Archaean to Proterozoic Crustal Evolution in the Central Zone of the Limpopo Belt (South Africa-Botswana): Constraints from Combined U-Pb and Lu-Hf Isotope Analyses of Zircon

A combined set of U–Pb and Lu–Hf in situ laser ablationICP-(MC)-MS zircon analyses were obtained from orthogneissesand granitoids in the Central Zone of the Limpopo Belt, whichcomprises the Beit Bridge and Mahalapye complexes. The resultsindicate that by combining the two isotope systems primary magmaticzircon domains can be distinguished from those formed duringlater metamorphic events, even if the distinct zircon domainsunderwent multiple Pb loss and the texture–age relationships,as obtained by cathodoluminescence images and U–Pb analyses,are ambiguous. Furthermore, the applied technique allows distinctionof zircon grains formed in juvenile magmas from those generatedby melting of older continental crust or affected by substantialcrustal contamination. The combined U–Pb and Lu–Hfdata reveal that the Sand River gneiss suite of the Beit BridgeComplex was emplaced at 3283 ± 8 Ma and formed from meltingof an older Archaean crust, which was derived from a depletedmantle source at around 3·65 Ga. The hafnium model age(T_DM^Hf) is significantly older than those obtained from zirconsfrom numerous Neoarchaean granitoids of the Beit Bridge Complex,comprising the Singelele gneiss (2647 ± 12 Ma), the Bulaigranite (2612 ± 7 Ma), the Regina gneiss (2649 ±9 Ma) and two samples of the Zanzibar gneiss (2613 ±6 Ma). These granitoids show initial Hf(t) values between +0·5 and –7·1, which correspond to initialT_DM^Hf between 3·46 and 3·01 Ga. These variableT_DM^Hf_initial and Hf(t)_initial values are interpreted to be theresult of different mixtures of reworked 3·65 Ga Palaeoarchaeancrust with juvenile magmas extracted from the depleted mantleduring the Neoarchaean at 2·65 Ga. This conclusion issupported by results obtained from the Mahalapye Complex, whichwas affected by migmatization and granite intrusions duringthe Palaeoproterozoic at 2·02–2·06 Ga. TheMokgware granite (2019 ± 9 Ma) contains zircon xenocrystswith Pb–Pb ages of 2·52–2·65 Ga and2·93 Ga and hafnium model ages of 3·0–3·4Ga, indicating that this granite is derived from remelting ofArchaean crust. In contrast, uniform T_DM^Hf_initial ages of 2·61–2·67Ga obtained from a diorite gneiss (2061 ± 6 Ma) of theMahalapye Complex indicate that its protolith may have beenformed from remelting of a Neoarchaean juvenile crust. VariableHf(t)_initial values from –3·7 to +6·3 ofzircon cores (2711 ± 11 Ma) in an adjacent leucosomealso support a model of mixing of juvenile mantle derived matterwith older crust in the Neoarchaean. KEY WORDS: Archaean; Palaeoproterozoic; Limpopo Belt; zircon, U–Pb dating; Lu–Hf isotopes; LA-ICP-MS     

Magnetic helicity in stellar dynamos: new numerical experiments

The theory of large scale dynamos is reviewed with particular emphasis on the magnetic helicity constraint in the presence of closed and open boundaries. In the presence of closed or periodic boundaries, helical dynamos respond to the helicity constraint by developing small scale separation in the kinematic regime, and by showing long time scales in the nonlinear regime where the scale separation has grown to the maximum possible value. A resistively limited evolution towards saturation is also found at intermediate scales before the largest scale of the system is reached. Larger aspect ratios can give rise to different structures of the mean field which are obtained at early times, but the final saturation field strength is still decreasing with decreasing resistivity. In the presence of shear, cyclic magnetic fields are found whose period is increasing with decreasing resistivity, but the saturation energy of the mean field is in strong super‐equipartition with the turbulent energy. It is shown that artificially induced losses of small scale field of opposite sign of magnetic helicity as the large scale field can, at least in principle, accelerate the production of large scale (poloidal) field. Based on mean field models with an outer potential field boundary condition in spherical geometry, we verify that the sign of the magnetic helicity flux from the large scale field agrees with the sign of α. For solar parameters, typical magnetic helicity fluxes lie around 10⁴⁷ Mx² per cycle.     

Geochemistry of drill core samples from Yaxcopoil‐1, Chicxulub impact crater,Mexico

Abstract— The chemical composition of suevites, displaced Cretaceous target rocks, and impact‐generated dikes within these rocks from the Yaxcopoil‐1 (Yax‐1) drill core, Chicxulub impact crater, Mexico, is reported and compared with the data from the Yucatán 6 (Y6) samples. Within the six suevite subunits of Yax‐1, four units with different chemical compositions can be distinguished: a) upper/lower sorted and upper suevite (depth of 795–846 m); b) middle suevite (depth of 846–861 m); c) brecciated impact melt rock (depth of 861–885 m); and d) lower suevite (depth of 885–895 m). The suevite sequence (a), (b), and (d) display an increase of the CaO content and a decrease of the silicate basement component from top to bottom. In contrast, the suevite of Y6 shows an inverse trend. The different distances of the Yax‐1 and Y6 drilling sites from the crater center (～60, and ～47 km, respectively) lead to different suevite sequences. Within the Cretaceous rocks of Yax‐1, a suevitic dike (depth of ～916 m) does not display chemical differences when compared with the suevite, while an impact melt rock dike (depth of ～1348 m) is significantly enriched in immobile elements. A clastic breccia dike (depth of ～1316 m) is dominated by material derived locally from the host rock, while the silicate‐rich component is similar to that found in the suevite. Significant enrichments of the K₂O content were observed in the Yax‐1 suevite and the impact‐generated dikes. All impactites of Yax‐1 and Y6 are mixtures of a crystalline basement and a carbonate component from the sedimentary cover. An anhydrite component in the impactites is missing (Yax‐1) or negligible (Y6).     

Stellar dynamo driven wind braking versus disc coupling

Star‐disc coupling is considered in numerical models where the stellar field is not an imposed perfect dipole, but instead a more irregular self‐adjusting dynamo‐generated field. Using axisymmetric simulations of the hydromagnetic mean‐field equations, it is shown that the resulting stellar field configuration is more complex, but significantly better suited for driving a stellar wind. In agreement with recent findings by a number of people, star‐disc coupling is less efficient in braking the star than previously thought. Moreover, stellar wind braking becomes equally important. In contrast to a perfect stellar dipole field, dynamo‐generated stellar fields favor field‐aligned accretion with considerably higher velocity at low latitudes, where the field is weaker and originating in the disc. Accretion is no longer nearly periodic (as it is in the case of a stellar dipole), but it is more irregular and episodic. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Fingerprinting the Late Pleistocene tephras of Ciomadul volcano,eastern–central Europe

Late Pleistocene tephras derived by large explosive volcanic eruptions are widespread in the Mediterranean and surrounding areas. They are important isochronous markers in stratigraphic sections and therefore it is important to constrain their sources. We report here tephrochronology results using multiple criteria to characterize the volcanic products of the Late Pleistocene Ciomadul volcano in eastern–central Europe. This dacitic volcano had an explosive eruption stage between 57 and 30 ka. The specific petrological character (ash texture, occurrence of plagioclase and amphibole phenocrysts and their compositions), the high-K calc-alkaline major element composition and particularly the distinct trace element characteristics provide a strong fingerprint of the Ciomadul volcano. This can be used for correlating tephra and cryptotephra occurrences within this timeframe. Remarkably, during this period several volcanic eruptions produced tephras with similar glass major element composition. However, they differ from Ciomadul tephras by glass trace element abundances, ratios of strongly incompatible trace elements and their mineral cargo that serve as discrimination tools. We used (U-Th)/He zircon dates combined with U-Th in situ rim dates along with luminescence and radiocarbon dating to constrain the age of the explosive eruptions of Ciomadul that yielded distal tephra layers but lack of identified proximal deposits.     

Hydrothermal fluid flow associated to the extensional evolution of the Adriatic rifted margin: Insights from the pre- to post-rift sedimentary sequence (SE Switzerland,N ITALY)

This paper investigates the hydrothermal fluid circulation that was linked to the extensional evolution of the Adriatic rifted margin during the Jurassic opening of the Alpine Tethys. Remnants of this rifted margin are spectacularly preserved in SE Switzerland and N Italy. Five study areas were chosen ranging from the former proximal to the most distal part of the margin. We demonstrate an intimate link between Jurassic extensional tectonics and fluid activity affecting the pre- to early post-rift sedimentary sequences. Nature, composition and origin of fluids are constrained by a multidisciplinary approach based on field observations and including geochemical (O-C, Sr, He isotopes, U-Pb datings, fluid inclusion microthermometry) and petrological methods. Several fluid-related diagenetic products and processes such as dolomitization, veining, hydraulic brecciation, and silicification can be recognized. It appears that different paleogeographic settings and different stratigraphic levels document distinct phases of fluid activity. The fluids reached temperatures of up to 150°C near paleo-seafloor. They were enriched in ¹⁸O, had high ⁸⁷Sr/⁸⁶Sr and low ³He/⁴He ratios, documenting a strong interaction between seawater and a granitic basement. Many lines of evidence point to the occurrence of over-pressured fluids and long-lasting fluid circulation due to fault-valve mechanisms and high thermal gradients. Two main stages with different fluid chemistry can be recognized: (1) a carbonate-rich stage that developed during the stretching phases and was linked to high-angle normal faulting, and (2) a silica-rich stage occurring during late rift exhumation of crustal and mantle rocks in the distal domains in the presence of detachment faults and high thermal gradients. This paper provides, for the first time, a large and robust characterization of fluid–rock interactions occurring during rifting along an almost complete section across a magma-poor rifted margin.     

Reconstruction of the prograde PT history of high-P migmatitic paragneisses via melt-reintegration approach and thermodynamic modelling (Allochthonous Complexes,NW Iberian Massif)

The Upper Units of the allochthonous complexes of the NW Iberian Massif constitute a terrane with continental affinity. They represent the vestiges of a Cambrian magmatic arc developed in the periphery of Gondwana (West African Craton) which was involved in the Devonian Variscan collision, undergoing high-P, high-T metamorphism. This includes ultramafic rocks, high-P mafic rocks (eclogites and granulites) and high-P migmatitic paragneisses. The latter rocks show an extensive migmatization with the leucosomes oriented parallel to the regional foliation. The migmatitic paragneisses are composed of garnet, kyanite, biotite, quartz, plagioclase, K-feldspar, rutile and Ti-hematite. Thermodynamic modelling using the measured bulk composition in the NCKFMASTHO system indicates metamorphic peak conditions of ~15 kbar and ~800 to 835°C, followed by a significant cooling. The prograde evolution is assessed by means of a melt-reintegration approach, using the composition of the garnet and its inclusions. An appropriate composition of liquid is added to the measured bulk composition to emulate the pre-melting bulk composition. Modelling of this melt-reintegrated composition allows to identify a colder high-P episode below ~500°C. Zircon crystals extracted from the leucosomes show overgrowths crystallized from the partial melt at c. 389 Ma (U–Pb system). The P–T–t path proposed reveals a subduction of the peri-Gondwanan arc-derived section down to mantle depths. An isobaric heating stage occurred as a result of residence at great depths and/or inception of a transient oceanic basin at c. 395 Ma. The ensuing near-isothermal exhumation occurred due to the extension related to the inception of the basin, reaching the thermal peak shortly before c. 389 Ma. Subsequent cooling is related to the underthrusting of colder oceanic and transitional crust below the HP-HT Upper Units.     

The impact of climate change on water fluxes in a Macaronesian cloud forest

Fog phenomena and their associated meteorological variables were continuously monitored during 4 years in an evergreen laurisilva cloud forest of the Anaga Massif Biosphere Reserve (Tenerife, Canary Islands), in order to establish its current dynamics. Fog was more frequent during night through early morning and in the afternoon, and particularly from May until September, coincidental with a frequent immersion of the 1025 m a.s.l. experimental site in the cloud layer of wind‐driven stratocumulus. The concomitant meteorological conditions during different fog regimes, characterized according to visibility (Ω) ranges, were compared with those when fog was absent. The presence of fog was associated with a significant reduction in global solar radiation, R_g, increased wind speed, and lower and more stable ambient temperatures. The foggy versus fog‐free hourly medians of R_g were found to be linearly related, whereas the proportion of median R_g reduction due to fog varied logarithmically with Ω. However, foggy versus fog‐free extreme values of the hourly R_g distributions departed from such a linear trend. By contrast, hourly temperatures during foggy versus fog‐free periods behaved linearly for most of the Ω range, except for very dense fog, Ω ≤ 100 m. Transpiration of the canopy, intermittently wetted due to interception of both rain and fog water droplets, was determined by quantifying the water balance at leaf scale with a mathematical model for the two representative hypostomatous species present at the site: the arboreal shrub Erica platycodon, with needle‐like leaves, and the laurophyll tree Myrica faya. Both tree transpiration and evaporation of the intercepted fog water were predictively higher during summer. By contrast, transpiration was reduced during February, in agreement with a 1 year period of sap velocity measurements, and was not appreciably affected by soil moisture content. The consequences of an anticipated downward shift of the stratocumulus cloud layer and of various projected Representative Concentration Pathways (RCPs) scenarios in the Macaronesian area were simulated, yielding in all cases a significant rise in transpiration for both species. Particularly, the simulated RCPs scenarios implied 29%–73% increments in transpiration from the actual values. Because fog is concomitant with lower temperatures and vapour pressure deficit, the modification of its current distribution as a consequence of climate change may have a direct effect on such associated meteorological variables, and therefore a meaningful impact in the water relations of the laurel cloud forests.     

Bioavailability and bacterial degradation rates of dissolved organic matter in a temperate coastal area during an annual cycle

The bioavailability and bacterial degradation rates of dissolved organic matter (DOM) were determined over a seasonal cycle in Loch Creran (Scotland) by measuring the decrease in dissolved organic carbon (DOC), nitrogen (DON) and phosphorous (DOP) concentrations during long-term laboratory incubations (150 days) at a constant temperature of 14 °C. The experiments showed that bioavailable DOC (BDOC) accounted for 29 ± 11% of DOC (average ± SD), bioavailable DON (BDON) for 52 ± 11% of DON and bioavailable DOP (BDOP) for 88 ± 8% of DOP. The seasonal variations in DOM concentrations were mainly due to the bioavailable fraction. BDOP was degraded at a rate of 12 ± 4% d^– 1 (average ± SD) while the degradation rates of BDOC and BDON were 7 ± 2% d^– 1 and 9 ± 2% d^– 1 respectively, indicating a preferential mineralization of DOP relative to DON and of DON relative to DOC. Positive correlations between concentration and degradation rate of DOM suggested that the higher the concentration the faster DOM would be degraded. On average, 77 ± 9% of BDOP, 62 ± 14% of BDON and 49 ± 19% of BDOC were mineralized during the residence time of water in Loch Creran, showing that this coastal area exported C-rich DOM to the adjacent Firth of Lorne. Four additional degradation experiments testing the effect of varying temperature on bioavailability and degradation rates of DOM were also conducted throughout the seasonal cycle (summer, autumn, winter and spring). Apart from the standard incubations at 14 °C, additional studies at 8 °C and 18 °C were also conducted. Bioavailability did not change with temperature, but degradation rates were stimulated by increased temperature, with a Q₁₀ of 2.6 ± 1.1 for DOC and 2.5 ± 0.7 for DON (average ± SD).     

Testing the preservation potential of early diagenetic dolomites as geochemical archives

Early marine diagenetic dolomite is a rather thermodynamically-stable carbonate phase and has potential to act as an archive of marine porewater properties. However, the variety of early to late diagenetic dolomite phases that can coexist within a single sample can result in extensive complexity. Here, the archive potential of early marine dolomites exposed to extreme post-depositional processes is tested using various types of analyses, including: petrography, fluid inclusion data, stable δ¹³C and δ¹⁸O isotopes, ⁸⁷Sr/⁸⁶Sr ratios, and U-Pb age dating of various dolomite phases. In this example, a Triassic carbonate platform was dissected and overprinted (diagenetic temperatures of 50 to 430°C) in a strike-slip zone in Southern Spain. Eight episodes of dolomitization, a dolostone cataclasite and late stage meteoric/vadose cementation were recognized. The following processes were found to be diagenetically relevant: (i) protolith deposition and fabric-preservation, and marine dolomitization of precursor aragonite and calcite during the Middle–Late Triassic; (ii) intermediate burial and formation of zebra saddle dolomite and precipitation of various dolomite cements in a Proto-Atlantic opening stress regime (T ca 250°C) during the Early–Middle Jurassic; (iii) dolomite cement precipitation during early Alpine tectonism, rapid burial to ca 15 km, and high-grade anchizone overprint during Alpine tectonic evolution in the Early Eocene to Early Miocene; (iv) brecciation of dolostones to cataclasite during the onset of the Carboneras Fault Zone activity during the Middle Miocene; and (v) late-stage regression and subsequent meteoric overprint. Data shown here document that, under favourable conditions, early diagenetic marine dolomites and their archive data may resist petrographic and geochemical resetting over time intervals of 10⁸ or more years. Evidence for this preservation includes preserved Late Triassic seawater δ¹³C_DIC values and primary fluid inclusion data. Data also indicate that oversimplified statements based on bulk data from other petrographically-complex dolomite archives must be considered with caution.