NE–SW trending Guadarrama with the younger NW–SE Betic compression, indicates that they record the far field effects of Alpine plate tectonics on Iberia. The trend of pre-existing lineaments was of major importance in influencing the style and magnitude of these of far field effects.     

The bedrock topography of the botany basin,New South Wales

The bedrock topography of the Botany Basin has been determined from seismic‐sparker records made in Botany Bay and Bate Bay, and from seismic‐refraction and gravity measurements on the Kurnell Peninsula. Supplementary information has been obtained from boreholes both on land and in the sea.

The Cooks and Georges Rivers formerly constituted the main drainage of the Basin and flowed generally southeastwards (beneath the present Kurnell Peninsula) and joined the Port Hacking River east of Cronulla. The depth of the bedrock channel of the former Georges River is 75–80 m b.s.l. at Taren Point, 90–95 m beneath the Kurnell Peninsula and 110–115 m at its junction with the Port Hacking River channel. The bedrock channel of the former Cooks River is about 30 m b.s.l. at Kyeemagh, its present entrance to Botany Bay, and it joined the Georges River at a location now 90 m b.s.l. beneath the Kurnell Peninsula.

A second drainage system existed in the north and east of Botany Bay and generated the present mouth beneath which the bedrock is now 110 m b.s.l. This channel followed a southeasterly course parallel to the present northern shore of Botany Bay and was separated from that of the ‘Cooks and Georges Rivers’ by a bedrock ridge which extended from beneath Sydney Airport to the northern extremity of the Kurnell Peninsula. Over much of its length this divide had a depth of about 30 m b.s.l.

The formation of the Kurnell Peninsula tombolo led to the diversion of the ‘Cooks/Georges River’ through the mouth of Botany Bay and subsequently led to the development of the bay. This change in the drainage system occurred when the sea was less than 30 m below the present sea level.     

Anthropogenic transformations of the Arctic ecosystem of Lake Imandra: Tendencies for recovery after long period of pollution

Transformation of an Arctic aquatic ecosystem (a case study of Lake Imandra) under the impact of a mining industrial complex is considered. Water chemical composition and the ecosystem’s structural components (phyto- and zooplankton, zoobenthos, and ichthiofauna) are analyzed for the following periods: the preindustrial background (reference) conditions, industrial development of mineral resources and strong anthropogenic impact, industrial recession and decreased anthropogenic impact, and stabilization. The main regularities of the aquatic ecosystem successions under the conditions of anthropogenic loads and their decrease are established.     

Coastal processes and cliff recession between Gabicce and Pesaro (northern Adriatic Sea): a case history

Cliff recession on the high rocky coast between Gabicce and Pesaro Adriatic sea causes a wide range of mass movement processes on the whole slope, affecting both the bedrock and the overburden. The outcropping late Miocene rock formations are represented by marls, marly limestones, dark laminated mudstones and bedded sandstones and marls. Mass movements are common because of stratification and discontinuities in the rocks that, together with the presence of groundwater and weathering processes, reduce the overall strength of the slopes. A model for the evolution of this coastal area is proposed, which involves cyclic basal erosion, followed by mass movement that favours debris accumulation at the base of the cliff. The longshore currents have to then remove the material before a new cycle can begin.     

Weak Contrast PP Wave Displacement R/T Coefficients in Weakly Anisotropic Elastic Media

—Approximate PP plane wave displacement coefficients of reflection and transmission for weak contrast interfaces separating weakly but arbitrarily anisotropic elastic media are presented. The PP reflection coefficient for such an interface has been derived recently by Vavry?uk and P?en?ík (1997). The PP transmission coefficient presented in this paper was derived by the same approach. The coefficients are given as a sum of the coefficient for the weak contrast interface separating two nearby isotropic media and a term depending linearly on contrasts of the so-called weak anisotropy (WA) parameters (parameters specifying deviation of properties of the medium from isotropy), across the interface. While the reflection coefficient depends only on 8 of the complete set of the WA parameters describing P-wave phase velocity in weakly anisotropic media, the transmission coefficient depends on their complete set. The PP reflection coefficient depends on "shear-wave splitting parameter" γ. Tests of accuracy of the approximate formulae are presented on several models.