In situ LA-ICPMS Isotopic and Geochronological Studies on Carbonatites and Phoscorites from the Guli Massif,Maymecha-Kotuy,Polar Siberia

In this study we present a fresh isotopic data, as well as U–Pb ages from different REE-minerals in carbonatites and phoscorites of Guli massif using in situ LA-ICPMS technique. The analyses were conducted on apatites and perovskites from calcio-carbonatite and phoscorite units, as well as on pyrochlores and baddeleyites from the carbonatites. The ⁸⁷Sr/⁸⁶Sr ratios obtained from apatites and perovskites from the phoscorites are 0.70308–0.70314 and 0.70306–0.70313, respectively; and 0.70310–0.70325 and 0.70314–0.70327, for the pyrochlores and apatites from the carbonatites, respectively.Furthermore, the in situ laser ablation analyses of apatites and perovskites from the phoscorite yield εNd from 3.6 (±1) to 5.1 (±0.5) and from 3.8 (±0.5) to 4.9 (±0.5), respectively; εNd of apatites, perovskites and pyrochlores from carbonatite ranges from 3.2 (±0.7) to 4.9 (±0.9), 3.9 (±0.6) to 4.5 (±0.8) and 3.2 (±0.4) to 4.4 (±0.8), respectively. Laser ablation analyses of baddeleyites yielded an eHf(t)d of +8.5 (± 0.18); prior to this study Hf isotopic characteristic of Guli massif was not known. Our new in situ εNd, ⁸⁷Sr/⁸⁶Sr and eHf data on minerals in the Guli carbonatites imply a depleted source with a long time integrated high Lu/Hf, Sm/Nd, Sr/Rb ratios.In situ U–Pb age determination was performed on perovskites from the carbonatites and phoscorites and also on pyrochlores and baddeleyites from carbonatites. The co-existing pyrochlores, perovskites and baddeleyites in carbonatites yielded ages of 252.3 ± 1.9, 252.5 ± 1.5 and 250.8 ± 1.4 Ma, respectively. The perovskites from the phoscorites yielded an age of 253.8 ± 1.9 Ma. The obtained age for Guli carbonatites and phoscorites lies within the range of ages previously reported for the Siberian Flood Basalts and suggest essentially synchronous emplacement with the Permian-Triassic boundary.     

Age and origin of groundwater resources in the Ararat Valley,Armenia: a baseline study applying hydrogeochemistry and environmental tracers

Within the Ararat Valley (Armenia), a continuously growing water demand (for irrigation and fish farming) and a simultaneous decline in groundwater recharge (due to climate change) result in increasing stress on the local groundwater resources. This detrimental development is reflected by groundwater-level drops and an associated reduction of the area with artesian conditions in the valley centre. This situation calls for increasing efforts aimed at more sustainable water resources management. The aim of this baseline study was the collection of data that allows for study on the origin and age distribution of the Ararat Valley groundwater based on environmental tracers, namely stable (δ²H, δ¹⁸O) and radioactive (³⁵S, ³H) isotopes, as well as physical-chemical indicators. The results show that the Ararat Valley receives modern recharge, despite its (semi-)arid climate. While subannual groundwater residence times could be disproved (³⁵S), the detected ³H pattern suggests groundwater ages of several decades, with the oldest waters being recharged around 60 years ago. The differing groundwater ages are reflected by varying scatter of stable isotope and hydrochemical signatures. The presence of young groundwater (i.e., younger that the 1970s), some containing nitrate, indicates groundwater vulnerability and underscores the importance of increased efforts to achieve sustainable management of this natural resource. Since stable isotope signatures indicate the recharge areas to be located in the mountains surrounding the valley, these efforts must not be limited to the central part of the valley where most of the abstraction wells are located.

     

Spinel assemblages in lunar meteorites Graves Nunataks 06157 and Dhofar 1528: Implications for impact melting and equilibration in the Moon's upper mantle

Magnesium‐rich spinel assemblages occur in the two lunar vitric breccia meteorites—Dhofar (Dho) 1528 and Graves Nunataks (GRA) 06157. Dho 1528 contains up to ~0.7 mm cumulate Mg‐rich spinel crystals associated with Mg‐rich olivine, Mg‐ and Al‐rich pyroxene, plagioclase, and rare cordierite. Using thermodynamic calculations of these mineral assemblages, we constrain equilibration depths and discuss an origin of these lithologies in the upper mantle of the Moon. In contrast, small, 10 to 20 μm spinel phenocryst assemblages in glassy melt rock clasts in Dho 1528 and GRA 06157 formed from the impact melting of Mg‐rich rocks. Some of these spinel phenocrysts match compositional constraints for spinel associated with “pink spinel anorthosites” inferred from remote sensing data. However, such spinel phenocrysts in meteorites and Apollo samples are typically associated with significant amounts of olivine ± pyroxene that exceed the compositional constraints for pink spinel anorthosites. We conclude that the remotely sensed “pink spinel anorthosites” have not been observed in the collections of lunar rocks. Moreover, we discuss impact‐excavation scenarios for the spinel‐bearing assemblages in Dhofar 1528 and compare the bulk rock composition of Dho 1528 to strikingly similar compositions of Luna 20 samples that contain ejecta from the Crisium impact basin.     

Petrogenesis of lunar impact melt rock meteorite Oued Awlitis 001

Oued Awlitis 001 is a highly feldspathic, moderately equilibrated, clast‐rich, poikilitic impact melt rock lunar meteorite that was recovered in 2014. Its poikilitic texture formed due to moderately slow cooling, which judging from textures of rocks in melt sheets of terrestrial impact structures, is observed in impact melt volumes at least 100 m thick. Such coherent impact melt volumes occur in lunar craters larger than ~50 km in diameter. The composition of Oued Awlitis 001 points toward a crustal origin distant from incompatible‐element‐rich regions. Comparison of the bulk composition of Oued Awlitis 001 with Lunar Prospector 5° γ‐ray spectrometer data indicates a limited region of matches on the lunar farside. After its initial formation in an impact crater larger than ~50 km in diameter, Oued Awlitis 001 was excavated from a depth greater than ~50 m. The cosmogenic nuclide inventory of Oued Awlitis 001 records ejection from the Moon 0.3 Ma ago from a depth of at least 4 m and little mass loss due to ablation during its passage through Earth's atmosphere. The terrestrial residence time must have been very short, probably less than a few hundred years; its exact determination was precluded by a high concentration of solar cosmic ray‐produced ¹⁴C. If the impact that excavated Oued Awlitis 001 also launched it, this event likely produced an impact crater >10 km in diameter. Using petrologic constraints and Lunar Reconnaissance Orbiter Camera and Diviner data, we test Giordano Bruno and Pierazzo as possible launch craters for Oued Awlitis 001.     

Singular value decomposition and cluster analysis as regression diagnostics tools for geodetic applications

It is well known that high-leverage observations significantly affect the estimation of parameters. In geodetic literature, mainly redundancy numbers are used for the detection of single high-leverage observations or of single redundant observations. In this paper a further objective method for the detection of groups of important and less important (and thus redundant) observations is developed. In addition, the parameters which are predominantly affected by these groups of observations are identified. This method thus complements other diagnostics tools, such as, e.g., multiple row diagnostics methods as described in statistical literature (see, e.g., Belsley et al. in Regression diagnostics: identifying influential data and sources of collinearity. Wiley, New York, 1980). The method proposed in this paper is based on geometric aspects of adjustment theory and uses the singular value decomposition of the design matrix of an adjustment problem together with cluster analysis methods for regression diagnostics. It can be applied to any geodetic adjustment problem and can be used for the detection of (groups of) observations that significantly affect the estimated parameters or that are of negligible impact. One of the advantages of the proposed method is the improvement of the reliability of observation plans and thus the reduction of the impact of individual observations (and outliers) on the estimated parameters. This is of particular importance for the very long baseline interferometry technique which serves as an application example of the regression diagnostics tool.     

Conventions on thermal expansion modelling of radio telescopes for geodetic and astrometric VLBI

Thermal expansion of radio telescopes has long been recognized as an effect which cannot be neglected in geodetic and astrometric VLBI data analysis if millimeter accuracy is desired. In this article, the author documents the conventions which are being set by the International VLBI Service for Geodesy and Astrometry (IVS) for a consistent modelling of this effect in its routine product generation. For the largest telescopes, the annual cycle of thermal expansion may change the height of the VLBI reference point by as much as 20 mm. However, for telescopes which are used in present-day IVS operations, the variations rather range from 4 to 6 mm.     

Comment on ‘García‐Santos G,Bruijnzeel LA. 2011. Rainfall,fog and throughfall dynamics in a subtropical ridge top cloud forest,National Park of Garajonay (La Gomera,Canary Islands,Spain). Hydrological Processes 25: 411–417’

A previous study aiming to characterize the water dynamics of a cloud forest in the Garajonay National Park (La Gomera) from measurements taken in a plot located in the upper part of a selected watershed within the park is here commented. Reported magnitudes of hydrological variables and conclusions based on them are in disagreement with those of numerous studies carried out previously at the same site. Large data dispersion and inapplicability of some of the hypothesis assumed are shown to invalidate most of the results. Copyright © 2011 John Wiley & Sons, Ltd.     

Intra-plate deformation in west-central Europe

The central part of Europe north of the alpine orogenic belt is generally seen as a relatively stable area of the western tip of the Eurasian plate. Indeed, up to now, no geodetically significant motions have been detected although an active rift system running roughly in SSE–NNW direction along the Rhine valley could have some effect on the stability of this region. Presently, the increasing accuracy of geodetic point motions should allow the study of small motions at levels down to nearly 0.1 mm/yr. We start our investigation with a closer look at the ‘true’ accuracy and significance of GPS derived point velocities of permanent stations. We compare and discuss the different levels of formal errors obtained by the three analysis centers considered in this study (EPN, JPL and SOPAC) and present additional ways of assessing the accuracy using the redundancy offered by different independent analyses and multiple systems operating at one site. On the average, all results indicate that a one-sigma level of ±0.3 mm/yr can be seen as a conservative estimate for the horizontal accuracy of point motions in central Europe. On the basis of this assumption we find that at present, the actual velocity field as determined by different analysis groups and centers does not show any significant east–west extensional deformation. We do however see a prominent north–south compressional velocity gradient of about 1 mm/yr/1000 km (1 nanostrain/yr) which could be associated with the Alpine thrust in conjunction with a south-directed horizontal component of the Fennoscandian Glacial Isostatic Adjustment.     

Development of an Enzyme Immunoassay for the Analysis of the Atrazine Metabolite Hydroxyatrazine Entwicklung eines Enzymimmunoassays zur Analyse des Atrazin-Metaboliten Hydroxyatrazin

A highly sensitive and specific enzyme immunoassay (EIA) is described for the detection of the atrazine metabolite hydroxyatrazine. Polyclonal antibodies were raised in rabbits by immunization with a hapten-bovine serum albumin (BSA) conjugate containing 8 hapten residues per molecule of BSA. An EIA with a horseradish peroxidase (HRP) hapten tracer was optimized in microtitre plates. A concentration of 50% B/B₀ was found at 0.10 μg/L for hydroxyatrazine. A limit of determination for hydroxyatrazine was reached at approximately 0.01 μg/L, i.e. well below the maximum concentration permitted by the EU guidelines for drinking water and the drinking water ordinance of the FRG. The assay did not require concentration or clean-up steps for drinking water or ground water samples. Validation experiments confirmed a good accuracy and precision. Hydroxyatrazine is reported to be the main atrazine metabolite found in soil samples. As organic solvents are usually employed for soil extraction, the influence of methanol as representative organic solvent on the assay was examined. Up to a concentration of 5% (v/v) methanol, the organic solvent did not affect the assay.     

Deep structure of the bohemian massif from phase velocities of Rayleigh and Love waves

Summary Phase velocities of Rayleigh and Love waves have been measured between the broadband seismic stations KHC (Kaperské Hory, South Bohemia) and KSP (Ksi, Lower Silesia), a profile that nearly coincides with the Interactional DSS Profile VII. The data for both wave types were separately inverted into models of shear-wave velocity versus depth. Novotný's model KHKS 82[1] for the DSS Profile VII was used as a start model. While the crustal section of Novotný's model is compatible with both of our data sets, our Rayleigh-wave data require smaller shear-wave velocities, on the average by 0.24 km/s, in the top 180 km of the mantle. The average difference between Novotný's model and our Love-wave model in that depth range is only 0.06 km/s. If our identification of the observed Love waves as the fundamental mode is correct, this result indicates the presence of polarization anisotropy in the uppermost mantle.

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