LES Study of the Energy Imbalance Problem with Eddy Covariance Fluxes

The spatial representativeness of heat fluxes on the basis of single-tower measurements, and the mechanism of the so-called energy imbalance problem, are investigated through numerical experiments using large-eddy simulation (LES). LES experiments are done for the daytime atmospheric boundary layer heated over a flat surface, as a best-case scenario completely free of sensor errors and the uncertainties of field conditions. Imbalance is defined as the deviation of the `turbulent' heat flux at a grid point from the horizontally averaged `total' heat flux. Both the theoretical and numerical results of the present study suggest the limitation of single-tower measurements and the necessity of horizontally-distributed observation networks.The temporally averaged `turbulent' flux based on a point measurement systematically underestimates the `total' flux (negative imbalance). This is attributed to local advection effects caused by the existence of turbulent organized structures (TOS), whose time scale is much longer than that of thermal plumes. The temporal and spatial change of TOS patterns causes low-frequency trends in the velocity and temperature data resulting in large scatter of the flux estimates. The influences of geostrophic wind speed, averaging time, observation height, computational domain size and resolution on tower-measured fluxes are also discussed. Finally, it is suggested that a weak inhomogenity in surface heating may reduce the negative bias of flux estimates.     

Enrichment of alkanes within a phytoplankton bloom during an in situ iron enrichment experiment in the western subarctic Pacific

During the Subarctic Pacific Iron Experiment for Ecosystem Dynamics Study ΙΙ (SEEDS-II), we monitored variations in the concentrations of non-methane hydrocarbons (NMHCs), CH₃Cl, N₂O, and CH₄ within a phytoplankton bloom. Stable isotopic compositions were also determined to evaluate the sources of the variations. Although there was little variation in either the concentrations or the stable isotopic compositions of alkenes, CH₃Cl, N₂O, and CH₄ during the 23-day observation period, alkane concentrations increased substantially as the phytoplankton bloomed. The column-integrated quantities of alkanes increased to 3 times pre-bloom levels for C₂H₆, 5 times for C₃H₈, and 20 times for n-C₄H₁₀. The δ¹³C values of both C₂H₆ and C₃H₈ remained almost constant while concentrations increased, whereas that of n-C₄H₁₀ increased by about 12‰. To evaluate the sources of the alkanes produced during the bloom, we compared their δ¹³C values with those of alkanes produced in axenic phytoplankton cultures in our laboratory. We concluded that during the SEEDS-ΙΙ experiment the major portions of C₂H₆ and C₃H₈ were produced during the autolysis of diatoms cells, whereas n-C₄H₁₀ was produced during autolysis of other phytoplankton cells such as cryptophytes and dinoflagellates.     

High pressure phase equilibria in the system CaTiO3-CaSiO3: stability of perovskite solid solutions

Phase relations in the system CaTiO₃-CaSiO₃ were experimentally examined at 5.3–14.7 GPa and 1200–1600 °C with a 6–8 type multianvil apparatus. As pressure increases, stability field of perovskite solid solution extends from CaTiO₃ to CaSiO₃, and the perovskite becomes stable for the entire composition range above about 12.3 GPa. The stability field of Ca(Ti_1?X, Si_X)₂O₅ (0.78<x≦1) titanite solid solution +Ca₂SiO₄ larnite exists in the CaSiO₃-rich composition range at 9.3–12.3 GPa and 1200 °C. Perovskite solid solutions containing CaSiO₃ component of 0 to 66 mol% could be quenched to 1 atm. The composition-molar volume relationship of perovskite solid solution showed that molar volume of perovskite solid solution linearly reduces from the value of CaTiO₃ to that of CaSiO₃.     

Arc-parallel extension in preparation of the rotation of southwest Japan: Tectonostratigraphy and structures of the Lower Miocene Ichishi Group

Opening of the Japan Sea back arc basin was accompanied by extensional tectonics in the drifting southwest Japan arc. Various trends of Early Miocene grabens in the arc suggest multi-directional rifting, which necessarily involved strike-slip components of some of basin-margin faults. However, such components are not well understood. In this work we conducted a field survey in the Early Miocene Ichishi basin on the northern side of the Median Tectonic Line, central southwest Japan. We found that the basin was a compound of grabens that were formed along normal and sinistral strike-slip faults, the latter of which had northeast–southwest trends. The block faulting in this phase produced basement highs between sub-basins, which were filled with the lower part of the Ichishi Group. We found a low-angle angular unconformity at a middle horizon in the group, with which we define the upper and lower part of the group. The upper part onlapped both the basement highs and the lower part. It means that the transtensional basin formation ceased sometime between 18 and 17.5 Ma in the Ichishi area. The Ichishi basin turned subsequently into a sag basin subsided due to normal faulting probably along the Nunobiki-sanchi-toen fault zone. The transtension and the basin sag were driven by ENE–WSW extensional stress. This arc-parallel extension produced grabens various areas including Ichishi in the Early Miocene. The extensional deformation was eventually localized to the deep rift along the Fossa Magna to make the lithosphere under southwest Japan decoupled from that under northeast Japan. The decoupling allowed the rapid rotation of southwest Japan from ~17.5 Ma. The cluster of those grabens around the Ise bay probably determined the southeastern margin of the Kinki triangle.     

The application of δ13C and C/N ratios as indicators of organic carbon sources and paleoenvironmental change of the mangrove ecosystem from Ba Lat Estuary, Red River, Vietnam

In this study, two sediment cores (~70 cm) were collected from separate mangrove forests straddling the Ba Lat Estuary, Red River of northern Vietnam, to examine the origins of sedimentary organic carbon (SOC) and reconstruct the paleoenvironment. In addition, mangrove leaves and particulate organic matter were collected and measured for δ¹³C to trace the origins of SOC. The cores were analyzed by high-resolution sections for δ¹³C, TOC, C/N ratios, sediment grain size, water content, and porosity, with values of δ¹³C, TOC, and C/N ratios ranging from −28.19 to −22.5‰, 2.14–30.94 mg/g, and 10.29–18.32, respectively. The δ¹³C and TOC relationship indicated that there were some small residual effects of diagenetic processes on TOC and δ¹³C values in mangrove sediments. However, the shifts of δ¹³C and C/N ratios from the bottom to the surface sediment of the cores explained the change in organic matter sources, with values of C/N > 12 and δ¹³C < −25‰, and C/N < 12 and δ¹³C > −25‰ indicated terrestrial (e.g., mangrove litter) and marine phytoplankton sources, respectively. The covarying δ¹³C, C/N ratios, and sediment grain sizes during the past 100 years in sediment cores showed that the paleoenvironment may be reconstructed into three environments (subtidal, tidal flat, and intertidal mangrove). General trends in δ¹³C and C/N followed a gradual increase in the C/N ratio and a concomitant decrease in δ¹³C from the subtidal, through to tidal flat, and to the intertidal mangrove. δ¹³C and C/N ratios are therefore effective in measuring the continuum of environmental change in mangrove ecosystem.     

Mineral distribution within polymineralic veins in the Sanbagawa belt,Japan: implications for mass transfer during vein formation

Pelitic schists of the Sanbagawa metamorphic belt contain several types of polymineralic veins that formed during the late stages of exhumation. The vein mineral assemblages are quartz + albite + K-feldspar + chlorite ± calcite (Type I, II) and quartz + albite + calcite (Type III). Type I and II veins contain quartz and albite with stretched-crystal and elongate-blocky textures, respectively. The mineral species within Type I veins vary with compositional bands within the host rocks. Type III veins are characterized by euhedral to subhedral quartz grains with concentric zoning and a homogeneous distribution along the vein length. The vein textures vary depending on the crack aperture during multiple crack-seal events: <0.08 mm for Type I, and 0.5–10 mm for Type III. Type II veins show intermediate features between Type I and III veins in terms of mineral distribution (weak dependence on the host rock composition) and apparent crack aperture (less than 1–15 mm). These observations suggest a transition in the dominant transport mechanism of vein components with increasing crack aperture, from diffusion from host rocks to fluid advection along cracks.     

Accretion and postaccretion tectonics of the Calamian Islands, North Palawan block, Philippines

Abstract   Upper Paleozoic to Mesozoic sedimentary sequences of chert (Liminangcong Formation), clastics (Guinlo Formation) and a number of limestone units (Coron Formation, Minilog Formation and Malajon Limestone) constitute the accretionary complex of the North Palawan block, Philippines. Based on chert-to-clastic transitions from different stratigraphic sequences around the Calamian Islands, three accretionary belts are delineated: the Northern Busuanga Belt (NBB), the Middle Busuanga Belt (MBB) and the Southern Busuanga Belt (SBB). The accretion events of these belts along the East Asian accretionary complex, indicated by their sedimentary transitions, began with the Middle Jurassic NBB accretion, followed by the Late Jurassic MBB accretion and the Early Cretaceous SBB accretion. Several limestone blocks that formed over the seamounts became juxtaposed with chert–clastic sequences during accretion. During the Late Cretaceous, accretion-subduction along the East Asian margin subsided bringing tectonic stability to the region. The seafloor spreading during the mid-Oligocene disconnected the entire North Palawan block from the Asian mainland and then migrated southward. The collision between the North Palawan block and the Philippine Island Arc system in the middle Miocene generated a megafold structure in the Calamian Islands as a result of the clockwise turn of the accretionary belts in the eastern Calamian from originally northeast–southwest to northwest–southeast.     

Improving the scientific assessment of carbon sinks

Abstract

The future role of carbon sinks with reference to the Kyoto Protocol depends significantly on developing an international consensus on carbon-sink assessment and carbon accounting. A clear and practical approach is needed that allows both the scientific community and policy-makers to construct a viable operational framework. This article proposes that a new strategy be developed for carbon-sink assessment based on full carbon accounting (FCA) alongside a separate political tool for carbon accounting. This approach is derived from the experience of the European critical loads (CL) concept, which seeks to quantify levels of pollutants (such as sulfur) that can be absorbed by the environment without causing ecological harm. Crucial to the implementation of such a strategy are robust institutional settings, such as an internationally coordinated monitoring system, open and fair access to the assessment processes, and international research cooperation programs for addressing associated problems of carbon-sink activities.     

Seasonal change of oceanographic conditions and chlorophyll <Emphasis Type="Italic">a</Emphasis> vertical distribution in the southwestern Okhotsk Sea during the non-iced season

Seasonal changes in oceanographic conditions related to primary productivity was investigated in the southwestern Okhotsk Sea during non-iced seasons, using the observation data conducted in 2000∼2006. Based on hydrographic characteristics, the studied area could be classified into two regions, the Coastal Region which is influenced under the Soya Warm Current and the Forerunner Water of the Soya Warm Current, and the Offshore Region where the Intermediate Cold Water was located in the subsurface layer. This study is the first report on seasonal change of nutrient and chlorophyll a concentrations in the offshore region of the southwestern Okhotsk Sea. Variability of concentrations of chlorophyll a and nutrients is temporally and regionally high in the Coastal Region. The maximum chlorophyll a concentration in April was observed at the surface layer of both regions. The most remarkable feature on the vertical structure in the Offshore Region was the consistent existence of the Intermediate Cold Water and the development of seasonal thermocline in the subsurface layer during summer and autumn. The stratification formed within the euphotic zone in the Offshore Region resulted in the formation of the subsurface chlorophyll a maximum (SCM) from May to October. Throughout the research period, although less amplitude of nutrients at the surface was observed in the Coastal Region than that in the Offshore Region, comparable amplitude of chlorophyll a concentration was observed between regions. These results suggested differences of environmental conditions for primary production between the two regions. Depending on the presence of SCM, relationships between chlorophyll a concentration at the sea surface and chlorophyll a standing stock within the euphotic layer were different. At most stations with SCM, the surface chlorophyll a concentration was lower than 0.6 mg m-3. This suggests that the presence of SCM and the chlorophyll a standing stock within the euphotic layer may be estimated using the surface chlorophyll a concentration from spring to autumn in the studied area.